The invention relates to the field of 
solar cell manufacturing, in particular to a compositely laminated ferroelectric-organic 
hybrid solar cell, and a preparation method thereof. The 
solar cell comprises substrate glass, a first ferroelectric layer, a ferroelectric-organic composite layer, a second ferroelectric layer and electrodes which are arranged from bottom to top, wherein the ferroelectric-organic composite layer is a composite layer comprising a ferroelectric layer and an 
active layer, and comprises a (P3HT:PCBM):BTO 
sol layer formed by the ferroelectric inorganic nanomaterial bariumtitanate (BTO) and the 
organic polymer material P3HT:PCBM of the 
active layer. The solar 
cell and the preparation method thereof have the advantages that ferroelectric BTO nanoparticles are introduced, and a built-in 
electric field generated by 
spontaneous polarization of the particles is utilized to inhibit 
electron hole recombination and reduce the generation of dark currents, so that the 
cell efficiency can be improved; as 
electron hole separation is promoted through the BTO built-in 
electric field, the parallel resistance of the 
cell is increased, and a higher 
fill factor is finally achieved; and 
polymer / inorganic nano-BTO composite photovoltaic devices can be manufactured on the basis of preparation of inorganic nano-
bismuth ferrite ferroelectric materials.