Coating liquid for forming inorganic oxide coating film, inorganic oxide coating film, and display device
A technology of oxide film and coating solution, which is applied in the direction of silicon oxide, silicon dioxide, coating, etc., can solve problems such as difficulty in film formation, and achieve high reliability
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[0155] Hereinafter, although the Example of this invention is demonstrated more concretely, it should not be construed as being limited to these Examples.
[0156] The abbreviations of the compounds used in this example are as follows.
[0157] TEOS: Tetraethoxysilane
[0158] ACPS: Acryloxypropyltrimethoxysilane
[0159] MPMS: Methacryloxypropyltrimethoxysilane
[0160] StTMS: Styryltrimethoxysilane
[0161] TTE: Tetraethoxytitanium
[0162] TIPT: titanium tetraisopropoxide
[0163] AN: aluminum nitrate nonahydrate
[0164] EG: ethylene glycol
[0165] HG: 2-methyl-2,4-pentanediol (alias: hexanediol)
[0166] BCS: 2-butoxyethanol (alias: butyl cellosolve)
[0167] PGME: Propylene Glycol Monomethyl Ether
[0168] EtOH: ethanol
Synthetic example 1
[0170]
[0171] 12.7 g of AN and 3.0 g of water were added to a 200 mL flask and stirred to dissolve AN. 13.4 g of EG, 38.3 g of HG, 36.4 g of BCS, 15.5 g of TEOS, and 18.5 g of MPMS were charged there, and stirred at room temperature for 30 minutes.
[0172]
[0173] 4.7 g of TIPT and 57.5 g of HG were put into a 300 mL flask, and stirred at room temperature for 30 minutes.
[0174] and were mixed and stirred at room temperature for 30 minutes to obtain a solution (K1).
[0175] 50.0 g of this solution K1 was weighed, and 99.1 g of PGME and 0.9 g of initiator function-imparted polymer UV-H4000 (manufactured by KSM Corporation) were added thereto to obtain a solution (KL1).
Synthetic example 2
[0177] 3.3 g of AN, 3.0 g of water, and 76.1 g of EtOH were added to a 300 ml flask and stirred to dissolve AN. 8.6 g of TEOS and 10.2 g of MPMS were thrown into this solution, and it stirred at room temperature for 30 minutes. Then, 18.8 g of TTE was injected|thrown-in, and it stirred at room temperature further for 30 minutes.
[0178] 109.3 g of HG and 46.8 g of BCS were added to this solution, and the pressure was gradually reduced to 80 mmHg ( 10.7 kPa) while distilling off the solvent to obtain 200 g of a solution (K2).
[0179] 50.0 g of this solution K2 was weighed, and 97.0 g of PGME and 3.0 g of polymer UV-H4000 (manufactured by KSM Co., Ltd.) providing an initiation function were added thereto to obtain a solution (KL2).
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