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High-performance PVB heat insulation resin film and preparation method thereof

A high-performance, heat-insulating adhesive technology, applied in adhesives, non-polymer adhesive additives, film/sheet adhesives, etc., can solve the problem of ATO's low heat insulation rate, poor heat resistance, and high price. problems, achieve high visible light transmittance and infrared blocking coefficient, uniform dispersion, and stable system

Active Publication Date: 2015-09-02
上海沪正纳米科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the ITO raw material is expensive and the production cost is high; the heat insulation rate of ATO is low, especially in the near-infrared region; the AZO raw material is easy to obtain, non-toxic and harmless, but its heat insulation effect is not very ideal

Method used

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  • High-performance PVB heat insulation resin film and preparation method thereof
  • High-performance PVB heat insulation resin film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Take 80g of butanone, 12.8g of blue nano-tungsten oxide powder, and 1.3g of polymethoxypropyl acetate, add polymethoxypropyl acetate and tungsten oxide powder to butanone, and grind in a ball mill for 3 hours to prepare nano slurry with tungsten oxide particle diameter less than 20nm.

Embodiment 2

[0026] Take 88g of methyl isobutyl ketone, 13.6g of blue nano-tungsten oxide powder, 0.7g of polymethoxypropyl acetate, 0.8g of polyether modified trisiloxane, mix polymethoxypropylacetate, polymethoxypropyl Ether-modified trisiloxane and tungsten oxide powder are added to methyl isobutyl ketone, and ground in a ball mill for 4 hours to prepare a nano-slurry with a particle diameter of tungsten oxide less than 20nm. The TEM pictures of nano tungsten oxide particles in the nano slurry are as follows figure 1 As shown, the optical transmittance of the nano-slurry is as figure 2 Shown in a.

Embodiment 3

[0028] Take 72g of isopropanol, 11.5g of blue nanometer tungsten oxide powder, 1.5g of polyether modified trisiloxane, add polyether modified trisiloxane and tungsten oxide powder into isopropanol, and grind in a ball mill Grinding in medium for 5 hours to prepare nano slurry with tungsten oxide particle diameter less than 20nm.

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Abstract

The invention discloses a high-performance PVB heat insulation resin film. The high-performance PVB heat insulation resin film comprises, by mass, 0.1-0.5% of tungsten oxide nanometer slurry containing tungsten oxide particles with diameters less than 20nm, 50-80% of PVB resin powder, 18-45% of a plasticizer, 0.1-1% of an anti-oxidant and 0.05-1% of an ultraviolet ray absorber. The high-performance PVB heat insulation resin film has high visible light transmittance and an infrared ray obstruction coefficient. Compared with PVB heat insulation resin films prepared from nanometer ATO, ITO and AZO, the high-performance PVB heat insulation resin film has a better capacity of obstructing infrared rays with wavelength of 1000nm or less in a near-infrared zone. The invention also discloses a preparation method of the PVB heat insulation resin film.

Description

technical field [0001] The invention relates to a high-performance PVB heat-insulating adhesive film, and furthermore, the invention also relates to a preparation method of the PVB heat-insulating adhesive film. Background technique [0002] PVB is the abbreviation of polyvinyl butyral, which can be produced by condensation reaction between polyvinyl alcohol and butyraldehyde. The U.S. government legislated in 1938 to require the use of PVB as the base material for the front windshield of motor vehicles. After more than 70 years of research and development and practice, PVB is still an essential raw material for the production of laminated glass. When the laminated glass is impacted and broken, the glass fragments still adhere to the PVB film, and the PVB adhesive layer endows the laminated glass with good impact resistance and penetration resistance, while maintaining superior optical properties. [0003] With the development of science and technology, people endow PVB la...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J7/00C09J129/14C09J11/04
Inventor 李佳怡郑爱玉李学成丁基哲
Owner 上海沪正纳米科技有限公司
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