Colored photosensitive resin composition for color filter, color filter, and liquid crystal display device comprising same
A technology of photosensitive resin and composition, which is applied in the direction of photosensitive materials, optical filters, photomechanical equipment, etc. used in photomechanical equipment, can solve the problems of drop, pattern peeling, etc., and achieve excellent transmittance and contrast, brightness and Excellent contrast effect
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Synthetic example 1
[0146] 120 parts by weight of propylene glycol monomethyl ether acetate, 80 parts by weight of propylene glycol monomethyl ether, 2 parts by weight of azobisiso Butyronitrile (AIBN), 13.0 parts by weight of acrylic acid, 10 parts by weight of benzyl methacrylate, 57.0 parts by weight of 4-methylstyrene, 20 parts by weight of methyl methacrylate, 3 parts by weight of n-dodecyl Alkylthiols with nitrogen replacement. After that, stirring was performed, and the temperature of the reaction liquid was raised to 110° C., and the reaction was performed for 6 hours. The solid content of the alkali-soluble resin thus synthesized had an acid value of 100.2 mgKOH / g, and a weight average molecular weight Mw measured by gel permeation chromatography (GPC) was about 15,110.
[0147] Manufacture of colored photosensitive resin composition
Embodiment 1
[0149] Mix the above-mentioned of 29.74 parts by weight, the of 5.66 parts by weight, the acid red 52 (Acid Red 52 of TCI America company) of 0.52 parts by weight, the solvent red 122 of 0.41 parts by weight (C.I.Solvent Red 122, Basf Company), 9.32 parts by weight of the resin of , 9.32 parts by weight of KAYARAD DPHA (manufactured by Nippon Kayaku Co., Ltd.), 0.93 parts by weight of TR-PBG-305 (manufactured by TRONLY Company) , 12.75 parts by weight of 4-hydroxy-4-methyl-2-pentanone, and 31.34 parts by weight of propylene glycol monomethyl ether acetate to manufacture a colored photosensitive resin composition.
Embodiment 2
[0151] 16.31 parts by weight of the above , 21.90 parts by weight of , 4.66 parts by weight of , 0.45 parts by weight of Solvent Red 122 (C.I.Solvent Red 122 , Basf Company), 8.42 parts by weight of the resin of , 8.42 parts by weight of KAYARAD DPHA (manufactured by Nippon Kayaku Co., Ltd.), 0.84 parts by weight of TR-PBG-305 (manufactured by TRONLY Company), 12.75 parts by weight of 4-hydroxy-4-methyl-2-pentanone and 26.27 parts by weight of propylene glycol monomethyl ether acetate were used to prepare a colored photosensitive resin composition.
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