Method and system for preparing carbonyl iron powder by utilizing red mud

A technology of carbonyl iron powder and carbonyl iron, which is applied to the removal of carbonyl iron and solid waste, can solve the problems of low utilization rate and long-term storage of industrial waste, and achieve effective utilization, long-term storage and utilization low rate effect

Pending Publication Date: 2015-10-21
JIANGSU PROVINCE METALLURGICAL DESIGN INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

To this end, an object of the present invention is to propose a method and system for preparing carbonyl iron powder from red mud, which can realize the effective utilization of red mud and obtain carbonyl iron powder with high added value, thereby fundamentally solving the problem of The problem of low utilization rate and long-term stockpiling of red mud, an industrial waste

Method used

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  • Method and system for preparing carbonyl iron powder by utilizing red mud
  • Method and system for preparing carbonyl iron powder by utilizing red mud
  • Method and system for preparing carbonyl iron powder by utilizing red mud

Examples

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Embodiment 1

[0089] Red mud, coal, and calcium oxide are mixed evenly and then pelletized and dried. The mixing mass ratio of red mud, coal, and calcium oxide is 100:25:10, and the dried mixed pellets are reduced at 1220°C to obtain Metallized pellets (the metallization rate is 92wt%, and the surface of the pellets shows a slight melting phenomenon), and then the obtained metallized pellets are separated by crushing, grinding and magnetic separation to obtain iron powder with an average particle size of less than 74 microns. Then, the iron powder is contacted with CO countercurrently to generate a carbonylation reaction to generate a gaseous mixture containing carbonyl iron and carbon monoxide, and the gaseous mixture containing carbonyl iron gas and carbon monoxide is condensed to obtain liquid carbonyl iron and carbon monoxide, and the carbon monoxide is returned to contact with the iron powder The reaction is continued, and finally the obtained liquid carbonyl iron is vaporized and then ...

Embodiment 2

[0091] Mix red mud, coal, and limestone and then make pellets and dry them. The mixing mass ratio of red mud, coal, and limestone is 100:35:15. The dried mixed pellets are reduced at 1250°C to obtain metallized pellets. Pellets (90.5wt% metallization rate, micro-melting on the surface of the pellets), and then the metallized pellets are separated through crushing, grinding and magnetic separation to obtain iron powder with an average particle size lower than 74 microns, and then The iron powder is contacted with CO countercurrently to generate a carbonylation reaction to form a gaseous mixture containing carbonyl iron and carbon monoxide, and then condense the gaseous mixture containing carbonyl iron gas and carbon monoxide to obtain liquid carbonyl iron and carbon monoxide, and return the carbon monoxide to contact with the iron powder to continue reaction, and finally gasify the obtained liquid carbonyl iron and then decompose it to obtain carbonyl iron powder with an iron gr...

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Abstract

The invention discloses a method and system for preparing carbonyl iron powder by utilizing red mud. The method comprises the following steps of: (1) mixing red mud, coal and additives to obtain a mixture, and performing pelletization on the mixture so as to obtain a mixed pellets; (2) performing reduction processing on the mixed pellets so as to obtain metalized pellets; (3) performing separation processing on the metalized pellets so as to obtain iron powder and tailings; (4) enabling the iron powder to be in contact with carbon monoxide so as to obtain a gaseous mixture containing carbonyl iron and carbon monoxide; (5) condensing the gaseous mixture containing the carbonyl iron and the carbon monoxide so as to obtain liquid carbonyl iron and first carbon monoxide; and (6) decomposing the liquid carbonyl iron so as to obtain carbonyl iron powder and second carbon monoxide. Through the adoption of the method, the red mud can be effectively utilized, and carbonyl iron powder with a high additional value can be obtained, so that the difficult problems that the industrial wastes, such as red mud, are low in utilization rate and need to be piled and stored for a long time are fundamentally solved.

Description

technical field [0001] The invention belongs to the technical field of metallurgy, in particular, the invention relates to a method and a system for preparing carbonyl iron powder from red mud. Background technique [0002] Red mud is the main waste generated during the production of alumina. Generally, 0.8-1.5 tons of red mud is produced for every ton of alumina produced. Because red mud contains many components and complex structure, its comprehensive utilization has become a worldwide scientific research problem. At present, it is mainly stockpiled, and the stockpiling of red mud not only takes up a lot of land, but also consumes a lot of maintenance costs. The alkali in the red mud will pollute the land environment and deteriorate the ecological environment. A large amount of valuable metals cannot be fully utilized, resulting in a waste of resources. With the increasing depletion of mineral resources and people's emphasis on environmental pollution, how to maximize t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01G49/16B09B3/00
Inventor 王静静宋文臣李红科曹志成薛逊吴道洪
Owner JIANGSU PROVINCE METALLURGICAL DESIGN INST
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