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Formula of water-based ink for preparation of printed matters with structural color light variability and preparation method of water-based ink

A water-based ink and ink technology, applied in ink, household utensils, applications, etc., can solve the problems of structural color whitening, environmental protection restrictions, low hue saturation, etc., and achieve the effect of rich color and luster

Active Publication Date: 2015-11-04
SUZHOU NANO FOREVER MATERIAL TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the application of the particles in the preparation of inks is disclosed, there are still great defects in the application of photonic crystals as pigments in ink formulations after they are assembled. On the one hand, the structural color of the photonic crystal is whitish due to scattering, and the hue saturation is low. On the other hand, when the assembled photonic crystal is dispersed in the ink as a pigment and affected by the solvent, it will disperse into nanoparticles and lose its structural color.
Therefore, the application of "structural color" materials with environmental protection, brilliant color and iridescent effect is limited.

Method used

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  • Formula of water-based ink for preparation of printed matters with structural color light variability and preparation method of water-based ink
  • Formula of water-based ink for preparation of printed matters with structural color light variability and preparation method of water-based ink
  • Formula of water-based ink for preparation of printed matters with structural color light variability and preparation method of water-based ink

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] A kind of preparation method that is used to prepare the water-based ink that has structural color light-changing characteristic print, comprises the following steps:

[0041] a. Add monodisperse styrene microsphere emulsion, water-based acrylic emulsion, and isobutanol into the kettle and stir evenly for 15 minutes;

[0042] b. adding silica nanoparticles, iron oxide red pigment, dispersant and defoamer to the material prepared in step a, stirring for 25 minutes; then grinding the stirred material to below 15 microns;

[0043] c. Add a certain weight portion of leveling agent, film-forming aid, and adhesion promoter to the material prepared in step b, stir for 15 minutes to make it evenly mixed, and prepare the ink;

[0044] Wherein, the parts by weight of each raw material are: particle diameter is 55 parts of styrene emulsions of 270 nanometers (solid content 60%, PDI is 0.03), 15 parts of acrylic acid emulsions (solid content 20%), silicon dioxide 13 parts (particle...

Embodiment 2

[0050] A kind of preparation method that is used to prepare the water-based ink that has structural color light-changing characteristic print, comprises the following steps:

[0051] a. Add monodisperse styrene microsphere emulsion, water-based acrylic acid emulsion, and isobutanol into the kettle and stir evenly for 10 minutes;

[0052] b. adding titanium dioxide nanoparticles, iron oxide red pigment, dispersant and defoamer to the material prepared in step a, stirring for 20 minutes; then grinding the stirred material to below 15 microns;

[0053] c. Add certain parts by weight of leveling agent, film-forming aid and adhesion promoter to the material prepared in step b, stir for 20 minutes to make it evenly mixed, and prepare the ink.

[0054] Wherein, the parts by weight of each raw material are: particle diameter is 47 parts of styrene microsphere emulsion (solid content 20%, PDI is 0.02), particle diameter is 190 nanometers, 15 parts of acrylic acid emulsion (solid conten...

Embodiment 3

[0060] A kind of preparation method that is used to prepare the water-based ink that has structural color light-changing characteristic print, comprises the following steps:

[0061] a. Add monodisperse styrene microsphere emulsion, water-based polyurethane emulsion, and n-butanol into the kettle and stir evenly, and the stirring time is 17 minutes;

[0062] b. adding zinc oxide nanoparticles, phthalocyanine green pigment, dispersant and defoamer to the material prepared in step a, stirring for 15 minutes; then grinding the stirred material to below 15 microns;

[0063] c. Add certain parts by weight of leveling agent, film-forming aid, and adhesion promoter to the material prepared in step b, stir for 17 minutes to make it evenly mixed, and prepare the ink.

[0064] Wherein, the parts by weight of each raw material are: particle diameter is 60 parts of styrene emulsions of 210 nanometers (solid content 40%, PDI is 0.02), water-based polyurethane emulsion 13 parts (solid conte...

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Abstract

Belonging to the field of ink preparation, the invention discloses a preparation method of a water-based ink. The method includes the steps of: (1) mixing a monodisperse nano-microsphere emulsion, water-based resin and an alcohol solvent and stirring the mixture evenly; (2) then adding inorganic nanoparticles, a dispersing agent and a defoaming agent, dispersing the materials evenly and then grinding the mixture fully; and (3) adding a leveling agent, a film-forming assistant, an adhesion promoter and a thickener, and mixing the materials evenly so as to obtain the water-based ink. The water-based ink provided by the invention can be used for preparation of printed matters with structural color light variability, after printing, monodisperse nano-microspheres are assembled into a hexagonal close-packed structure, thereby forming an ink layer with photonic crystals, the color generated by a photonic band gap structure can generate transformation along with view angle change, an iridescent effect can appear, and the color and luster of the ink printed matters are relatively independent and can be combined with each other, so that colorful visual effects can be formed.

Description

technical field [0001] The invention belongs to ink, and in particular relates to a preparation method of water-based ink and an ink formula. Background technique [0002] Ink is a colloidal dispersion system composed of pigment (dye) material, filler, binder, solvent, auxiliary agent, etc. It is an indispensable coloring material used in the printing process. Through printing, the pattern and text are displayed on the substrate, which is used for various printings such as books, periodicals, packaging, and decoration. With the continuous emergence of new dyes and pigments, inks with different hues, lightness, and saturation appear one after another. While meeting the colorful color requirements, people hope that inks can provide magnificent effects such as metallic texture and pearl color. Noble and gorgeous image. As a result, pearlescent inks, metallic inks and other inks added with effect pigments appeared. These inks are prepared by using tiny metal flakes or pearlesc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/50C09D11/107C09D11/03C09D11/102C09D11/105
Inventor 叶常青窦仁美刘德云宋延林
Owner SUZHOU NANO FOREVER MATERIAL TECH
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