Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Core-shell organosilicon modified polyacrylate stiffener and preparation method thereof

A polyacrylate and silicone technology, applied in textiles, papermaking, fiber treatment, etc., can solve problems such as poor hand feeling, poor film-forming properties of stiffening agents, weak adhesion, etc. strong effect

Active Publication Date: 2015-11-11
深圳天鼎新材料有限公司
View PDF5 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The stiffening agent obtained by this method has poor film-forming properties, weak adhesion and bad hand feeling.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The preparation method of stiffening agent is as follows in this example:

[0029] (1) Pre-emulsification of vinyl silicone oil

[0030] Take 5 grams of vinyl silicone oil with a viscosity of 1600mpa s and put it in a 100ml beaker, add 2 grams of AE0-4, 1 gram of AEO-9, 1 gram of OS-15, stir evenly, drop a small amount of deionized water, and During continuous stirring, deionized water was continuously added dropwise until the phase inversion point, and then the remaining deionized water was added. The total amount of water used was 11 grams.

[0031] (2) Add 1 gram of dodecyltrimethylammonium chloride, 5 grams of AEO-9, 5 grams of OS-15, 0.1 grams of acetic acid, and 2 grams of methacrylic acid into a straight four-necked small bottle with a capacity of 500 ml. Glycidyl esters, 2 g hydroxyethyl methacrylate, 2 g dimethyldiallylammonium chloride, 2 g ethylene glycol diacrylate, 23.5 g methyl methacrylate, 5 g methyl acrylate, 15 gram styrene, 23.5 gram butyl acrylate,...

Embodiment 2

[0036] The preparation method of stiffening agent is as follows in this example:

[0037] (1) Pre-emulsification of vinyl silicone oil

[0038] Take 1 gram of vinyl silicone oil with a viscosity of 300mpa s in a 100ml beaker, add 2 grams of AE0-4, 1 gram of AEO-9, 1 gram of OS-15 and stir well, then drop a small amount of deionized water, and During continuous stirring, deionized water was continuously added dropwise until the phase inversion point, and then the remaining deionized water was added, and the total amount of water used was 15 grams.

[0039] (2) Add 1 gram of dodecyltrimethylammonium chloride, 5 grams of AEO-9, 5 grams of OS-15, 0.1 grams of acetic acid, and 1 gram of methacrylic acid into a straight four-necked small bottle with a capacity of 500 ml. Glycidyl esters, 1 g hydroxyethyl methacrylate, 1 g dimethyldiallylammonium chloride, 2 g ethylene glycol diacrylate, 32 g methyl methacrylate, 5 g methyl acrylate, 25 gram styrene, 20 gram butyl acrylate, 12 gram...

Embodiment 3

[0044] The preparation method of stiffening agent is as follows in this example:

[0045] (1) Pre-emulsification of vinyl silicone oil

[0046] Take 5 grams of vinyl silicone oil with a viscosity of 100000mpa s and put it in a 100ml beaker, add 3 grams of AE0-4, 1 gram of AEO-9, 1 gram of OS-15 and stir well, then drop a small amount of deionized water, and During continuous stirring, deionized water was continuously added dropwise until the phase inversion point, and then the remaining deionized water was added, and the total amount of water used was 10 grams.

[0047] (2) Add 1 gram of dodecyltrimethylammonium chloride, 5 grams of AEO-9, 5 grams of O-25, 0.1 grams of acetic acid, and 1 gram of methacrylic acid into a straight four-necked small bottle with a capacity of 500 milliliters. Glycidyl esters, 1 g hydroxyethyl methacrylate, 4 g dimethyldiallylammonium chloride, 2 g ethylene glycol diacrylate, 13.5 g methyl methacrylate, 5 g methyl acrylate, 25 gram styrene, 13.5 g...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
viscosityaaaaaaaaaa
viscosityaaaaaaaaaa
viscosityaaaaaaaaaa
Login to View More

Abstract

The invention discloses a core-shell organosilicon modified polyacrylate stiffener. The stiffener is prepared by carrying out emulsion polymerization on vinyl monomer and vinyl silicone oil, wherein the vinyl silicone oil accounts for 1-5% of the total mass of the vinyl monomer and vinyl silicone oil; and vinyl monomer at least comprises acrylate monomer. The core-shell organosilicon modified polyacrylate has favorable film-forming property and high adhesion. In the emulsion polymerization process, dimethyl diallyl ammonium chloride and ethylene glycol diacrylate are used as reticular crosslinking agents to effectively and greatly enhance the average molecular weight of the polymer, thereby providing rich hand feeling on the premise of ensuring the finishing stiffness of the emulsion. The vinyl silicone oil can endow smoothness, and the cationic emulsifier and cationic initiator ensure the weak cation type of the emulsion and even enable the integral emulsion to have the properties approximate to non-ions, thereby implementing favorable compatibility with the organosilicon smoothing agent.

Description

technical field [0001] The invention relates to the technical field of printing and dyeing auxiliaries, in particular to a stiffening agent for core-shell type organosilicon-modified polyacrylate and a preparation method thereof. Background technique [0002] Ordinary stiffeners, such as polyvinyl acetate white glue resin, although the fabrics treated with it have better stiffness and richer hand feeling, they are brittle, have poor frost resistance, are not washable, and become soft after a long period of storage , and is an anionic type, it cannot be used in the same bath with silicone emulsion, especially amino silicone oil emulsion system. It needs to be shaped twice, which wastes time and energy. Etherified hexamethylolmelamine resin has good stiffness, shrinkage, elasticity and hand feeling after finishing. However, after finishing, the fabric is easy to absorb moisture, the hardness decreases, it will turn yellow and its strength will decrease, and it will release fr...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08F230/08C08F220/32C08F220/28C08F226/02C08F220/14C08F212/08C08F220/18D06M15/356D06M15/263
Inventor 叶林宇
Owner 深圳天鼎新材料有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com