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Acid adding inhibiter and method for acid pickling through acid adding inhibiter

A technology of corrosion inhibitor and pickling solution, which is applied in the field of acid pickling by adding corrosion inhibitor to acid and pickling of automobile structural steel. Corrosion inhibition, overcoming surface defects, and improving appearance

Active Publication Date: 2015-11-11
PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The inventor of the present invention found in the process of hot-rolled pickling of automobile structural steel with the existing corrosion inhibitor that the steel plate was often felt to be unclean after pickling. During the pickling process or during the drying process after pickling, It is often found that there are black spots, yellow spots, lumpy black spots and darkening on the whole plate surface, and the corrosion rate of the steel plate is very high and the quality loss is large, which not only affects the surface quality, but also has a negative impact on the subsequent treatment. , the inventor of the present invention thinks that this is due to the high content of chromium and vanadium in the steel of the automobile structure, and realizes that a corrosion inhibitor that is especially suitable for the steel of the automobile structure should be developed

Method used

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  • Acid adding inhibiter and method for acid pickling through acid adding inhibiter
  • Acid adding inhibiter and method for acid pickling through acid adding inhibiter
  • Acid adding inhibiter and method for acid pickling through acid adding inhibiter

Examples

Experimental program
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Effect test

Embodiment 1

[0040] In container, add the water of 70kg, under the condition of stirring, add 5kg polyepichlorohydrin alkyl trimethyl ammonium chloride (formula (I) structure, X 1 =Cl, m=4), 10 kg of thiourea, 10 kg of aluminum phosphate and 5 kg of phytic acid, and dissolved them in sequence to obtain an aqueous solution I1 with a corrosion inhibitor added to the acid.

Embodiment 2

[0042] Add 65kg of water to the container, add 10kg of tetrabutylammonium iodide, 10kg of thiourea, 10kg of a 1:1 mixture of aluminium phosphate and aluminium dihydrogen phosphate and 5kg of phytic acid to the water successively under stirring conditions and make them sequentially Dissolve, and finally obtain the aqueous solution I2 of the corrosion inhibitor added to the acid.

Embodiment 3

[0044] In container, add the water of 82kg, under the condition of stirring, add successively 5kg tetradecylbenzyldimethyl ammonium chloride, 5kg thiourea, 5kg aluminium dihydrogen phosphate and 3kg phytic acid and tannic acid 1: 1 and make them dissolve in sequence, and finally obtain the aqueous solution I3 with corrosion inhibitor added to the acid.

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Abstract

The invention relates to the field of inhibiters, and discloses an acid adding inhibiter and a method for acid pickling through the acid adding inhibiter. The acid adding inhibiter comprises quaternary ammonium compounds, thiourea, aluminum phosphate and / or aluminum dihydrogen phosphate and phytic acid and / or tannic acid. The acid adding inhibiter can be used in special steel such as automobile structural steel, is small in use amount and has excellent corrosion inhibition performance. Automobile structural steel hot-rolled acid pickling plates with good surface quality can be obtained. Besides, operation cost is low, and economic benefits are good.

Description

technical field [0001] The invention relates to the field of corrosion inhibitors, in particular, to a corrosion inhibitor for addition in acid, a preparation method for the inhibitor for addition in acid, and the use of the inhibitor for addition in acid to acidify automobile structural steel method of washing. Background technique [0002] P510, P510L, SAPH and other series of automotive structural steel hot-rolled pickled sheets are high-grade products in pickling sheets, mainly used for structural parts such as automobile chassis or inner door panels. quality, and the strength is higher than that of the cold-rolled sheet. With the continuous development of the automobile industry, the market's requirements for hot-rolled acid-washed sheets for automobiles continue to increase. On the premise of ensuring stamping and forming performance, it is also necessary to have a certain surface gloss to improve the surface quality of product coating and pre-treatment. The goal. ...

Claims

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Application Information

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IPC IPC(8): C23G1/06C23F11/04
Inventor 许哲峰李正荣郑之旺李俊洪翁建军李卫平王羿周伟
Owner PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP
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