Block polyether elasticity organosilicone softener and preparation method and application thereof

A silicone softener, block polyether technology, applied in textiles, papermaking, fiber processing, etc., can solve the problems of poor product stability and unfavorable wide use, and achieve the effect of excellent elastic feel and style characteristics.

Active Publication Date: 2016-01-06
HANGZHOU TRANSFAR FINE CHEM CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN102505495A discloses a silicone softener with a body structure. The fabric treated by it has good softness and smoothness, and has excellent elasticity. However, this softener needs to be emulsified by adding a large amount of emulsifier, and the product stability is not good. Good, so not conducive to widespread use

Method used

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  • Block polyether elasticity organosilicone softener and preparation method and application thereof
  • Block polyether elasticity organosilicone softener and preparation method and application thereof
  • Block polyether elasticity organosilicone softener and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] In a four-necked flask equipped with a thermometer, a reflux condenser and an electric stirrer, add 9g of formula (1) structure 60g formula (2) structure 369g of isopropanol, heated with a water bath, slowly warming up, when the temperature is controlled at 40°C, pre-react for 1 hour, then continue to heat up to 60-70°C, slowly add 300g of formula (3) end epoxy silicone oil dropwise to In the diamino-based polyether (i.e. the substance of the formula (2)) and the tertiary amino-based polyether (i.e. the substance of the formula (1)), the temperature is slowly raised to 70-90°C, and the reaction time is controlled at 5-25 hours. After the end, lower the temperature to below 40°C, add 7 parts of glacial acetic acid, and slowly add 2237 parts of deionized water to obtain a block polyether elastic silicone softener.

[0029]

Embodiment 2

[0031] In a four-necked flask equipped with a thermometer, a reflux condenser and an electric stirrer, add 55g of the formula (4) structure 30g of formula (2) structure 385g of isopropanol, heated in a water bath, and slowly raised the temperature. When the temperature was controlled at 35°C, pre-reacted for 1 hour, and then continued to heat up to 60-70°C, slowly added 300g of formula (5) end epoxy silicone oil to the In the diamino-based polyether (i.e. the substance of formula (2)) and the tertiary amino-based polyether (i.e. the substance of formula (4)), the temperature is slowly raised to 70-90°C, and the reaction time is controlled at 5-25 hours. After the end, lower the temperature to below 40°C, add 7 parts of glacial acetic acid, and slowly add 2303 parts of deionized water to obtain a block polyether elastic silicone softener.

[0032]

Embodiment 3

[0034] In a four-necked flask equipped with a thermometer, a reflux condenser and an electric stirrer, add 55g of formula (4) structure 65g formula (6) structure 420g of isopropanol, heated in a water bath, and slowly raised the temperature. When the temperature was controlled at 45°C, pre-reacted for 1 hour, and then continued to heat up to 60-70°C, slowly added 300g of formula (5) epoxy silicone oil to the In the diamino-based polyether (i.e. the substance of the formula (6)) and the tertiary amino-based polyether (i.e. the substance of the formula (4)), the temperature is slowly raised to 70-90°C, and the reaction time is controlled at 5-25 hours. After the end, lower the temperature to below 40°C, add 7 parts of glacial acetic acid, and slowly add 2513 parts of deionized water to obtain a block polyether elastic silicone softener.

[0035]

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Abstract

The invention relates to a block polyether elasticity organosilicone softener and a preparation method and an application thereof. Fabric treated by adopting an existing organosilicone softener in a physical conformation has good softness and smoothness and excellent elasticity, but the softener requires addition of a lot of emulsifier for emulsification; and the product stability is poor, and therefore, the softener is not beneficial to wide application. The novel organosilicone softener with a net structure is prepared by epoxide addition reaction of three compounds in a general formula A, a general formula B and a general formula C; the structure of the softener is changed into (An1Bn2Cn3)p; n1 is 1-3; n2 is 1-3; n3 is 1-3; and p is 1-10. According to the block polyether elasticity organosilicone softener provided by the invention, the fabric can be endowed with comprehensive feel of softness, smoothness, fluffiness and elasticity; and particularly, the block polyether elasticity organosilicone softener has an excellent elastic handle style, and has the characteristics of self-emulsification and excellent chemical stability of acid resistance, alkali resistance, salt resistance and the like.

Description

technical field [0001] The invention relates to the field of textile finishing, in particular to a block polyether elastic silicone softener and its preparation method and application. Background technique [0002] During the dyeing and finishing process, fiber fabrics are treated with strong alkali, resins, dyes / printing paints and other chemicals, as well as thermomechanical effects, and the fiber structure will be deformed, resulting in stiff and rough hand feeling of the fabric. Therefore, soft and smooth treatment is an indispensable and important step in the finishing process. Silicone is the most popular type of softener in the textile industry. It has developed from the initial mechanical blending type to today's multifunctional microemulsion. Modified polysiloxane emulsion fabric finishing agent has excellent softening effect and has been widely used, but there is also the problem that the emulsion breaks and sticks to the roller, which leads to the problem of sili...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M15/65C08G81/00
Inventor 刘志华傅幼林王胜鹏陈华群陈天逸陈八斤夏军韩莉颖沈燕
Owner HANGZHOU TRANSFAR FINE CHEM CO LTD
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