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Water-based high moisture permeability, anti-ultraviolet functional coating glue and preparation method

A technology of anti-ultraviolet and coating glue, which is applied in textiles, papermaking, fiber treatment, etc., can solve the problems of undisclosed technologies, and achieve the effects of low production cost, simple preparation method, and good moisture permeability

Active Publication Date: 2017-06-27
LIAONING FIXED STAR FINE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, there is no public technology for synthesizing water-based high moisture-permeable and anti-ultraviolet functional coating glue by emulsion polymerization process.

Method used

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  • Water-based high moisture permeability, anti-ultraviolet functional coating glue and preparation method

Examples

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Effect test

Embodiment 1

[0034] Polymerization: 90 parts of ethylene glycol polyether with an average molecular weight of 2000, 110 parts of ethylene glycol polyether with an average molecular weight of 1000, 60 parts of toluene diisocyanate, and 60 parts of acetone are added to the reactor and heated to 77-83 °C. React at low temperature for 2 hours, add 8 parts of 1,4-butanediol, react at 77-83°C for 3 hours, add 2.5 parts of nano-titanium dioxide, react at 77-83°C for 1 hour, cool down to 57-63°C Put the material in the emulsification kettle, add 620 parts of deionized water to disperse into polyurethane emulsion;

[0035] Emulsion thickening: Add 2 parts of associative polyurethane leveling rheology agent, stir for 1 hour, filter and discharge to obtain the product.

Embodiment 2

[0037] Polymerization: 95 parts of ethylene glycol polyether with an average molecular weight of 2000, 105 parts of ethylene glycol polyether with an average molecular weight of 1000, 57 parts of toluene diisocyanate, and 62 parts of acetone are added to the reactor and heated to 77-83 °C. React at low temperature for 2.5 hours, add 9 parts of 1,4-butanediol, react at 77-83°C for 3.5 hours, add 3 parts of nano-titanium dioxide, react at 77-83°C for 1.5 hours, cool down to 57-63°C Put the material in the emulsification kettle, add 585 parts of deionized water to disperse into polyurethane emulsion;

[0038] Emulsion thickening: Add 1.6 parts of associative polyurethane leveling rheological agent, stir for 1.5 hours, filter and discharge to obtain the product.

Embodiment 3

[0040] Polymerization reaction: 100 parts of ethylene glycol polyether with an average molecular weight of 2000, 100 parts of ethylene glycol polyether with an average molecular weight of 1000, 59 parts of toluene diisocyanate, and 64 parts of acetone are added to the reactor and heated to 77-83 °C. React at low temperature for 2 hours, add 9.5 parts of 1,4-butanediol, react at 77-83°C for 3 hours, add 3.5 parts of nano-titanium dioxide, react at 77-83°C for 1 hour, cool down to 57-63°C Put the material in the emulsification kettle, add 605 parts of deionized water to disperse into polyurethane emulsion;

[0041] Emulsion thickening: Add 1.8 parts of associative polyurethane leveling rheological agent, stir for 1 hour, filter and discharge to obtain the product.

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PUM

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Abstract

The invention discloses waterborne high-moisture-permeability anti-ultraviolet functional coating glue which is prepared in the mode that 90-110 parts of ethylene glycol polyether with the average molecular weight being 2000, 90-110 parts of ethylene glycol polyether with the average molecular weight being 1000, 55-60 parts of toluene diisocynate, 60-65 parts of acetone, 8-10 parts of 1,4-butanediol and 2.5-4 parts of nano titanium dioxide are polymerized, and the materials are dispersed in 580-620 parts of deionized water and thickened through 1.5-2 parts of associative polyurethane flatting and rheological agents. The moisture-permeable anti-ultraviolet functional coating glue is particularly suitable for 15-20D fine-denier nylon chemical fabric, and is soft in using hand feel and good in fastness.

Description

technical field [0001] The invention relates to a coating glue for after-finishing of textiles. The glue coating is used to process 15-20D fine-denier nylon chemical fiber cloth, which has two functions of high moisture permeability and anti-ultraviolet rays. Its technical feature is to use nano-titanium dioxide to modify the water-based polyurethane prepolymer to synthesize a water-based coating adhesive with high moisture permeability and anti-ultraviolet function. Background technique [0002] Summer sun protection skin clothing is mostly made of 15-20D fine-denier nylon chemical fiber cloth. After coating processing, it is required to have a moisture permeability of more than 3500 (according to GB / T12704.1-2009 standard), and an anti-ultraviolet UVA index value of 5%. Below, the anti-ultraviolet UVB index value is below 5%, and the anti-ultraviolet UPF index value is above 50 (the anti-ultraviolet index is tested according to: GB / T18830:2009 standard). This coated fabri...

Claims

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Application Information

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IPC IPC(8): D06M15/568D06M11/46C08G18/66C08G18/48C08G18/32D06M101/34
Inventor 陶忠华杨文堂倪成涛周明
Owner LIAONING FIXED STAR FINE CHEM
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