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Method and device for reducing emission of NOx in waste flue gas of coke oven

A coke oven flue and nitrogen oxide technology, which is applied in the heating of coke ovens, coke ovens, and combustible gas heating coke ovens, etc., can solve the problems of small coke oven combustion chambers and can not be used, so as to improve the production efficiency of coke ovens , reduce the coking cycle, and facilitate the implementation

Inactive Publication Date: 2016-02-03
BAOSHAN IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Source control methods are now mainly low NO X (X=1, 2) combustion method, this method cannot be applied due to the small space of the coke oven combustion chamber

Method used

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  • Method and device for reducing emission of NOx in waste flue gas of coke oven

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] The concentration of nitrogen oxides in a certain coke oven gas is 400mg / m 3 , mixed with pure oxygen and circulating flue gas, mixed with combustion-supporting gas O 2 content of 30%, using coke oven gas as fuel, can make coke oven flue gas NO X The content is controlled at 150mg / m 3 the following.

Embodiment 2

[0044] The concentration of nitrogen oxides in a certain coke oven gas is 410mg / m 3 , mixed with pure oxygen and circulating flue gas, mixed with combustion-supporting gas O 2 Content 18%, using coke oven gas as fuel, can make coke oven flue gas NO X content control in 1 50mg / m 3 the following.

Embodiment 3

[0046] The concentration of nitrogen oxides in a certain coke oven gas is 450mg / m 3 , mixed with pure oxygen and circulating flue gas, mixed with combustion-supporting gas O 2 Content 25%, using coke oven gas as fuel, can make coke oven flue gas NO X The content is controlled at 150mg / m 3 the following.

[0047] The invention provides a method and device for reducing the emission of nitrogen oxides in coke oven flue gas, by using pure oxygen and circulating flue gas to mix, and using coke oven gas as fuel to avoid nitrogen oxides 2 The introduction of, so as to achieve the reduction of NO X emission; the flue gas circulation can use a part of the waste heat of the flue gas to improve the thermal efficiency of combustion; if the refractory material of the coke oven combustion chamber permits, it can increase the mixed combustion-supporting gas O 2 content, increase the temperature of the coke oven combustion chamber, thereby improving the heat transfer effect, reducing the co...

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Abstract

The invention provides a method for reducing emission of NOx in waste flue gas of a coke oven. The method comprises the following steps: (1) introducing oxygen and circulating flue gas of the coke oven into gas mixing equipment to be mixed to obtain a mixed combustion-supporting gas in which the content of O2 is 0-100 percent; (2) introducing gas of the coke oven and the mixed combustion-supporting gas into the combustion chamber of the coke oven to be burnt to produce waste flue gas of the coke oven; (3) after the waste flue gas of the coke oven, produced in the step (2), is cooled down by a heat exchanger, ensuring that part of the waste flue gas of the coke oven enters the gas mixing equipment via a flue gas recirculation blower to be mixed with pure oxygen to produce mixed combustion-supporting gas to participate in combustion and the other part of waste flue gas of the coke oven passes through a smoke removal blower and then enters a smoke discharge chimney to be directly discharged. The method controls production of nitrogen oxides by the waste flue gas of the coke oven from the source, adopts mixing of pure oxygen and circulating flue gas to avoid introduction of N2, and enables emission of nitrogen oxides in the waste flue gas of the coke oven to meet the national standards.

Description

technical field [0001] The invention belongs to the technical field of flue gas denitrification, and relates to a method for denitrification of coke oven flue gas, in particular to a method and a device for reducing the emission of nitrogen oxides in coke oven flue gas. Background technique [0002] Flue gas denitrification technology is mainly divided into source treatment and end treatment. There are three main types of terminal flue gas denitrification technologies: SCR (SelectiveCatalyticReduction, referred to as SCR, selective catalytic reduction method), SNCR (SelectiveNon-CatalyticReduction, referred to as SNCR, selective non-catalytic reduction method) and catalytic oxidation / reduction method, of which: SCR, SNCR Both belong to the dry method; the catalytic oxidation / reduction method belongs to the wet method. [0003] At present, the most widely used method is the SCR method. The SCR method is extremely expensive in terms of engineering costs, high operating costs...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10B21/18
Inventor 郭水华向顺华程乐意
Owner BAOSHAN IRON & STEEL CO LTD
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