Overlapped copper-acid storage battery

A battery, cupric acid technology, applied in the direction of half-lead battery, etc., can solve the problems of losing supporting active material and build-up current, the battery cannot be charged, and the number of cycles is limited, so as to achieve the effect of long service life, extended service life and low cost.

Inactive Publication Date: 2016-02-10
汤恭年
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, lead-acid batteries have disadvantages, that is, short life and limited number of cycles. The main reason is that the lead grid of the positive plate cannot withstand the erosion of oxidation during charging and is broken, so it loses the function of supporting active materials and gathering current.
The lead particles, the active material of the negative plate, react with the dilute sulfuric acid to accumulate lead sulfate every time it is discharged, resulting in the “lead sulfate” of the white plate, forming a huge resistance, so that the battery cannot be charged and becomes invalid.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Make a single such as figure 1 , Figure 5 The shown 1.4V250AH copper acid battery contains a positive plate, a negative plate and a glass fiber separator.

[0049] by figure 2 The positive plate is used as a model, and the production is as follows Figure 7 The positive plate shown. The size of the positive plate frame is 53.2 cm long, 31.5 cm wide, and 0.6 cm thick, with 31 holes in the horizontal direction and 31 holes in the vertical direction, and the active material is lead dioxide. There are three protruding lead pile heads outside the frame, which are welded on as figure 2 The riser 10 shown in is connected to the positive electrode conductive copper plate 6, and the number of risers is 2.

[0050] Negative plate with image 3 The sample plate is adjusted accordingly, and the size of the shell is designed according to the total volume of the positive and negative plates plus the electrolyte and the reserved space. The carrier fluid of the negative plate...

Embodiment 2

[0053] Make a single such as figure 1 , Figure 5 The shown 1.4V250AH copper acid battery contains a positive plate, a negative plate and a glass fiber separator.

[0054] by figure 2 The positive plate is used as a model, and the production is as follows Figure 7 The positive plate shown. The size of the positive plate frame is 53.2 cm long, 31.5 cm wide, and 0.6 cm thick, with 31 holes in the horizontal direction and 31 holes in the vertical direction, and the active material is lead dioxide. There are three protruding lead pile heads outside the frame, which are welded on as figure 2 The riser 10 shown in is connected to the conductive copper plate 6, and the number of risers is 2.

[0055] Negative plate with image 3 The sample plate is adjusted accordingly, and the size of the shell is designed according to the total volume of the positive and polar plates plus the electrolyte and the reserved space. The carrier fluid of the negative plate is copper material, a...

Embodiment 3

[0058] Make a single such as figure 1 , Figure 5 The shown 1.4V250AH copper acid battery contains a positive plate, a negative plate and a glass fiber separator.

[0059] by figure 2 The positive plate is used as a model, and the production is as follows Figure 7 The positive plate shown. The size of the positive plate frame is 53.2 cm long, 31.5 cm wide, and 0.6 cm thick, with 31 holes in the horizontal direction and 31 holes in the vertical direction, and the active material is lead dioxide. There are three protruding lead pile heads outside the frame, which are welded on as figure 2 The riser 10 shown in is connected to the positive electrode conductive copper plate 6, and the number of risers is 2.

[0060] Negative plate with image 3 The sample plate is adjusted accordingly, and the size of the shell is designed according to the total volume of the positive and polar plates plus the electrolyte and the reserved space. The carrier fluid of the negative plate is...

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Abstract

The invention relates to the technical field of electrochemical energy storage equipment, and discloses an overlapped copper-acid storage battery. The overlapped copper-acid storage battery comprises a housing (1), an electrolyte (7), a negative electrode plate (5) and a partition plate (4); the electrolyte comprises a copper sulfate saturated aqueous solution; the current carrier of the negative electrode plate is a pure lead sheet or a copper sheet, wherein a metal layer resistant to dilute sulphuric acid is plated on the surface of the copper sheet; and a copper layer is plated on the surface of the current carrier of the negative electrode plate to be used as the negative electrode active substance. According to the copper-acid storage battery, copper is used to replace lead to be used as the negative electrode active substance; the mixed liquid of dilute sulphuric acid and copper sulfate is used as the electrolyte; the charging/discharging electrochemical reaction of the negative electrode plate only comprises the conversion of copper and the copper sulfate, so that the headache problem that the lead sulfate deposition in the negative electrode plate of a lead-acid storage battery is solved completely, and the service life of the copper-acid storage battery is greatly prolonged consequently.

Description

technical field [0001] The invention relates to the technical field of electrochemical energy storage equipment, in particular to a copper-acid battery derived from a lead-acid battery. Background technique [0002] Lead-acid batteries are currently the world's most mature technology, cheapest, stable performance, high voltage, high current, and most abundant raw materials. [0003] However, lead-acid batteries have disadvantages, that is, short life and limited number of cycles. The main reason is that the lead grid of the positive plate cannot withstand the erosion of oxidation during charging and is broken, so it loses the function of supporting active materials and gathering current. The lead particles, the active material of the negative plate, react with dilute sulfuric acid to accumulate lead sulfate every time it is discharged, resulting in the "lead sulfate" of the white plate, forming a huge resistance, so that the battery cannot be charged and fails. Contents of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/20H01M10/22
CPCH01M10/20H01M10/22Y02E60/10
Inventor 汤恭年陈尚发汤礼铀汤礼守
Owner 汤恭年
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