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3D printer window glass material based on magnesia modification, and preparation method thereof

A 3D printer and window glass technology, applied in the field of window glass materials, can solve the problems of scratches on the surface, poor heat resistance, poor wear resistance, etc.

Inactive Publication Date: 2016-03-30
ANHUI CHUNGU 3D PRINTING INTELLIGENT EQUIP IND TECH RES INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the main component of the inorganic glass material is silicate, this kind of glass material has excellent wear resistance and heat resistance performance, but this kind of glass material has the defect of being fragile
The plexiglass material has the advantage of excellent resistance to cracking, but its surface can form scratches, and its heat resistance is poor
[0003] 3D printer window glass is an important component in 3D printers. In order to facilitate the observation of the process in the printer, it is necessary to require the window glass to have excellent light transmittance, tensile strength, heat resistance and wear resistance, but currently It is difficult for glass materials to meet these requirements at the same time, especially the poor wear resistance

Method used

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  • 3D printer window glass material based on magnesia modification, and preparation method thereof
  • 3D printer window glass material based on magnesia modification, and preparation method thereof
  • 3D printer window glass material based on magnesia modification, and preparation method thereof

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preparation example Construction

[0014] The invention provides a method for preparing a 3D printer window glass material modified by magnesite, comprising:

[0015] 1) In the presence of ultraviolet rays, dissolving nano-magnesite, the complex compound of the structure shown in formula (I) and graphene in N,N-dimethylformamide and ultrasonically stirring to form a modified liquid;

[0016] 2) Mix polymethyl methacrylate, xylitol, aluminum hydroxide, silicon oxide, silver oxide, rare earth oxide, vinyl phenyl silicone oil and modifying liquid, then melt, cool, and granulate to obtain 3D printer window glass material;

[0017]

[0018] Wherein, Mes is 2,4,6-trimethylphenyl.

[0019] In step 1) of the present invention, the wavelength of ultraviolet rays can be selected in a wide range, but in order to make the obtained 3D printer window glass material have more excellent mechanical properties and wear resistance, preferably, in step 1) Among them, the wavelength of ultraviolet light is 150-200nm.

[0020]...

Embodiment 1

[0030] 1) In the presence of ultraviolet light (wavelength is 180nm), the complex compound of structure shown in formula (I), graphene, N,N-dimethylformamide with nano-magnesia magnesite (particle diameter is 37nm) Mix according to the weight ratio of 100:30:3.3:250, and stir for 5 hours under the condition of ultrasonic (frequency 27KHz) at 60°C to form a modified liquid;

[0031] 2) Mix polymethyl methacrylate, xylitol, aluminum hydroxide, silicon oxide, silver oxide, rare earth oxide (cerium oxide), vinyl phenyl silicone oil and modifying solution at 100:10:1.2: 5: 0.5: 1.7: 45: 9 weight ratio mixed, then melted at 180°C for 40 minutes, cooled at 10°C, and granulated to prepare 3D printer window glass material A1;

[0032]

[0033] Wherein, Mes is 2,4,6-trimethylphenyl.

Embodiment 2

[0035] 1) In the presence of ultraviolet light (wavelength is 150nm), the complex compound of structure shown in formula (I), graphene, N,N-dimethylformamide with nano-magnesia magnesite (particle size is 35nm) Mix according to the weight ratio of 100:28:3:200, and stir for 4 hours under the condition of ultrasonic (frequency 25KHz) at 55°C to form a modified liquid;

[0036] 2) Mix polymethyl methacrylate, xylitol, aluminum hydroxide, silicon oxide, silver oxide, rare earth oxide (praseodymium oxide), vinyl phenyl silicone oil, and modifying solution at a ratio of 100:8:1:3: Mix at a weight ratio of 0.1:1.2:40:5, then melt at 175°C for 30 minutes, cool at 5°C, and granulate to obtain 3D printer window glass material A2;

[0037]

[0038] Wherein, Mes is 2,4,6-trimethylphenyl.

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Abstract

The present invention discloses a 3D printer window glass material based on magnesia modification, and a preparation method thereof. The preparation method comprises: 1) in the presence of ultraviolet rays, dissolving nanometer magnesia, a complex having a structure represented by a formula (I) and graphene in N,N-dimethylformamide, and carrying out ultrasonic stirring to form a modification liquid; and 2) mixing polymethyl methacrylate, xylitol, aluminum hydroxide, silicon oxide, silver oxide, a rare earth oxide, vinyl phenyl silicone oil and the modification liquid, melting, cooling, and granulating to prepare the 3D printer window glass material, wherein Mes is mesityl. According to the present invention, the 3D printer window glass material prepared through the method has excellent mechanical properties and excellent wear resistance. The formula (I) is defined in the specification.

Description

technical field [0001] The invention relates to a window glass material, in particular to a magnesite-modified 3D printer window glass material and a preparation method thereof. Background technique [0002] Window glass materials can be divided into inorganic glass materials and organic glass materials according to the material. Among them, the main component of the inorganic glass material is silicate. This kind of glass material has excellent wear resistance and heat resistance performance, but this kind of glass material has the defect of being fragile. The plexiglass material has the advantage of excellent resistance to cracking, but its surface can form scratches, and its heat resistance is poor. [0003] 3D printer window glass is an important component in 3D printers. In order to facilitate the observation of the process in the printer, it is necessary to require the window glass to have excellent light transmittance, tensile strength, heat resistance and wear resis...

Claims

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Application Information

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IPC IPC(8): C08L33/12C08L83/07C08K13/06C08K9/00C08K5/00C08K3/04C08K3/22C08K3/36
CPCC08L33/12C08K2201/003C08K2201/011C08L83/04C08K13/06C08K9/00C08K2003/222C08K5/00C08K3/04C08K2003/2227C08K3/36
Inventor 章传凡吕月林吕晨黄仲佳郑兰斌吴志华刘俊松
Owner ANHUI CHUNGU 3D PRINTING INTELLIGENT EQUIP IND TECH RES INST CO LTD