A low stress state composite substrate for gan growth

A composite substrate, low-stress technology, applied in semiconductor devices, electrical components, circuits, etc., can solve problems affecting the quality of homogeneous epitaxy and chip preparation, GaN epitaxial film wrinkles, poor high temperature stability, etc., to suppress substrate warping Curved and wrinkled epitaxial film, improved epitaxial growth quality, and good thermal and electrical conductivity

Active Publication Date: 2019-01-04
SINO NITRIDE SEMICON
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Existing patents (patent application number: 201210068033.0 and patent application number: 201210068026.0) describe the preparation of composite substrates for GaN growth based on low-temperature bonding and laser lift-off technology and its preparation methods, but currently use dielectric bonding The following problems exist in the preparation of thermally and electrically conductive GaN composite substrates with laser lift-off technology: (1) In the past, lower temperature bonding was mainly used below 600 °C, and the high temperature stability was poor, and GaN was already formed when epitaxially growing GaN at a high temperature above 1000 °C. The bonding structure of the substrate will change again, seriously affecting the quality of homoepitaxial and chip preparation in the later stage; (2) The changes in the substrate transfer process and thermal and conductive substrates will generate greater stress in the transferred substrate, resulting in recombination The substrate is warped to a certain extent, and even wrinkles are formed on the GaN epitaxial film, making it difficult to achieve high-performance GaN single crystal epitaxy and chip preparation
Poor high temperature stability and severe stress residue are the main reasons restricting the further application of substrate transfer technology on high-performance GaN composite substrates

Method used

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  • A low stress state composite substrate for gan growth
  • A low stress state composite substrate for gan growth
  • A low stress state composite substrate for gan growth

Examples

Experimental program
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Effect test

Embodiment 1

[0036] Embodiment 1: use Ni as the stress compensation layer, conductive Ag paste bonding CuMo metal substrate and GaN epitaxial layer, obtain the low stress state composite substrate that is used for GaN growth, specific preparation method is as follows:

[0037] (1) Epitaxial growth of a GaN single crystal layer on a sapphire substrate: On a 2-inch 430-micron-thick flat sapphire substrate, first use MOCVD technology to epitaxially grow a 4-micron-thick GaN single-crystal layer, and then grow thicker in HVPE The thickness of the GaN layer is up to 15 microns.

[0038] (2) Use magnetron sputtering to deposit a Ni thin layer with a thickness of 500 nm on the back side of the CuMo metal substrate as a stress compensation layer, such as Figure 4 (a) shown.

[0039] (3) On the GaN surface of the above-mentioned sapphire-based GaN composite substrate and the front surface of the CuMo substrate with a thickness of 300 microns, respectively spin-coat a conductive Ag paste of about ...

Embodiment 2

[0042] Embodiment 2: Using Au / Pd as the stress compensation layer, Ti / Pd bonded Si substrate and GaN epitaxial layer of adhesive transfer, a low-stress state composite substrate for GaN growth with gallium polarity facing outward is obtained, The specific preparation method is as follows:

[0043] (1) Preparation of adhesive transfer sapphire-based GaN composite substrate: On a 2-inch 430-micron-thick flat sapphire substrate, a 4-micron-thick GaN single crystal layer is epitaxially grown by MOCVD technology, and then grown in HVPE to thicken GaN layer thickness to 15 microns, and then use UV anaerobic adhesive to bond the GaN epitaxial film to a 2-inch 430-micron thick sapphire temporary substrate, the new sapphire substrate is used as a transfer support substrate, and then the original The epitaxial sapphire substrate is removed, and the GaN single crystal layer bonded on the new sapphire substrate is obtained, such as Figure 5 a) as shown.

[0044] (2) On the back side of...

Embodiment 3

[0048] Example 3: Using SiN x As a stress compensation layer, AuAu bonded AlSi metal substrate and GaN epitaxial layer to obtain a low stress state composite substrate for GaN growth, the specific process steps are as follows (such as Figure 6 shown):

[0049] (1) Epitaxial growth of a GaN single crystal layer on a sapphire substrate: On a 2-inch 430-micron-thick flat sapphire substrate, first use MOCVD technology to epitaxially grow a 4-micron-thick GaN single-crystal layer, and then grow thicker in HVPE The thickness of the GaN layer is up to 15 microns.

[0050] (2) SiN with a thickness of 5 microns was prepared by plasma-enhanced chemical vapor deposition on the back of the AlSi metal substrate x thin layer, as a stress compensation layer.

[0051] (3) On the GaN surface of the above-mentioned sapphire-based GaN composite substrate, use magnetron sputtering to prepare a 1 micron thick Au conductive bonding medium layer, and then perform high-temperature diffusion at a ...

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Abstract

The invention discloses a low stress state composite substrate for GaN growth. The substrate comprises a thermally and electrically conductive substrate, a thermally and electrically conductive bonding dielectric layer of high melting point, a GaN monocrystal epitaxial layer and a stress compensation layer, wherein the melting point of the thermally and electrically conductive substrate is higher than 1000 DEG C, the thermally and electrically conductive bonding dielectric layer is placed on the substrate, and the stress compensation layer is prepared at the back side of the thermally and electrically conductive substrate. A GaN epitaxial wafer is bonded to the thermally and electrically conductive substrate by the high-temperature diffusion bonding technology. According to the composite substrate of the invention, homoepitaxy can be realized and a vertical structural device can be directly prepared as a traditional composite substrate, the low stress state and high-temperature stability can be also realized, and the quality of subsequent GaN epitaxial growth and chip preparation can be effectively improved.

Description

technical field [0001] The invention relates to the technical field of semiconductor optoelectronic devices, in particular to a low-stress state and high-temperature stable composite substrate for GaN growth. Background technique [0002] Wide bandgap GaN-based semiconductor materials have excellent optoelectronic properties and have been widely used in the production of light-emitting diodes, lasers, ultraviolet detectors and high-temperature, high-frequency, high-power electronic devices, and can be applied to the preparation of high-end microelectronics required by aerospace Devices, such as high-mobility transistors (HEMTs) and heterojunction transistors (HFETs), have become research hotspots in the international optoelectronics field. [0003] Since the preparation of GaN bulk single crystal is very difficult, large-scale single crystal GaN is difficult to obtain directly, and the price is expensive, the epitaxial growth of GaN material system is mainly based on the lar...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L33/02H01L33/12
Inventor 汪青孙永健陈志忠张国义童玉珍
Owner SINO NITRIDE SEMICON
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