Lithium transition-metal oxide cell

A technology of lithium transition metals and oxides, applied in battery electrodes, secondary batteries, non-aqueous electrolyte batteries, etc., can solve the problems of poor cycle life, low charge and discharge performance, low initial efficiency, etc., and achieve improved adhesion Focus on improving power performance and prolonging service life

Active Publication Date: 2016-05-04
TIANJIN ENERGIES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Graphite materials have the advantages of high first-time efficiency, high lithium intercalation capacity, low lithium intercalation potential, abundant resources, and low price. At the same time, there are some defects: first, graphite materials show large volume changes during the process of lithium intercalation and deintercalation. During the cycle of the battery, a large stress is generated between the carbon material particles, which leads to powder loss of the negative electrode and poor cycle life; secondly, the graphite material has a complete sheet structure and can only insert lithium from the end face, and the high-current charge and discharge performance is low
Hard carbon materials have some characteristics that are completely different from graphite materials. The advantages of hard carbon are low temperature power and cycle performance, but its initial efficiency is low and processing performance is poor.

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0028] A lithium transition metal oxide battery, comprising a negative electrode sheet and a positive electrode sheet;

[0029] The negative electrode sheet includes a negative electrode active material layer, a negative electrode collector Cu foil, and the negative electrode active material layer includes a mixture of graphite and hard carbon, a negative electrode binder, and a negative electrode conductive agent. The negative electrode active material layer adopts graphite (95wt%), and the negative electrode The conductive agent uses SuperP (2wt%), and the negative electrode binder uses CMC (1wt%) and SBR (2wt%);

[0030] The positive electrode sheet includes a positive electrode active material layer, a positive electrode current collector Al foil, and a positive electrode conductive coating. The positive electrode active material layer includes a lithium transition metal oxide, a positive electrode binder, and a positive electrode conductive agent. The lithium transition me...

Embodiment 2

[0043] A lithium transition metal oxide battery, comprising a negative electrode sheet and a positive electrode sheet;

[0044] The negative electrode sheet includes a negative electrode active material layer, a negative electrode collector Cu foil, and the negative electrode active material layer includes a mixture of graphite and hard carbon, a negative electrode binder, and a negative electrode conductive agent. The negative electrode active material layer adopts graphite (95wt%), and the negative electrode The conductive agent uses SuperP (2wt%), and the negative electrode binder uses CMC (1wt%) and SBR (2wt%);

[0045] The positive electrode sheet includes a positive electrode active material layer, a positive electrode current collector Al foil, and a positive electrode conductive coating. The positive electrode active material layer includes a lithium transition metal oxide, a positive electrode binder, and a positive electrode conductive agent. The lithium transition me...

Embodiment 3

[0048] A lithium transition metal oxide battery, comprising a negative electrode sheet and a positive electrode sheet;

[0049] The negative electrode sheet includes a negative electrode active material layer, a negative electrode collector Cu foil, and the negative electrode active material layer includes a mixture of graphite and hard carbon, a negative electrode binder, and a negative electrode conductive agent. The negative electrode active material layer adopts graphite (95wt%), and the negative electrode The conductive agent uses SuperP (2wt%), and the negative electrode binder uses CMC (1wt%) and SBR (2wt%);

[0050] The positive electrode sheet includes a positive electrode active material layer, a positive electrode current collector Al foil, and a positive electrode conductive coating. The positive electrode active material layer includes a lithium transition metal oxide, a positive electrode binder, and a positive electrode conductive agent. The lithium transition me...

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Abstract

The invention provides a lithium transition-metal oxide cell. The lithium transition-metal oxide cell comprises a negative plate and a positive plate. The negative plate comprises a negative active substance layer, negative current collector Cu foil and a negative conductive coating. The negative current collector Cu foil is coated with the negative conductive coating. The negative active substance layer is located on the negative conductive coating. The negative active substance layer comprises a mixture of graphite and hard carbon, a negative pole binder and a negative pole conductive agent. The positive plate comprises a positive active substance layer, positive current collector Al foil and a positive conductive coating. The positive current collector Al foil is coated with the positive conductive coating. The positive active substance layer is located on the positive conductive coating. The positive active substance layer comprises a lithium transition-metal oxide, a positive pole binder and a positive conductive agent. The lithium transition-metal oxide cell improves cell high-rate charge-discharge performances, prolongs a cell service life and can be used for electric bicycles, electric automobiles and energy storage power stations.

Description

technical field [0001] The invention belongs to the field of batteries, in particular to a lithium transition metal oxide battery. Background technique [0002] Known as clean energy and high-efficiency energy, lithium battery energy has been popular in the market since its successful development. Among them, lithium-ion batteries have been developing rapidly in recent years and are widely used in various industries. With the development of emerging industries such as electric bicycles, electric vehicles, and energy storage power stations, higher requirements are placed on the power and life of lithium-ion batteries. [0003] Lithium-ion battery positive and negative electrode materials are lithium ions, lithium ion intercalation compound with layered or tunnel structure that can be freely inserted and extracted. Graphite materials have the advantages of high first-time efficiency, high lithium intercalation capacity, low lithium intercalation potential, abundant resources,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/133H01M4/131H01M10/0525H01M4/1391H01M4/1393H01M10/058
CPCH01M4/131H01M4/133H01M4/1391H01M4/1393H01M10/0525H01M10/058Y02E60/10Y02P70/50
Inventor 宋文娥杨红彦冯树南从长杰王驰伟
Owner TIANJIN ENERGIES
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