Preparation method of nano silver tri-proof antibacterial finishing agent
A technology of antibacterial finishing agent and three-proof finishing agent, which is applied in the direction of fiber treatment, liquid repellent fiber, anti-coloring pollution/anti-fouling fiber, etc. It can solve the problems of dispersibility, poor stability, easy agglomeration, etc., and achieve Not easy to agglomerate, good dispersion, simple process effect
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Embodiment 1
[0028] The first step is the preparation of nano-silver coated with modified starch, the method is as follows:
[0029] (1) the silver nitrate solution of preparation 0.05mol / L and the sodium citrate solution that concentration is 1% are subsequent use;
[0030] (2) Add 50ml of water into the three-necked flask, then add 0.25g of modified starch, turn on the heat-collecting constant temperature heating magnetic stirrer, put the above three-necked flask into it, stir and heat up to 95°C for about 30min to gelatinize the starch;
[0031] (3) Lower the temperature to 70°C, add dropwise 10ml of the prepared silver nitrate solution into the three-necked flask, and continuously stir for 10 minutes;
[0032] (4) Add 2ml of the prepared sodium citrate solution dropwise at a rate of 1 drop / s, and stir to make it fully react;
[0033] (5) After the color of the reaction system no longer changes, that is, after the reaction is sufficient, the prepared sol is taken out from the reaction ...
Embodiment 2
[0038] The first step is the preparation of nano-silver coated with modified starch, and its preparation steps and process are the same as in Example 1.
[0039] The second step is to prepare nano-silver three-proof antibacterial finishing agent according to the optimization results of each component, as follows: (1) according to nano-silver sol: HS1100:ATB9800:TPM9007=0.3:7:2:3, weigh 3g of nano-silver sol , HS1100 three-proof finishing agent 70g, ATB9800 antibacterial finishing agent 20g, TPM9007 antibacterial finishing agent 30g (total liquid weight 1000g)
[0040] (2) First place 70g of HS1100 three-proof finishing agent in a three-necked flask with stirring, then gradually add 3g of nano-silver sol, 20g of ATB9800 antibacterial finishing agent, 30g of TPM9007 antibacterial finishing agent, and add water to a total liquid weight of 1000g.
[0041] (3) Stir the compounded three antibacterial agent at normal temperature and pressure for 10 minutes until it is uniform.
Embodiment 3
[0043] The first step is the preparation of nano-silver coated with modified starch, and its preparation steps and process are the same as in Example 1.
[0044] The second step is to prepare nano-silver three-proof antibacterial finishing agent according to the optimization results of each component, as follows: (1) according to nano-silver sol: HS1100:ATB9800:TPM9007=0.4:8:3:3, weigh 4g of nano-silver sol , HS1100 three-proof finishing agent 80g, ATB9800 antibacterial finishing agent 30g, TPM9007 antibacterial finishing agent 30g (total liquid weight 1000g)
[0045] (2) First place 80g of HS1100 three-proof finishing agent in a three-necked flask with stirring, then gradually add 4g of nano-silver sol, 30g of ATB9800 antibacterial finishing agent, 30g of TPM9007 antibacterial finishing agent, and add water to a total liquid weight of 1000g.
[0046] (3) Stir the compounded three antibacterial agent at normal temperature and pressure for 10 minutes until it is uniform.
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