A method for advanced treatment of sewage after ozone reflux secondary oxidation
A technology of ozone oxidation and secondary oxidation, applied in the direction of oxidized water/sewage treatment, multi-stage water/sewage treatment, degassed water/sewage treatment, etc. Membrane difficulties, high investment and operating costs, etc., to achieve the effect of low construction and operating costs, efficient and stable operation, and flexible operation
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Embodiment 1
[0024] The raw water sample for the pilot test is the effluent from the secondary settling tank of the sewage treatment plant of a refining and chemical enterprise. The water quality and quantity are as follows:
[0025]
[0026] Raw water first enters the former ozone oxidation tank B, stays for 45min, and the ozone produced by the ozone generator A is added to the former ozone oxidation tank B through the ozone dosing pipeline 2, and the ozone dosage is 2kgO 3 / kgCOD, the COD removal rate of ozone oxidation before control is 35%. The effluent from the front ozone oxidation pool B enters the BAF pool C through channels, and the filtration rate of the BAF pool is controlled at 4m / h. Take 25%, 50%, 75%, 100% respectively, stay for 45min, and then add 2kgO 3 / kgCOD, the COD removal rate of ozone oxidation after control is 35%. The effluent from the ozone oxidation tank E is sent back to the BAF tank C for further processing.
[0027] The COD removal rate of the whole proce...
Embodiment 2
[0032] Guarantee that other conditions are constant among the embodiment 1, rear ozone dosage is 2.5kgO 3 / kgCOD, the COD removal rate of ozone oxidation after control is 50%.
[0033] The COD removal rate of the whole process sewage is as follows:
[0034]
[0035] When the reflux ratio is 25%, 50%, 75%, and 100%, the highest COD removal rate of the whole process is 61%, 64.5%, 67.2%, and 69.3%.
[0036] When the COD removal rate of post-ozone oxidation is increased, the total COD removal rate of the overall process is significantly improved. Similarly, the higher the reflux ratio, the higher the COD removal rate.
Embodiment 3
[0038] Keep other conditions unchanged in Example 1, cancel the rear ozone oxidation pool E, and part of the sewage in the clear water pool directly returns to the front ozone oxidation pool B.
[0039] The COD removal rate of the whole process sewage is as follows:
[0040]
[0041] When the reflux ratio is 25%, 50%, 75%, and 100%, the highest COD removal rate of the whole process is 61%, 63%, 64%, and 64.8%.
[0042] When the total ozone dosage is the same, it has the same effect as in Example 1 when only increasing the reflux without the post-ozone oxidation pool.
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