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Polythiophene/organic micro-crystal muscovite conductive mineral material and preparing method thereof

A technology for microcrystalline muscovite and mineral materials, applied in the field of functional mineral materials, can solve the problems of toxic organic solvents, decreased material conductivity, personnel and air pollution, etc., and achieves mild implementation conditions, improved material conductivity, and increased interlayer spacing. improved effect

Active Publication Date: 2016-07-13
CHENGDU UNIVERSITY OF TECHNOLOGY
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional compounding of thiophene and silicate is mostly thiophene derivatives. With the deepening of research, researchers have found that thiophene derivatives increase the steric hindrance due to the introduction of substituents, which indirectly leads to the fact that thiophene polymerization often shows no order, leading to a decrease in the conductivity of the material; on the other hand, organic solvents are toxic, and most of the chloroform after the reaction evaporates, causing serious pollution to personnel and air.

Method used

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preparation example Construction

[0040] The preparation method of polythiophene / organic microcrystalline muscovite conductive mineral material of the present invention comprises the steps:

[0041] a. Dissolve 6-10 parts by weight of organic microcrystalline muscovite and 1-5 parts by weight of emulsifier in water, and stir at a constant temperature of 55-65°C to obtain a milky dispersion solution;

[0042] b. Add 3 to 30 parts by weight of thiophene to the milky dispersion solution and stir;

[0043] c. Cool down to 15-25°C and continue stirring;

[0044] d. Add 0.15 to 0.7 parts by weight of ferric chloride hexahydrate, stir and fully react;

[0045] f. Add 1 to 8 parts by weight of calcium chloride, break the emulsion with ethanol, let it stand for discharging, filter and wash;

[0046] g. Vacuum drying at 60-70°C to constant weight, grinding and refining to obtain the polythiophene / organic microcrystalline muscovite conductive mineral material.

[0047] Further, as a more preferred technical solution, ...

Embodiment 1

[0073] a, Weigh 20.0002g microcrystalline muscovite, add to 100ml6mol / L of HN0 3 In the solution, stir at a constant temperature of 85°C for 6h, let it stand for cooling and filter, filter and wash several times, vacuum-dry at 60°C, and grind to obtain acidified microcrystalline muscovite (K1).

[0074] b. Weigh 15.004g of the above K1, 90.120g of LiNO 3 Grind and mix evenly, place in a tube furnace at 400°C for 5 hours, let stand to cool, wash and filter several times, vacuum-dry at 60°C, and grind to obtain Lithified microcrystalline muscovite (K2).

[0075] c. Weigh 3.004g of the above-mentioned K2 and dissolve it in an appropriate amount of deionized water, add 0.4387g of hexadecyltrimethylammonium bromide, stir at a constant temperature of 80°C for 6h, let it stand for cooling, wash and filter several times until there is no Br - (0.1mol / LAgNO 3 Solution detection, until there is no white precipitate), take it out and grind it to obtain the modified organic microcrystal...

Embodiment 2

[0079] a. Weigh 3.002 g of microcrystalline muscovite after ligation in Example 1 and dissolve it in an appropriate amount of deionized water, add 1.231 g of hexadecyltrimethylammonium bromide, stir at a constant temperature of 80° C. for 6 h, let it stand for cooling, and then Wash and filter until no Br - (0.1mol / LAgNO 3 Solution detection, until there is no white precipitate), take it out and grind it, which is the modified organic microcrystalline muscovite.

[0080] b. Weigh 0.9008g of the organic microcrystalline muscovite obtained in the above step a and dissolve it in 40ml of deionized water, add 0.1805g of SDBS, stir vigorously at 60°C for 1h, pipette 0.45mlTP into the reaction solution, and continue stirring vigorously for 2h; cool down to room temperature, weigh 0.0214gFeCl 3 ·6H 2 O was dissolved in 5ml deionized water, and FeCl was slowly added dropwise 3 Solution, continue to react for 12 hours; stop stirring, add 25ml of absolute ethanol, 0.3134g of anhydrou...

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Abstract

The invention relates to a polythiophene / organic micro-crystal muscovite conductive mineral material and a preparing method thereof and belongs to the field of functional mineral materials.The preparing method comprises the steps of a, dissolving organic micro-crystal muscovite and an emulgator in water and conducting stirring to obtain an emulsus dispersion solution; b, adding thiophene to the emulsus dispersion solution and conducting stirring; c, conducting cooling and continuing stirring; d, adding ferric trichloride, and conducting stirring for sufficient reaction; f, adding calcium chloride and ethyl alcohol for demulsification, conducting standing and discharging, and conducting filtration and washing; g, conducting vacuum drying to a constant weight, and conducting grinding and refining to obtain the polythiophene / organic micro-crystal muscovite conductive mineral material.The polythiophene / organic micro-crystal muscovite conductive mineral material prepared with the method has a high conversion rate and high conductivity, thermal stability is improved, and the process is simple and environmentally friendly.

Description

technical field [0001] The invention relates to a polythiophene / organic microcrystalline muscovite conductive mineral material and a preparation method thereof, belonging to the field of functional mineral materials. Background technique [0002] Functional materials are the core of the new material research field and the foundation and guide of national economy, social development and national defense construction. It involves information technology, energy technology, environmental protection technology and other modern high-tech. In the development and application of functional materials, some new inorganic / organic and organic / inorganic functional mineral materials with excellent performance and even the ability to collect other substances have been developed rapidly. Among them, conductive mineral materials are one of them, which make minerals conductive and can be used in antistatic agents, conductive agents, conductive coatings, conductive plastics, long-term anti-cor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G61/12C08K3/34C08L65/00
CPCC08G61/126C08G2261/3223C08K3/34C08K2201/001C08L2201/08C08L65/00
Inventor 龙剑平凌英杨梅张文涛舒朝著
Owner CHENGDU UNIVERSITY OF TECHNOLOGY
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