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Glass ceramic with unique optical property and preparation method thereof

A technology of optical properties and glass-ceramics, which is applied in glass manufacturing equipment, glass furnace equipment, glass molding, etc., can solve the problems of lower thermal efficiency, lack of combination of applications, and failure to meet the entire area through transmission.

Inactive Publication Date: 2016-07-27
温州市康尔微晶器皿有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Infrared waves have the highest heating efficiency. Since the transmittance of the vanadium-free glass-ceramics in the infrared region will decrease after measurement, the thermal efficiency will be reduced and the energy consumption will be increased when the glass-ceramics is applied to the cooker; and the glass-ceramics Can only pass through blue and red LEDs, and use Fe 2+ 、Co 2+ , N i2+ As a coloring agent, its transmission in the visible light region cannot satisfy the entire region, it appears monotonous, lacks a combination of applications, and has certain limitations

Method used

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  • Glass ceramic with unique optical property and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A black glass-ceramic with unique optical properties, the composition of which is by weight percentage:

[0037] Li 2 O4.2%, Al 2 o 3 23%, SiO 2 62.2%, Na 2 O0.6%, K 2 O0.6%, MgO1.4%, ZnO2%, P 2 o 5 1.47%, TiO 2 3.25%, ZrO 2 0.8%, SnO 2 0.25%, MnO 2 0.05%, V 2 o 5 0.06%, Fe 2 o 3 0.12%.

[0038] A kind of preparation method of described black glass-ceramic with unique optical performance, comprises the steps:

[0039] a) mixing all the materials in proportion to form a mixture;

[0040] b) Add the mixture to an oxy-combustion kiln for calcining and melting. The temperature of the kiln is between 1650°C and 1680°C to form molten glass; calcining through an oxy-fuel combustion kiln can make the material more heated Uniformity, fast heating, and the formed glass liquid is uniform and stable.

[0041] c) The molten glass is cooled and homogenized in the working pool, and pressed into a glass plate with a thickness of 2mm-15mm by a calender at 1400°C-1450°C...

Embodiment 2

[0047] A black glass-ceramic with unique optical properties, the composition of which is by weight percentage:

[0048] Li 2 O3.95%, Al 2 o 3 21.4%, SiO 2 65.04%, Na 2 O0.1%, K 2 O0.1%, MgO0.43%, CaO0.5%, SrO0.4%, BaO1.05%, P 2 o 5 0.8%, TiO 2 4%, ZrO 2 1.5%, SnO 2 0.5%, V 2 o 5 0.08%, Fe 2 o 3 0.15%.

[0049] A kind of preparation method of described black glass-ceramic with unique optical performance, comprises the steps:

[0050] a) mixing all the materials in proportion to form a mixture;

[0051] b) Adding the mixture to an oxy-fuel furnace for calcining and melting, the temperature of the furnace is between 1650°C and 1680°C to form molten glass;

[0052] c) cooling and homogenizing the molten glass through a working pool, and pressing it into a glass plate with a thickness of 2mm-15mm at 1400°C-1450°C with a calender;

[0053] d) subjecting the glass plate to annealing, cooling, and cutting procedures to make a glass original sheet;

[0054] e) Put the...

Embodiment 3

[0058] A black glass-ceramic with unique optical properties, the composition of which is by weight percentage:

[0059] Li 2 O3.2%, Al 2 o 3 19%, SiO 2 68%, Na 2 O0.6%, K 2 O0.25%, MgO0.3%, CaO0.35%, BaO1.35%, ZnO1%, P 2 o 5 1.5%, TiO 2 2.8%, ZrO 2 1.45%, SnO 2 0.1%, CoO0.02%, V 2 o 5 0.01%, Fe 2 o 3 0.07%.

[0060] A kind of preparation method of described black glass-ceramic with unique optical performance, comprises the steps:

[0061] a) mixing all the materials in proportion to form a mixture;

[0062] b) Adding the mixture to an oxy-fuel furnace for calcining and melting, the temperature of the furnace is between 1650°C and 1680°C to form molten glass;

[0063] c) cooling and homogenizing the molten glass through a working pool, and pressing it into a glass plate with a thickness of 2mm-15mm at 1400°C-1450°C with a calender;

[0064] d) subjecting the glass plate to annealing, cooling, and cutting procedures to make a glass original sheet;

[0065] e) P...

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Abstract

The invention relates to the field of glass production and particularly relates to glass ceramic with unique optical property and a preparation method thereof. In the invention, the content of V2O5, Fe2O3, CoO, MnO2, TiO2 and SiO2 can meet the requirements of transmission spectra, for example, a standard light source and far infrared rays are allowed to permeate; due to the component types of a coloring agent, the glass ceramic has perfect display ability for standard red LED or LEDs of other colors such as yellow, blue, green and white, and thus corresponding products like the color of a stove are enriched.

Description

technical field [0001] The invention relates to the field of glass manufacturing, in particular to a black glass-ceramic with unique optical properties and a preparation method thereof. Background technique [0002] Black glass-ceramic is widely used in induction cooker or cooker panels, and this glass-ceramic can generally be made into flat plates or other shapes. [0003] The production of these glass-ceramics is divided into several stages: [0004] Various raw materials are mixed according to a certain ratio and a certain amount of broken glass is added, and melted at 1600-1680 ° C. During the melting process, arsenic oxide or antimony oxide is generally used as a clarifier. These clarifiers ensure the melting quality of the glass and the crystallized glass. performance. [0005] The patent (CN104609733A) describes "a vanadium-free, arsenic-free and low-expansion glass-ceramic and its preparation method", using SnO 2 and CeO 2 As clarifying agent, Fe 2 o 3 , CoO, N...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C10/14C03B5/235C03B13/00C03B32/02
CPCC03C10/0009C03B5/2353C03B13/00C03B32/02
Inventor 陈明形章锦明
Owner 温州市康尔微晶器皿有限公司