Composition capable of obtaining self-healing cured product and self-healing coating film having the cured film
A composition and compound technology, applied in coatings, polyurea/polyurethane coatings, etc., can solve the problems of insufficient oil resistance and difficult adhesion of surface protective film, and achieve excellent self-healing, good self-healing, and oil resistance excellent effect
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Embodiment 1~6、 comparative example 1~6
[0124] The ingredients shown in the following Table 1 were blended according to the mixing ratio shown in the following Table 1, and mixed and dispersed at room temperature using a three-roll mill to prepare Examples 1-6 and Comparative Examples 1-6. Composition used. Using the test piece preparation process described later, the prepared composition was coated on a substrate to prepare a test piece. The compounding quantity of each component shown in the following Table 1 shows parts by mass unless otherwise specified, and the blank part shows not compounding.
[0125]
[0126] In addition, the details of each component in Table 1 are as follows.
[0127] (A) Polyol
[0128] ・PLACCEL 312: manufactured by DAICEL Co., Ltd., polycaprolactone triol (hydroxyl value=135 mgKOH / g)
[0129] · PLACCEL 308: manufactured by Daicel Co., Ltd., polycaprolactone triol (hydroxyl value=195 mgKOH / g)
[0130] ・PLACCEL 305: manufactured by DAICEL Co., Ltd., polycaprolactone triol (hydroxyl ...
Embodiment 7~12、 comparative example 7~8
[0177] The components shown in the following Table 3 were mixed according to the mixing ratio shown in the following Table 3, and were mixed and dispersed at room temperature using a three-roll mill to prepare Examples 7-12 and Comparative Examples 7-8. Composition used. In addition, the number of compounding in the following Table 3 shows a mass part, and a blank part shows not compounding.
[0178]
[0179] In addition, the details of the components in Table 3 are as follows.
[0180] (B) Aliphatic polyisocyanate and / or modified body of the aliphatic polyisocyanate
[0181] - DURANATE D201: A SAHIKASEI CHEMICALS Co., Ltd. product.
[0182] (G) Polydialkylsiloxane whose terminal is modified by hydroxyl group
[0183] · Silmer OH Di-10: manufactured by SILTECH Corporation.
[0184] - KF-9701: manufactured by Daicel Co., Ltd.
[0185] (H) UV absorber
[0186] · KEMISORB 113: CHEMIPRO Chemicals Co., Ltd. product.
[0187] Polyurethane Catalyst
[0188] - Zn-Octoate 22...
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