Graphene-modified natural latex polymer and modification method thereof

A graphene modification and natural latex technology, applied in the field of natural rubber compositions, can solve problems such as uneven dispersion of graphene, and achieve the effects of improved mechanical properties, easy large-scale production, and easy availability of raw materials

Active Publication Date: 2016-08-31
沈阳天地乳胶有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In view of this, the object of the present invention is to provide a kind of graphene modified natural latex pol

Method used

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  • Graphene-modified natural latex polymer and modification method thereof

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Example Embodiment

[0045] Example 1

[0046] Graphene modified natural latex polymer modification method of the present invention, comprises the steps:

[0047] 1) First, dissolve graphene oxide and a coupling agent with a mass percentage of 50% in absolute ethanol under continuous stirring, then add graphene oxide to form a uniform dispersion, heat to 80°C, and continue to react for 15 hours , the obtained pasty product was first washed with absolute ethanol to remove excess unreacted coupling agent, and then washed with distilled water, and the undried pasty product was dispersed in distilled water, added hydrazine hydrate, and heated at 100°C Under the reduction reaction for 6h, the added mass of the hydrazine hydrate is 3 times of the added mass of the graphene oxide; then the product obtained is washed with excess absolute ethanol and distilled water, and the modified functionalized graphene is obtained after drying; the functionalized The size of graphene is 200-800nm, and the thicknes...

Example Embodiment

[0062] Example 2

[0063] Graphene modified natural latex polymer modification method of the present invention, comprises the steps:

[0064] 1) First, dissolve graphene oxide and a coupling agent with a mass percentage of 2% in absolute ethanol under continuous stirring, then add graphene oxide to form a uniform dispersion, heat to 60°C, and continue to react for 24 hours , the obtained paste product was first washed with absolute ethanol to remove excess unreacted coupling agent, and then washed with distilled water, and the undried paste product was dispersed in distilled water, added hydrazine hydrate, and heated at 80°C Under the reduction reaction for 4h, the added quality of the hydrazine hydrate is 0.5 times of the added quality of the graphene oxide; then the product obtained is washed with excess absolute ethanol and distilled water, and the modified functionalized graphene is obtained after drying; functionalized The size of graphene is 200-800nm, and the thickn...

Example Embodiment

[0079] Example 3

[0080] Graphene modified natural latex polymer modification method of the present invention, comprises the steps:

[0081]1) First, dissolve graphene oxide and a coupling agent with a mass percentage of 100% in absolute ethanol under continuous stirring, then add graphene oxide to form a uniform dispersion, heat to 70°C, and continue to react for 10 hours , the obtained paste product was first washed with absolute ethanol to remove excess unreacted coupling agent, and then washed with distilled water, and the undried paste product was dispersed in distilled water, added hydrazine hydrate, and heated at 85°C Under the reduction reaction for 5h, the added quality of the hydrazine hydrate is 5 times of the added quality of the graphene oxide; then the product obtained is washed with excess absolute ethanol and distilled water, and the modified functionalized graphene is obtained after drying; functionalized The size of graphene is 200-800nm, and the thickne...

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Abstract

The invention discloses a graphene-modified natural latex polymer and a modification method thereof. The modification method comprises modifying graphene through a coupling agent, uniformly dispersing the modified functionalized graphene in natural rubber to obtain the graphene-modified natural latex polymer and the modification method solves the problem of nonuniform dispersion of graphene in natural rubber. The graphene-modified natural latex polymer improves mechanical properties by 20-200%, improves barrier properties and blocks various viruses. The modification method of the graphene-modified natural latex polymer utilizes easily available raw materials and easily realizes large scale production. The invention also discloses the graphene-modified natural latex polymer prepared through the modification method.

Description

Technical field [0001] The present invention is a composition technology field of natural rubber, which is specifically a graphene modified natural latex polymer and its modification method. Background technique [0002] Natural rubber has excellent comprehensive performance, the products have excellent elasticity, high strength, large elongation, small extension and smaller creep, etc., and have been widely used in the chemical industry.However, natural rubber cannot meet many practical needs in terms of physical mechanical properties such as pure glue hardness and stretch strength. It is urgently needed to improve its strength, abrasion resistance, anti -aging and other properties, and broaden its application field. [0003] Nano -material has special surface effects, small -sized effects, quantum size effects, and quantum tunnel effects. The composite material shows unique performance of mechanics, heat, optics, and electromagnetic science.In the rubber industry, the composite...

Claims

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Application Information

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IPC IPC(8): C08L7/00C08K13/06C08K9/06C08K3/04C08K3/28C08K3/22C08K3/32C08K5/13C08K3/06C08K5/39C08K5/40C08K5/42
CPCC08K3/04C08K3/06C08K3/22C08K3/28C08K3/32C08K5/13C08K5/39C08K5/40C08K5/42C08K9/06C08K13/06C08K2003/2296C08L7/00
Inventor 饶先花李朝龙潘长富高翾王强史浩飞
Owner 沈阳天地乳胶有限公司
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