Lightweight organic-inorganic composite heat insulation foam material and preparation method thereof
A foam material, composite thermal insulation technology, applied in nanotechnology, nanotechnology, nanotechnology and other directions for material and surface science, can solve the problems of reducing the porosity of polyurethane and the thermal insulation performance of polyurethane foam, so as to improve the thermal insulation performance, The effect of improving tensile strength and good thermal insulation performance
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Embodiment 1
[0036] A method for preparing an organic-inorganic composite thermal insulation foam material, comprising:
[0037] (1) Preparation of nano zeolite molecular sieve
[0038] After mixing water and tetrapropylamine and stirring evenly, add ethyl orthosilicate and stir at room temperature at a speed of 400r / min for 24h, after aging for 24h, add aluminum isopropoxide and continue stirring at a speed of 600r / min for 24h to obtain A sol containing silicon and aluminum, the molar mass ratio of ethyl orthosilicate, tetrapropylamine, water, and aluminum isopropoxide in the sol is 1:0.31:17.5:0.003, and the sol is subjected to microwave-assisted heating for 48 hours in sequence. Aging reaction, segmented hydrothermal crystallization reaction, vacuum filtration, washing, and drying at 110°C to obtain nano-zeolite molecular sieves with a particle size of 80-85nm; among them, the first hydrothermal crystallization temperature is 80°C, and the crystallization time is 90min ;The second hydrot...
Embodiment 2
[0052] A method for preparing an organic-inorganic composite thermal insulation foam material, comprising:
[0053] (1) Preparation of nano zeolite molecular sieve
[0054] After mixing water and tetrapropylamine and stirring evenly, add ethyl orthosilicate and stir at room temperature at a speed of 300r / min for 20h, after aging for 26h, add aluminum isopropoxide and continue stirring at a speed of 500r / min for 25h to obtain A sol containing silicon and aluminum, the molar mass ratio of ethyl orthosilicate, tetrapropylamine, water, and aluminum isopropoxide in the sol is 1:0.35:18.5:0.003, and the sol is subjected to microwave-assisted heating for 48 hours in sequence. Aging reaction, segmented hydrothermal crystallization reaction, vacuum filtration, washing, and drying at 110°C to obtain nano-zeolite molecular sieves with a particle size of 85-90nm; among them, the first stage hydrothermal crystallization temperature is 80°C, and the crystallization time is 90min ;The secon...
Embodiment 3
[0068] A method for preparing an organic-inorganic composite thermal insulation foam material, comprising:
[0069] (1) Preparation of nano zeolite molecular sieve
[0070] After mixing water and tetrapropylamine and stirring evenly, add ethyl orthosilicate and stir at room temperature at a speed of 500r / min for 28h, after aging for 22h, add aluminum isopropoxide and continue stirring at a speed of 700r / min for 26h to obtain A sol containing silicon and aluminum, the molar mass ratio of ethyl orthosilicate, tetrapropylamine, water, and aluminum isopropoxide in the sol is 1:0.3:17.5:0.004, and the sol is subjected to microwave-assisted heating for 48 hours in sequence. Aging reaction, segmented hydrothermal crystallization reaction, vacuum filtration, washing, and drying at 110°C to obtain nano-zeolite molecular sieves with a particle size of 90-95nm; among them, the first hydrothermal crystallization temperature is 80°C, and the crystallization time is 90min ;The second hydro...
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Abstract
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