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Lightweight organic-inorganic composite heat insulation foam material and preparation method thereof

A foam material, composite thermal insulation technology, applied in nanotechnology, nanotechnology, nanotechnology and other directions for material and surface science, can solve the problems of reducing the porosity of polyurethane and the thermal insulation performance of polyurethane foam, so as to improve the thermal insulation performance, The effect of improving tensile strength and good thermal insulation performance

Inactive Publication Date: 2016-09-28
中山市泰源包装材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, after adding modified materials, although the compressive strength of polyurethane foam is improved, the porosity of polyurethane is reduced at the same time, which makes the thermal insulation performance of polyurethane foam decrease.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A method for preparing an organic-inorganic composite thermal insulation foam material, comprising:

[0037] (1) Preparation of nano zeolite molecular sieve

[0038] After mixing water and tetrapropylamine and stirring evenly, add ethyl orthosilicate and stir at room temperature at a speed of 400r / min for 24h, after aging for 24h, add aluminum isopropoxide and continue stirring at a speed of 600r / min for 24h to obtain A sol containing silicon and aluminum, the molar mass ratio of ethyl orthosilicate, tetrapropylamine, water, and aluminum isopropoxide in the sol is 1:0.31:17.5:0.003, and the sol is subjected to microwave-assisted heating for 48 hours in sequence. Aging reaction, segmented hydrothermal crystallization reaction, vacuum filtration, washing, and drying at 110°C to obtain nano-zeolite molecular sieves with a particle size of 80-85nm; among them, the first hydrothermal crystallization temperature is 80°C, and the crystallization time is 90min ;The second hydrot...

Embodiment 2

[0052] A method for preparing an organic-inorganic composite thermal insulation foam material, comprising:

[0053] (1) Preparation of nano zeolite molecular sieve

[0054] After mixing water and tetrapropylamine and stirring evenly, add ethyl orthosilicate and stir at room temperature at a speed of 300r / min for 20h, after aging for 26h, add aluminum isopropoxide and continue stirring at a speed of 500r / min for 25h to obtain A sol containing silicon and aluminum, the molar mass ratio of ethyl orthosilicate, tetrapropylamine, water, and aluminum isopropoxide in the sol is 1:0.35:18.5:0.003, and the sol is subjected to microwave-assisted heating for 48 hours in sequence. Aging reaction, segmented hydrothermal crystallization reaction, vacuum filtration, washing, and drying at 110°C to obtain nano-zeolite molecular sieves with a particle size of 85-90nm; among them, the first stage hydrothermal crystallization temperature is 80°C, and the crystallization time is 90min ;The secon...

Embodiment 3

[0068] A method for preparing an organic-inorganic composite thermal insulation foam material, comprising:

[0069] (1) Preparation of nano zeolite molecular sieve

[0070] After mixing water and tetrapropylamine and stirring evenly, add ethyl orthosilicate and stir at room temperature at a speed of 500r / min for 28h, after aging for 22h, add aluminum isopropoxide and continue stirring at a speed of 700r / min for 26h to obtain A sol containing silicon and aluminum, the molar mass ratio of ethyl orthosilicate, tetrapropylamine, water, and aluminum isopropoxide in the sol is 1:0.3:17.5:0.004, and the sol is subjected to microwave-assisted heating for 48 hours in sequence. Aging reaction, segmented hydrothermal crystallization reaction, vacuum filtration, washing, and drying at 110°C to obtain nano-zeolite molecular sieves with a particle size of 90-95nm; among them, the first hydrothermal crystallization temperature is 80°C, and the crystallization time is 90min ;The second hydro...

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PUM

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Abstract

The invention discloses a lightweight organic-inorganic composite heat insulation foam material and a preparation method thereof. The composite heat insulation foam material is prepared through compounding 60-70 mass% of polyurethane foam, 10-20 mass% of nanometer zeolite-porous fiber composite aerogel, and the balance of modified meso-porous C-SiO2 nanospheres. The preparation method comprises the following steps: mixing above three substances, carrying out injection molding on the obtained mixture, carrying out swelling fixing on the injection molded mixture, demolding the obtained material, and post-curing the demolded material to obtain the organic-inorganic composite heat insulation foam material. The novel porous fiber composite aerogel is a polyurethane foam modifier, so the tensile strength of the polyurethane foam is improved, and the good heat insulation performance of the polyurethane foam material is ensured; and polyurethane is filled and modified with the modified meso-porous C-SiO2 nanospheres, so the heat insulation performance of the polyurethane foam is improved.

Description

technical field [0001] The invention relates to a light organic-inorganic composite thermal insulation foam material and a preparation method, which belongs to the technical field of composite functional materials and is suitable for the thermal insulation material of refrigerators. Background technique [0002] In recent years, the energy consumption of refrigerators accounts for more than 10% of the total energy consumption of households. For household refrigerators, the insulation of the box plays an important role. Early refrigerators usually used sponge, asbestos, etc. as insulation materials, but these materials did not have high heat insulation ability, which easily caused heat loss, resulting in high energy consumption of refrigerators, and because they were not waterproof, the insulation performance gradually lost during use. [0003] At present, the insulation material of domestic refrigerators is mainly rigid polyurethane foam material, and its thermal conductivit...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/08C08L1/04C08K3/34C08K3/36C08K7/26C08G18/48C08G18/66C01B39/04B82Y30/00C01B33/18C08G101/00
CPCC01B33/18C01B39/04C01P2004/32C01P2004/64C08G18/4837C08G18/6674C08G2101/00C08L75/08C08L1/04C08K3/34C08K3/36C08K7/26
Inventor 魏亮
Owner 中山市泰源包装材料有限公司
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