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Low-expansion-coefficient red transparent glass and preparation method thereof

A low expansion coefficient, transparent glass technology, applied in the field of glass preparation, can solve the problems of difficult to produce bubble glass, low alkali metal content, high temperature viscosity of glass, etc., and achieve the effect of improving coloring efficiency, uniform color and low expansion coefficient

Inactive Publication Date: 2016-11-23
欧小宇
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the SiO2-B2O3-Al2O3-Na2O system is the main method used in the production of glass with low thermal expansion coefficient and low refractive index. However, since SiO2 and Al2O3 are refractory components, the alkali metal content must be very low to make the expansion coefficient low, resulting in The high-temperature viscosity of glass is very high, and it is difficult to produce glass with quality indicators such as bubbles and streaks that meet the standard

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] A red transparent glass with a low expansion coefficient, its weight percent composition is: SiO2: 58%, Al2O3: 8%, B2O3: 13%, MgO: 8%, K2O: 1.5%, Li2O: 0.5%, CeO2: 3%, TiO2: 4%, ZnO: 2.5%, BaO: 0.5%, Cu2O: 1%.

[0014] A preparation method of low expansion coefficient red transparent glass, which is carried out according to the following steps: (1) pulverizing the raw materials of low expansion coefficient red transparent glass; (2) carrying out batching according to the formula of low expansion coefficient red transparent glass, The order of adding raw materials during batching is SiO2, Al2O3, B2O3, BaO, MgO, ZnO, K2O, Li2O, CeO2, TiO2, Cu2O; (2) Use V-type mixer to mix the ingredients; (3) Put the batching materials into the pre- The heater is preheated, and the preheating temperature is 460°C; (4) The preheated batch material is melted at 1540°C for 23 hours to obtain a high-temperature molten glass; (6) The high-temperature molten glass is cooled to 1320°C; (7) The...

Embodiment 2

[0016] A red transparent glass with a low expansion coefficient, its weight percent composition is: SiO2: 61%, Al2O3: 5%, B2O3: 16%, MgO: 5%, K2O: 0.8%, Li2O: 1.2%, CeO2: 2.5%, TiO2: 3.5%, ZnO: 2%, BaO: 1.5%, Cu2O: 1.5%.

[0017] A preparation method of low expansion coefficient red transparent glass, which is carried out according to the following steps: (1) pulverizing the raw materials of low expansion coefficient red transparent glass; (2) carrying out batching according to the formula of low expansion coefficient red transparent glass, The order of adding raw materials during batching is SiO2, Al2O3, B2O3, BaO, MgO, ZnO, K2O, Li2O, CeO2, TiO2, Cu2O; (2) Use V-type mixer to mix the ingredients; (3) Put the batching materials into the pre- The heater is preheated, and the preheating temperature is 490°C; (4) the preheated batch is melted at 1600°C for 22 hours to obtain a high-temperature molten glass; (6) the high-temperature molten glass is cooled to 1330°C; (7) The mold...

Embodiment 3

[0019] A red transparent glass with a low expansion coefficient, its weight percent composition is: SiO2: 59%, Al2O3: 7%, B2O3: 15%, MgO: 7%, K2O: 0.5%, Li2O: 1%, CeO2: 1%, TiO2: 1%, ZnO: 4%, BaO: 2.5%, Cu2O: 2%.

[0020] A preparation method of low expansion coefficient red transparent glass, which is carried out according to the following steps: (1) pulverizing the raw materials of low expansion coefficient red transparent glass; (2) carrying out batching according to the formula of low expansion coefficient red transparent glass, The order of adding raw materials during batching is SiO2, Al2O3, B2O3, BaO, MgO, ZnO, K2O, Li2O, CeO2, TiO2, Cu2O; (2) Use V-type mixer to mix the ingredients; (3) Put the batching materials into the pre- The heater is preheated, and the preheating temperature is 540°C; (4) the preheated batch is melted at 1640°C for 21 hours to obtain a high-temperature molten glass; (6) the high-temperature molten glass is cooled to 1360°C; (7) using The mold e...

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PUM

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Abstract

The invention discloses low-expansion-coefficient red transparent glass and a preparation method thereof. The low-expansion-coefficient red transparent glass is prepared from the following ingredients in percentage by weight: 58 to 61 percent of SiO2, 5 to 8 percent of Al2O3, 13 to 16 percent of B2O3, 5 to 8 percent of MgO, 0.5 to 1.5 percent of K2O, 0.5 to 1.5 percent of Li2O, 1 to 3 percent of CeO2, 1 to 4 percent of TiO2, 2 to 4 percent of ZnO, 0.5 to 2.5 percent of BaO and 1 to 2 percent of Cu2O. The preparation method comprises the following preparation steps of raw material crushing treatment, material proportioning, mixing, preheating, melting, cooling, pressing forming, annealing, fine grinding, inspection, drying, packaging and warehouse entering. Raw materials are subjected to crushing processing, so that the fineness is high; according to the preparation method, the preheating is performed, so that the coloring efficiency is improved; the prepared glass does not have stripes; the color is uniform; the expansion coefficient is low.

Description

technical field [0001] The invention relates to the technical field of glass preparation, in particular to a red transparent glass with a low expansion coefficient and a preparation method thereof. Background technique [0002] Objects expand and contract due to temperature changes. As the temperature rises, the amplitude of the thermal motion of the particles in the glass increases, the distance between the particles becomes larger, and the external performance is expansion. However, the increase of particle spacing must overcome the force between particles. For oxide glass, this force is the bond force 2z / r2 between various cations and oxygen ions. The greater the bond force, the greater the glass expansion. Difficult, the smaller the coefficient of thermal expansion; conversely, the greater the coefficient of thermal expansion of glass; the bond strength of the Si-O bond is greater, so quartz glass has a small coefficient of thermal expansion. [0003] Cuprous oxide is ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C4/02C03C3/095
CPCC03C4/02C03C3/095
Inventor 欧小宇
Owner 欧小宇