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Preparation method of quartz glass and quartz glass

A technology of quartz glass and compounds, applied in glass manufacturing equipment, glass molding, manufacturing tools, etc., can solve problems such as failure to meet semiconductor application requirements, fast corrosion rate, corrosion, etc.

Active Publication Date: 2019-02-19
CHINA BUILDING MATERIALS ACAD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Si-O chemical bonds are easily corroded by hydrofluoric acid. According to calculations, in the hydrofluoric acid environment, the corrosion rate of quartz glass composed entirely of Si-O chemical bonds has reached 150 μm / h. The corrosion rate is faster in hydrofluoric acid environment, which cannot meet the application requirements of semiconductor etching in hydrofluoric acid environment

Method used

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  • Preparation method of quartz glass and quartz glass
  • Preparation method of quartz glass and quartz glass
  • Preparation method of quartz glass and quartz glass

Examples

Experimental program
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Effect test

preparation example Construction

[0061] Such as figure 1 As shown, an embodiment of the present invention provides a method for preparing quartz glass, which includes:

[0062] Step 10. The first doping compound and the second doping compound are dissolved and mixed with a dissolving agent to form a doping mixed solution. The first doping compound is an aluminum-containing compound, and the second doping compound includes a Zr-containing compound, At least one of Y-containing compounds, La-containing compounds, Sc-containing compounds, Th-containing compounds, V-containing compounds, and Ti-containing compounds;

[0063] Wherein, the dissolving agent may be a kind of dissolving agent, which can dissolve the first doping compound and the second doping compound at the same time; or, the dissolving agent may include two dissolving agents, and one dissolving agent is used to dissolve the first doping compound. Doping compound, another dissolving agent is used to dissolve the second doping compound to form the doping m...

Embodiment approach

[0112] 1. Vacuum electric melting process melting method:

[0113] The crystalline doped silica powder is ground, and the ground doped silica powder is sieved to obtain the sieved silica powder. The silicon dioxide powder is melted into the quartz glass product at 1000-2500 degrees Celsius using a melting process, specifically:

[0114] The doped silica powder after grinding is sieved to obtain the doped silica powder with particles of 20-200 mesh, and the doped silica powder with 20-200 mesh is melted by vacuum electric melting process The finished quartz glass.

[0115] 2. High-frequency plasma melting process melting method:

[0116] The crystalline doped silica powder is ground, and the ground doped silica powder is sieved to obtain the sieved silica powder. The silicon dioxide powder is melted into the quartz glass product at 1000-2500 degrees Celsius using a melting process, specifically:

[0117] The ground doped silica powder is sieved to obtain the doped silica powder with a...

Embodiment 2

[0132] A quartz glass provided by an embodiment of the present invention includes:

[0133] Quartz glass product, prepared by the method for preparing the quartz glass product;

[0134] The method for preparing the quartz glass includes:

[0135] The first doping compound and the second doping compound are dissolved and mixed with a dissolving agent to form a doping mixed solution, the first doping compound is an aluminum-containing compound, and the second doping compound includes a Zr-containing compound and a Y-containing compound , At least one of La-containing compounds, Sc-containing compounds, Th-containing compounds, V-containing compounds, and Ti-containing compounds;

[0136] Volume parts L 1 Of silicon alkoxide, parts by volume L 2 Of water, volume L 3 Mixed with alcohol organic solvents to form silicon alkoxide solution;

[0137] The silicon alkoxide solution, the doped mixed solution and the catalyst are subjected to hydrolysis and polycondensation reaction to prepare dope...

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Abstract

The invention relates to quartz glass and a preparation method thereof, relates to the technical field of quartz glass manufacture, and mainly aims to improve corrosion resistance of quartz glass finished products under the environments containing fluorine such as hydrofluoric acid and fluorine gas F2. The method includes the steps: dissolving and mixing first doping compounds and second doping compounds by the aid of dissolving agents to form doping mixed solution; performing hydrolysis condensation reaction for silanol saline solution, the doping mixed solution and catalyst to obtain doping silica gel; firing the doping silica gel to prepare the quartz glass finished products. The first doping compounds are compounds containing aluminum, quartz glass finished products contain Al2O3 and at least one in ZrO2, Y2O3, La2O3, Sc2O3, ThO2, V2O5 and TiO2, and the doping mixed solution is fired into the Al2O3, the ZrO2, the Y2O3, the La2O3, the Sc2O3, the ThO2, the V2O5 and the TiO2. Holes in a tetrahedron network structure of SiO2 are filled with the Al2O3, the ZrO2, the Y2O3, the La2O3, the Sc2O3, the ThO2, the V2O5 and the TiO2 by the aid of a network middle body or a network outside body, and the quartz glass is resistant in acid corrosion.

Description

Technical field [0001] The invention relates to the technical field of quartz glass manufacturing, in particular to a method for preparing quartz glass and quartz glass. Background technique [0002] Quartz glass is an amorphous material with silicon dioxide as the main component. Its microstructure is a simple network composed of silicon dioxide tetrahedral structural units. Since the Si-O chemical bond energy is large and the structure is very tight, Quartz glass has unique properties, such as high temperature resistance, low expansion coefficient, thermal shock resistance, high chemical stability and good electrical insulation properties. [0003] Due to the unique properties of quartz glass, it is an irreplaceable ideal auxiliary material for the semiconductor integrated circuit manufacturing process, including quartz glass tube, quartz glass sheet, quartz glass ring, quartz glass plate, quartz glass flange, quartz glass groove boat, Quartz glass cleaning tank and other device...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C3/06C03C1/02C03C6/08C03B20/00
CPCC03B19/066C03C1/026C03C3/06C03C2201/36
Inventor 聂兰舰向在奎贾亚男王蕾邵竹锋王慧张辰阳符博王玉芬
Owner CHINA BUILDING MATERIALS ACAD