Method and application of preparing supported palladium carbon catalyst by self-polymerization of dopamine
A supported palladium and carbon catalyst technology, applied in electrochemical generators, fuel cells, structural parts, etc., can solve the problems of cumbersome steps and inconsistencies, and achieve the effects of simple preparation method, simple operation and few steps.
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Embodiment 1
[0031] 1. Preparation of supported palladium carbon catalyst
[0032] Prepare 0.05 mol / L Tris-HCl (pH 8.5) solution and 50 mmol / L K 2 PdCl 4 solution, ready for use; weigh 0.095 g of dopamine hydrochloride powder and dissolve it with 10 mL of prepared Tris-HCl solution; add 0.25 mL of prepared K 2 PdCl 4 After mixing the solution thoroughly, leave it open at room temperature; after reacting for 24 hours, centrifuge the black product and dry it in an oven at 40°C for 12 hours; keep the collected product in an inert atmosphere at 600°C for 2 h; after cooling, the product is collected to obtain a supported palladium-carbon catalyst, which is denoted as Pd / C(PDA)-1. As determined by ICP-OES, the content of Pd in the synthesized catalyst was 1.3 wt%.
[0033] figure 1 It is a flow chart for the preparation of the supported palladium-carbon catalyst proposed by the present invention. Using DA as a carbon source, the palladium precursor is reduced to palladium metal particles...
Embodiment 2
[0043] 1. Preparation of supported palladium carbon catalyst
[0044] Prepare 0.05 mol / L Tris-HCl (pH 8.5) solution and 50 mmol / L K 2 PdCl 4 solution, ready for use; weigh 0.095 g of dopamine hydrochloride powder and dissolve it with 10 mL of prepared Tris-HCl solution; add 0.50 mL of prepared K 2 PdCl 4 After mixing the solution thoroughly, leave it open at room temperature; after reacting for 24 hours, centrifuge the black product and dry it in an oven at 40°C for 12 hours; keep the collected product in an inert atmosphere at 600°C for 2 h; after cooling, the product is collected to obtain a supported palladium-carbon catalyst, which is denoted as Pd / C(PDA)-2. As determined by ICP-OES, the content of Pd in the synthesized catalyst was 2.1 wt%.
[0045] 2. Electrocatalytic oxidation of methanol in alkaline environment
[0046] Weigh 5 mg of catalyst and put it in 4 mL of Nafion solution (0.2 wt%), after ultrasonic mixing for 30 min, add 50 μL dropwise on the surface of...
Embodiment 3
[0048] 1. Preparation of supported palladium carbon catalyst
[0049] Prepare 0.05 mol / L Tris-HCl (pH 8.5) solution and 50 mmol / L K 2 PdCl 4 solution, ready for use; weigh 0.095 g of dopamine hydrochloride powder and dissolve it with 10 mL of prepared Tris-HCl solution; add 1.00 mL of prepared K 2 PdCl 4 After mixing the solution thoroughly, leave it open at room temperature; after reacting for 24 hours, centrifuge the black product and dry it in an oven at 40°C for 12 hours; keep the collected product in an inert atmosphere at 600°C for 2 h; after cooling, the product is collected to obtain a supported palladium-carbon catalyst, which is denoted as Pd / C(PDA)-3. As determined by ICP-OES, the content of Pd in the synthesized catalyst was 3.7 wt%.
[0050] 2. Electrocatalytic oxidation of methanol in alkaline environment
[0051] Weigh 5 mg of catalyst and put it in 4 mL of Nafion solution (0.2 wt%), after ultrasonic mixing for 30 min, add 50 μL dropwise on the surface of...
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