Preparation and application of novel environment-friendly foaming PVC specific uracil zinc composite stabilizer

A composite stabilizer, the technology of zinc uracil is applied in the field of preparation of a new type of environmental protection foamed PVC special uracil zinc composite stabilizer, which can solve the problems of production workers and the environment, high toxicity, poor thermal stabilization effect, etc.

Inactive Publication Date: 2017-02-22
SHENZHEN AIMSEA IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] PVC heat stabilizer is a kind of compound that can inhibit the thermal degradation of PVC resin. It is an indispensable additive in PVC molding formula; before a suitable heat stabilizer is developed, PVC is still a kind of material with no practical value. The development of stabilizer technology can drive the improvement of PVC processing performance and product performance; the more commonly used heat stabilizers in the PVC industry include lead salts, organotin, metal soaps, rare earths and calcium zinc stabilizers; lead salts Stabilizer is the most commonly used heat stabilizer for PVC. It is cheap and has good thermal stability, but it is highly toxic and harmful to production workers and the environment. In recent years, the consumption has shown a downward trend; since organic stabilizers do not contain met...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Step 1, the preparation of zinc uracil;

[0034] Based on the quality of the total reactant, zinc uracil is prepared according to the following formula:

[0035] Uracil 100 parts

[0036] Phase transfer catalyst 2 parts

[0037] 520 parts of water

[0038] 260 parts of concentrated ammonia water

[0039] Zinc nitrate 160 parts

[0040] 210 parts of isopropanol

[0041] Add uracil and water into the 2L three-necked flask according to the above ratio, stir and heat to 50°C until the uracil is completely dissolved, then add concentrated ammonia water and phase transfer catalyst into the reaction kettle in sequence according to the above ratio, and after the dispersion is uniform, proceed Add zinc nitrate and isopropanol to this solution once, and continue to stir and react at this temperature for 2 h; The obtained product is dried in a vacuum oven, and finally dried and ground to obtain uracil zinc metal salt.

[0042] Step 2, compounding reaction;

[0043] Based o...

Embodiment 2

[0067] Step 1, the preparation of zinc uracil;

[0068] Based on the quality of the total reactant, zinc uracil is prepared according to the following formula:

[0069] Uracil 100 parts

[0070] 1.7 parts of phase transfer catalyst

[0071] 490 parts of water

[0072] 240 parts of concentrated ammonia water

[0073] Zinc nitrate 140 parts

[0074] 190 parts of isopropanol

[0075] Add uracil and water into the 2L three-necked flask according to the above ratio, stir and heat to 50°C until the uracil is completely dissolved, then add concentrated ammonia water and phase transfer catalyst into the reaction kettle in sequence according to the above ratio, and after the dispersion is uniform, proceed Add zinc nitrate and isopropanol to this solution for the second time, and continue to stir and react at this temperature for 2 h; after the reaction is completed, cool down to room temperature and take out the reaction mixture; Dry in a vacuum oven to obtain the product. Final...

Embodiment 3

[0101] Step 1, the preparation of zinc uracil;

[0102] Based on the quality of the total reactant, zinc uracil is prepared according to the following formula:

[0103] Uracil 100 parts

[0104] Phase transfer catalyst 1.5 parts

[0105] 460 parts of water

[0106] Concentrated ammonia water 220 parts

[0107] Zinc nitrate 120 parts

[0108] 170 parts of isopropanol

[0109] Add uracil and water into the 2L three-necked flask according to the above ratio, stir and heat to 50°C until the uracil is completely dissolved, then add concentrated ammonia water and phase transfer catalyst into the reaction kettle in sequence according to the above ratio, and after the dispersion is uniform, proceed Add zinc nitrate and isopropanol to this solution once, and continue to stir and react at this temperature for 2 h; The obtained product is dried in a vacuum oven, and finally dried and ground to obtain uracil zinc metal salt.

[0110] Step 2, compounding reaction;

[0111] Based on...

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PUM

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Abstract

The invention relates to the technical field of a chemical stabilizer, and particularly discloses a preparation and an application of the novel environment-friendly foaming PVC specific uracil zinc composite stabilizer. The uracil zinc composite stabilizer is prepared by compounding uracil metal salt by uracil and zinc nitrate under the catalyst condition; according to the setting formula, compounding hydrotalcite, antioxygen, lubricant, zinc stearate and assistant thermal stabilizer and uracil zinc metal salt, and preparing uracil zinc composite thermal stabilizer. The uracil zinc composite stabilizer can replace lead cadmium salt type poisonous stabilizer, and has good compatibility and dispersibility with PVC (polyvinyl chloride); moreover, the composite stabilizer has relatively good thermal stability, light stability and coloring force. Compared with ordinary zinc stearate, the zinc content is improved, and the stabilizer has very good effect of inhibiting zinc burning; the ageing performance in later period and the sunproof weather resistance are significantly improved; the foaming PVC industry has wide application prospect.

Description

technical field [0001] The invention relates to the technical field of chemical stabilizers, and specifically designs the preparation and application of a novel environment-friendly foamed PVC special-purpose uracil-zinc composite stabilizer. Background technique [0002] Foamed plastics, also known as porous plastics, are resin-based plastics filled with countless tiny cell structures; polyvinyl chloride (PVC) foamed plastics are widely used in insulating materials and daily-use materials due to their low price and excellent performance. Plastic products, compared with other foam plastics, PVC foam plastic itself has better flame retardancy, and is widely used in furniture, construction, automobile, advertising, decoration and other industries; in developed countries such as the United States, France, Germany, Switzerland and Korea In China, PVC foam is widely used in wall partition materials, and has achieved very considerable environmental effects and economic benefits; i...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08K13/02C08K5/3462C08K5/098C08K3/26C08J9/10C08J9/08C07D239/54
CPCC08K13/02C07D239/54C08J9/08C08J9/103C08J2203/02C08J2203/04C08J2203/18C08J2327/06C08K3/26C08K5/098C08K5/3462C08L2201/08C08L2203/14C08L27/06
Inventor 严一丰严晴周国庆张显范修强肖阳生高金奎翟华伟杨光龙喜香
Owner SHENZHEN AIMSEA IND
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