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High-fire-resistant rigid polyurethane foam external wall insulation material and preparation method thereof

A technology of polyurethane rigid foam and external wall thermal insulation is applied in the field of external wall thermal insulation materials, which can solve the problems of conflict between fire and flame retardant properties and mechanical properties, and achieve the effects of excellent mechanical properties and high flame retardant properties.

Inactive Publication Date: 2017-03-15
合肥广能新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of the main problems existing in the combination of polyurethane rigid foam insulation systems at home and abroad, combined with the current research progress of polyurethane rigid foam fire and flame retardant technology, polyurethane insulation materials have reached the national standard B1 or higher fire protection level, and the single addition of flame retardant technology The problem cannot be solved, and there is a problem that the fire-proof and flame-retardant properties of polyurethane rigid foam insulation materials are contradictory with the mechanical properties. The present invention proposes a high-flame-retardant polyurethane rigid foam external wall insulation material. excellent mechanical properties

Method used

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  • High-fire-resistant rigid polyurethane foam external wall insulation material and preparation method thereof
  • High-fire-resistant rigid polyurethane foam external wall insulation material and preparation method thereof

Examples

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Effect test

Embodiment 1

[0021] A highly flame-retardant polyurethane rigid foam external wall insulation material, which consists of component A and component B. Calculated in parts by weight, component A consists of 1 part of chlorinated polypropylene resin, 4 parts of brominated epoxy resin, Composed of 60 parts of polyether polyol, 7 parts of vitrified microspheres, 1 part of dibutyltin laurate, 15 parts of dimethyl methyl phosphate, 1 part of polyether modified organosiloxane and 15 parts of foaming agent, group B Divided into polyphenyl polymethylene polyisocyanate, the foaming agent is composed of 1 part of pentane, 6 parts of pentafluoropentane and 4 parts of dichloroethane. The mixing weight ratio of A component and B component is 1:1.

[0022] The preparation method comprises the following steps: premixing chlorinated polypropylene resin, brominated epoxy resin, polyether polyol, ethylene dichloride and pentafluoropentane, and simultaneously adding vitrified microbeads and polyether modified...

Embodiment 2

[0024] A highly flame-retardant polyurethane rigid foam external wall insulation material, composed of component A and component B, calculated in parts by weight, component A consists of 2 parts of chlorinated polypropylene resin, 10 parts of brominated epoxy resin, 70 parts of polyether polyol, 5 parts of vitrified microspheres, 2 parts of stannous octoate, 24 parts of tris(2-chloroethyl) phosphate, 2 parts of polyether modified organosiloxane and 24 parts of foaming agent , Component B is polyphenyl polymethylene polyisocyanate, and the blowing agent is composed of 3 parts of pentane, 9 parts of pentafluoropentane and 2 parts of dichloroethane. The mixing weight ratio of component A and component B is 1:1.4.

[0025] The preparation method comprises the following steps: premixing chlorinated polypropylene resin, brominated epoxy resin, polyether polyol, ethylene dichloride and pentafluoropentane, and simultaneously adding vitrified microbeads and polyether modified silicone ...

Embodiment 3

[0027] A highly flame-retardant polyurethane rigid foam external wall insulation material, which consists of component A and component B. Calculated in parts by weight, component A consists of 4 parts of chlorinated polypropylene resin, 16 parts of brominated epoxy resin, Composed of 80 parts of polyether polyol, 10 parts of vitrified microspheres, 4 parts of dioctyltin diacetate, 30 parts of tribromoneopentyl alcohol, 3 parts of polyether modified organosiloxane and 30 parts of foaming agent, component B It is polyphenyl polymethylene polyisocyanate, and the foaming agent is composed of 5 parts of pentane, 12 parts of pentafluoropentane and 6 parts of dichloroethane. The mixing weight ratio of component A to component B is 1:1.8.

[0028] The preparation method comprises the following steps: premixing chlorinated polypropylene resin, brominated epoxy resin, polyether polyol, ethylene dichloride and pentafluoropentane, and simultaneously adding vitrified microbeads and polyeth...

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Abstract

The invention provides a high-fire-resistant rigid polyurethane foam external wall insulation material and a preparation method thereof. The high-fire-resistant rigid polyurethane foam external wall insulation material comprises a component A and a component B. The component A comprises, by weight, 1-4 parts of chlorinated polypropylene resin, 4-16 parts of brominated epoxy resin, 60-80 parts of polyether polyol, 5-10 parts of glass beads, 1-4 parts of catalysts, 15-30 parts of fire retardants, 1-3 parts of stabilizers and 15-30 parts of foaming agents. The component B comprises polyphenyl polymethylene polyisocyanate. The foaming agents comprise 1-5 parts of pentane, 6-12 parts of amyl pentafluoride and 2-6 parts of dichloroethane. The fire resistance of the insulation material is improved while excellent mechanical property is kept.

Description

technical field [0001] The invention belongs to the technical field of thermal insulation materials for external walls, and in particular relates to a high flame-retardant polyurethane rigid foam thermal insulation material for external walls and a preparation method thereof. Background technique [0002] The organic insulation materials currently used on a large scale in my country's building energy conservation mainly include EPS (polystyrene foam), PS (extruded polystyrene foam) and PU (polyurethane foam), all of which are flammable organic insulation materials. The biggest advantage is the quality Lightweight, good heat preservation and heat insulation; the biggest defect is poor fire safety, easy aging, and easy burning. If these new building energy-saving materials have not been modified by the chemical structure of flame retardant and smoke reduction, if they are simply added with flame retardants, there will be serious fire hazards, leading to frequent building fire a...

Claims

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Application Information

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IPC IPC(8): C08L75/08C08L23/28C08K7/20C08K5/521C08J9/14C08G18/48C08G18/58C08G18/30C08G101/00
CPCC08G18/2885C08G18/4045C08G18/482C08G18/582C08J9/141C08J9/145C08J9/146C08J2203/14C08J2203/142C08J2203/202C08J2205/10C08J2375/08C08K2201/014C08L75/08C08L2201/02C08G2110/0025C08L23/28C08K7/20C08K5/521
Inventor 刘涛
Owner 合肥广能新材料科技有限公司
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