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A kind of preparation method and application of lithium ion battery porous negative electrode material

A lithium-ion battery and negative electrode material technology, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of low material porosity, high material cost, complex process, etc., achieve high capacity, simple pore-making process, and process simple effect

Inactive Publication Date: 2019-05-17
TIANJIN UNIVERSITY OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The purpose of the present invention is to address the above existing problems and provide a preparation method and application of a porous negative electrode material for lithium ion batteries. The method utilizes the characteristics of low solid solubility of metal germanium and tin, and combines dealloying methods to prepare porous germanium and porous tin. The double-skeleton structure formed together, this double-skeleton structure is used as the negative electrode material of lithium-ion batteries, exhibits high capacitance and cycle performance, and has the characteristics of low material cost, simple preparation process, and short process cycle, which overcomes the existing Disadvantages such as complicated technical process, long production cycle, high energy consumption, high material cost, low output, and low material porosity

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  • A kind of preparation method and application of lithium ion battery porous negative electrode material
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Embodiment 1

[0029] A preparation method of a lithium-ion battery porous negative electrode material, the steps are as follows:

[0030] 1) Preparation of Ge-Sn-Al alloy ingot

[0031] According to the target alloy composition Ge 15 sn 15 Al 70 (atomic ratio), the germanium block with a purity of 99.99%, the tin block with a purity of 99.99%, and the aluminum block with a purity of 99.99% are prepared as raw materials. When preparing materials, the amount of raw materials is multiplied by a correction factor to reduce the composition deviation caused by the burning loss during alloy smelting. According to the test results of burning loss obtained by the inventor through a large number of experiments, the correction coefficients are 1.01 for germanium, 1.16 for tin, and 1.05 for aluminum. The weighed raw materials are smelted by arc melting method, and the vacuum degree of the materials is pumped to 2.5×10 -3 Pa, the argon gas with a purity of 99.999% is introduced to -0.05MPa, and the...

Embodiment 2

[0040] A preparation method of a lithium-ion battery porous negative electrode material, the steps are as follows:

[0041] 1) Preparation of Ge-Sn-Al alloy ingot

[0042] According to the target alloy composition Ge 10 sn 10 Al 80 (atomic ratio), the germanium block of 99.99% purity, the tin block of 99.99% purity, and the aluminum block of 99.99% purity are prepared as raw materials. When preparing materials, the amount of raw materials is multiplied by a correction factor to reduce the composition deviation caused by the burning loss during alloy smelting. According to the test results of burning loss obtained by the inventor through a large number of experiments, the correction coefficients are 1.01 for germanium, 1.16 for tin, and 1.05 for aluminum. The weighed raw materials are smelted by arc melting method, and the vacuum degree of the materials is pumped to 2.5×10 -3 Pa, the argon gas with a purity of 99.999% is introduced to -0.05MPa, and the arc melting starts. ...

Embodiment 3

[0051] A preparation method of a lithium-ion battery porous negative electrode material, the steps are as follows:

[0052] 1) Preparation of Ge-Sn-Al alloy ingot

[0053] According to the target alloy composition Ge 12.5 sn 12.5 Al 75 (atomic ratio), the germanium block of 99.99% purity, the tin block of 99.99% purity, and the aluminum block of 99.99% purity are prepared as raw materials. When preparing materials, the amount of raw materials is multiplied by a correction factor to reduce the composition deviation caused by the burning loss during alloy smelting. According to the test results of burning loss obtained by the inventor through a large number of experiments, the correction coefficients are 1.01 for germanium, 1.16 for tin, and 1.05 for aluminum. The weighed raw materials are smelted by arc melting method, and the vacuum degree of the materials is pumped to 2.5×10 -3 Pa, the argon gas with a purity of 99.999% is introduced to -0.05MPa, and the arc melting star...

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Abstract

The invention provides a preparation method of a porous negative electrode material for a lithium-ion battery. Germanium and tin in a precursor alloy are designed at an equal atomic ratio, and the composition ratio of a precursor and dealloying process parameters are provided and controlled to prepare a porous double-skeleton negative electrode material formed by entangling a porous germanium skeleton and a porous tin skeleton. The method has the advantages that the negative electrode material for the lithium-ion battery is a double-skeleton nano porous material, and is high in porosity and small in hole pitch, the diffusion distances of lithium ions are shortened, the problem of volume expansion of the negative electrode material in the cycle process is greatly solved and the rate capability and the cycling stability of the battery are improved; the negative electrode material plays a synergistic contribution role in the performance of the battery in the cycle process, high cost caused by individual use of germanium is reduced, and meanwhile, the performance of the battery is kept stable in a high-capacity region; and the process is simple, the method can be carried out at a room temperature, complicated equipment is not needed, the overall production cycle is short and the output is high.

Description

technical field [0001] The invention relates to the field of preparation of negative electrode materials for lithium ion batteries, in particular to a preparation method and application of porous negative electrode materials for lithium ion batteries. Background technique [0002] Environmental pollution and energy crisis have seriously restricted the rapid development of human society, and vigorously developing new energy technologies has reached a worldwide consensus. The development of new high-performance energy storage devices is an effective way to efficiently utilize new energy technologies. Lithium-ion battery is a new type of energy storage device developed in recent years. Compared with traditional secondary batteries, it has outstanding advantages, such as high working voltage, large specific energy, and long cycle life. It plays a huge role in devices such as batteries. In the development of electrode materials for lithium-ion batteries, the development of high...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/38H01M4/46H01M4/36H01M10/0525H01M4/134
CPCH01M4/134H01M4/36H01M4/38H01M4/387H01M4/46H01M10/0525Y02E60/10
Inventor 王志峰刘喜正安翠华丁轶
Owner TIANJIN UNIVERSITY OF TECHNOLOGY