HAA solidified polyester resin for sand streak powder coating and preparation method thereof
A technology of powder coating and polyester resin, which is applied in the field of polyester resin, can solve the problems of insufficient unevenness of texture, insufficient mechanical properties, and high gloss of sand grains, and achieve strong unevenness, excellent mechanical properties, and low surface gloss Effect
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[0025] Some specific examples are enumerated below to illustrate the present invention, and Table 1 shows the examples and comparative examples of polyester resins. In the reactor, add neopentyl glycol, methylpropanediol, 1,4-cyclohexanedimethanol, trimethylolpropane, and trimethylolethane in proportions listed in Table 1, and heat up to the Melt; then add terephthalic acid, monobutyl dihydroxy tin chloride, continue to heat up the reaction with nitrogen, until 180 ° C esterification water begins to form and distill; then gradually increase the temperature to 245 ° C, and react for 9 to 13 hours to More than 95% of the esterification water is discharged. At this time, the material system is clear and transparent, and the acid value reaches 18-23mgKOH / g; the temperature is lowered to 230°C, and the acidolysis agent is added in a proportioned amount, and the reaction is 2-4 hours. At this time, the material system is clear Transparent, the acid value reaches 32-38 mgKOH / g; after...
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