Catalytic cracking catalyst containing y molecular sieve and preparation method thereof
A catalytic cracking and molecular sieve technology, which is applied in the direction of molecular sieve catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the problems such as the influence of unstudied active component Y-type molecular sieve particles on the dispersion degree, and achieve the effect of high activity
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Embodiment 1
[0063] A kind of preparation method of highly dispersed NaY molecular sieve catalytic cracking catalyst
[0064] (1) Preparation of guiding agent: Take 28.4g of sodium hydroxide (Beijing Chemical Plant, industrial grade) and add it to 66.9g of water, stir until the sodium hydroxide is completely dissolved, then add 4.7g of sodium metaaluminate (Beijing Chemical Plant, industrial grade) grade), continue to stir until the sodium metaaluminate is completely dissolved to obtain sodium metaaluminate solution A (Al 2 o 3 The content is 22wt.%, Na 2 O content is 3 wt.%). Get the water glass of the solution A of 38.2g and 82g (Beijing Red Star Soda Soda Factory, SiO 2 Content 27.81wt.%, Na 2 O content 8.74wt.%) were mixed and stirred evenly, after stirring for 2 hours, aged at 20°C for 72 hours. Based on 100wt.% of the directing agent, the molar ratio of each component is: 19Na 2 O: Al 2 o 3 :34SiO 2 :550H 2 O.
[0065] (2) Preparation of NaY molecular sieve: Dissolve 75.5g...
Embodiment 2
[0071] Unless otherwise specified, the source of each raw material is the same as in Example 1.
[0072] (1) Preparation of guiding agent: Take 38.7g of sodium hydroxide and add it to 33.2g of water, stir until the sodium hydroxide is completely dissolved, then add 17.3g of sodium metaaluminate, and continue stirring until the sodium metaaluminate is completely dissolved to obtain metaaluminum Sodium acid solution A (Al 2 o 3 The content is 11wt.%, Na 2 O content is 30 wt.%). Take 12g of solution A and 56g of water glass, mix and stir evenly, add 14.9g of sodium hydroxide and 39g of water, stir for 2h, then age at 50°C for 0.2h. Based on 100wt.% of the directing agent, the molar ratio of each component is: 25Na 2 O: Al 2 o 3 :20SiO2 2 :350H 2 O.
[0073] (2) Preparation of NaY molecular sieve: Dissolve 37.7g of aluminum sulfate in 162.3g of water to form Al 2 o 3 Content is 3wt.% aluminum sulfate solution B; Dissolve 46.5g sodium hydroxide in 122.1g water, add 31.5g...
Embodiment 3
[0079] Unless otherwise specified, the source of each raw material is the same as in Example 1.
[0080] (1) Preparation of guiding agent: Take 25.8g of sodium hydroxide and add it to 64.8g of water, stir until the sodium hydroxide is completely dissolved, then add 9.4g of sodium metaaluminate, and continue stirring until the sodium metaaluminate is completely dissolved to obtain metaaluminum Sodium acid solution A (Al 2 o 3 The content is 6wt.%, Na 2 O content is 20 wt.%). Take 22g of solution A and 45g of water glass, mix and stir evenly, add 3.5g of sodium hydroxide and 72.1g of water, stir for 2h, then age at 30°C for 36h. Based on 100wt.% of the directing agent, the molar ratio of each component is: 25Na 2 O: Al 2 o 3 :16SiO2 2 :220H 2 O.
[0081] (2) Preparation of NaY molecular sieve: Dissolve 37.7g of aluminum sulfate in 62.3g of water to form Al 2 o 3 Content is the aluminum sulfate solution B of 6wt.%; Dissolve 19.4g sodium hydroxide in 7.9g water, add 72....
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