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Catalytic cracking catalyst containing y molecular sieve and preparation method thereof

A catalytic cracking and molecular sieve technology, which is applied in the direction of molecular sieve catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the problems such as the influence of unstudied active component Y-type molecular sieve particles on the dispersion degree, and achieve the effect of high activity

Active Publication Date: 2019-06-11
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, none of the above patents has studied the effect of the particle size and degree of particle dispersion of the active component Y-type molecular sieve in the catalytic cracking catalyst on its catalytic cracking reaction performance.

Method used

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  • Catalytic cracking catalyst containing y molecular sieve and preparation method thereof
  • Catalytic cracking catalyst containing y molecular sieve and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0063] A kind of preparation method of highly dispersed NaY molecular sieve catalytic cracking catalyst

[0064] (1) Preparation of guiding agent: Take 28.4g of sodium hydroxide (Beijing Chemical Plant, industrial grade) and add it to 66.9g of water, stir until the sodium hydroxide is completely dissolved, then add 4.7g of sodium metaaluminate (Beijing Chemical Plant, industrial grade) grade), continue to stir until the sodium metaaluminate is completely dissolved to obtain sodium metaaluminate solution A (Al 2 o 3 The content is 22wt.%, Na 2 O content is 3 wt.%). Get the water glass of the solution A of 38.2g and 82g (Beijing Red Star Soda Soda Factory, SiO 2 Content 27.81wt.%, Na 2 O content 8.74wt.%) were mixed and stirred evenly, after stirring for 2 hours, aged at 20°C for 72 hours. Based on 100wt.% of the directing agent, the molar ratio of each component is: 19Na 2 O: Al 2 o 3 :34SiO 2 :550H 2 O.

[0065] (2) Preparation of NaY molecular sieve: Dissolve 75.5g...

Embodiment 2

[0071] Unless otherwise specified, the source of each raw material is the same as in Example 1.

[0072] (1) Preparation of guiding agent: Take 38.7g of sodium hydroxide and add it to 33.2g of water, stir until the sodium hydroxide is completely dissolved, then add 17.3g of sodium metaaluminate, and continue stirring until the sodium metaaluminate is completely dissolved to obtain metaaluminum Sodium acid solution A (Al 2 o 3 The content is 11wt.%, Na 2 O content is 30 wt.%). Take 12g of solution A and 56g of water glass, mix and stir evenly, add 14.9g of sodium hydroxide and 39g of water, stir for 2h, then age at 50°C for 0.2h. Based on 100wt.% of the directing agent, the molar ratio of each component is: 25Na 2 O: Al 2 o 3 :20SiO2 2 :350H 2 O.

[0073] (2) Preparation of NaY molecular sieve: Dissolve 37.7g of aluminum sulfate in 162.3g of water to form Al 2 o 3 Content is 3wt.% aluminum sulfate solution B; Dissolve 46.5g sodium hydroxide in 122.1g water, add 31.5g...

Embodiment 3

[0079] Unless otherwise specified, the source of each raw material is the same as in Example 1.

[0080] (1) Preparation of guiding agent: Take 25.8g of sodium hydroxide and add it to 64.8g of water, stir until the sodium hydroxide is completely dissolved, then add 9.4g of sodium metaaluminate, and continue stirring until the sodium metaaluminate is completely dissolved to obtain metaaluminum Sodium acid solution A (Al 2 o 3 The content is 6wt.%, Na 2 O content is 20 wt.%). Take 22g of solution A and 45g of water glass, mix and stir evenly, add 3.5g of sodium hydroxide and 72.1g of water, stir for 2h, then age at 30°C for 36h. Based on 100wt.% of the directing agent, the molar ratio of each component is: 25Na 2 O: Al 2 o 3 :16SiO2 2 :220H 2 O.

[0081] (2) Preparation of NaY molecular sieve: Dissolve 37.7g of aluminum sulfate in 62.3g of water to form Al 2 o 3 Content is the aluminum sulfate solution B of 6wt.%; Dissolve 19.4g sodium hydroxide in 7.9g water, add 72....

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Abstract

The invention provides a catalytic cracking catalyst containing a Y molecular sieve. The catalytic cracking catalyst containing the Y molecular sieve comprises the following components: an H-type Y molecular sieve, kaolin and an aluminum sol component; and on the basis of taking the H-type Y molecular sieve as an active component and the total weight of the catalyst, the content of the H-type Y molecular sieve is 15 to 50 percent by weight, the content of the kaolin is 40 to 60 percent by weight and the content of the aluminum sol based on Al2O3 is 10 to 25 percent by weight. The invention also provides a preparation method of the catalytic cracking catalyst containing the Y molecular sieve. When the used Y molecular sieve is prepared, a certain amount of surfactant is added into the final synthesis mixture. By adoption of the method provided by the invention, the catalytic cracking catalyst containing the high-dispersibility small-grain-size Y molecular sieve can be obtained efficiently and conveniently. Compared with the prior art, the catalytic cracking catalyst has higher catalytic activity.

Description

technical field [0001] The invention relates to a catalytic cracking catalyst containing Y molecular sieve and a preparation method thereof, in particular to a catalytic cracking catalyst containing highly dispersed Y molecular sieve and a preparation method thereof. Background technique [0002] Molecular sieves have been widely used as catalytic cracking catalysts, especially in petroleum refining and petrochemical applications. Molecular sieves, aluminum silicate, and aluminum oxide are often used as catalysts in acid-catalyzed reactions such as catalytic cracking, isomerization, and alkylation in the petroleum industry. The structural characteristics of molecular sieve determine its catalytic performance. Molecular sieve has special structural properties such as regular crystal structure, large specific surface area, uniform micropore structure, good ion exchange performance and non-skeleton components existing in the crystal structure. , making molecular sieves widely ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B39/24B01J29/08
Inventor 庞新梅刘百军王更更沈宜泓尹延超邢昕苗译文赵俊郭成玉
Owner PETROCHINA CO LTD