Selective near-infrared light response shape memory polymer composite material and preparation method thereof
A near-infrared light-responsive, memory polymer technology, applied in chemical instruments and methods, compounds containing elements of Group 3/13 of the periodic table, and organic compounds of Group 3/13 without C-metal bonds, etc. Nanoparticles are expensive, complicated in preparation process, and cannot be widely used, so as to achieve the effect of promoting application, improving dispersibility, and improving photothermal effect.
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[0042] The preparation method of rare earth organic complex includes the following steps:
[0043] S1: Dissolve A mol rare earth chloride in 10mL-10L ethanol to generate a rare earth chloride solution; if the carboxylic acid organic ligand is liquid at room temperature, directly use B mol carboxylic acid organic ligand as the first reagent ; If the carboxylic acid organic ligand is not liquid at room temperature, dissolve B mol carboxylic acid organic ligand in 10mL-10L ethanol to generate a carboxylic acid organic ligand solution and use it as the first reagent; if conjugated If the organic ligand is liquid at room temperature, directly use C mol conjugated organic ligand as the second reagent; if the conjugated organic ligand is not liquid at room temperature, dissolve C mol conjugated organic ligand in In 10mL-10L ethanol, a conjugated organic ligand solution is generated and used as the second reagent; the ranges of A, B and C are all 0.001 to 1;
[0044] S2: Into a three-neck...
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[0049] Example 1:
[0050] Example 1 discloses the rare earth ytterbium organic complex Yb (TTA) 3 Phen and rare earth neodymium organic complex Nd(TTA) 3 Phen as RN 4 Method for preparing selective near-infrared light-responsive photothermal filler. Among them, the organic complex of rare earth ytterbium selectively absorbs near infrared light at 980nm; the organic complex of rare earth neodymium selectively absorbs near infrared light at 808nm. Among them, α-thenoyl trifluoroacetone (TTA) and 1,10-phenanthroline (phen) are used as conjugated organic ligands N, n=4; carboxylic acid organic ligands M are not used.
[0051] Example 1 discloses Yb (TTA) 3 The preparation method of Phen includes the following steps:
[0052] S1.11: Add 10mmol YbCl 3 ·6H 2 O is dissolved in 30mL ethanol to generate YbCl 3 Solution; Dissolve 30mmol α-thenoyl trifluoroacetone in 50mL ethanol to produce a solution of α-thenoyl trifluoroacetone; dissolve 10mmol 1,10-phenanthroline in 30mL ethanol to produce...
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[0064] Example 2:
[0065] Example 2 discloses the rare earth ytterbium organic complex Yb (TTA) 3 Phen and rare earth neodymium organic complex Nd(TTA) 3 Phen as RN 4 Method for preparing selective near-infrared light-responsive photothermal filler. Among them, the organic complex of rare earth ytterbium selectively absorbs near infrared light at 980nm; the organic complex of rare earth neodymium selectively absorbs near infrared light at 808nm. Among them, α-thenoyl trifluoroacetone (TTA) and 1,10-phenanthroline (phen) are used as conjugated organic ligands N, n=4; carboxylic acid organic ligands M are not used.
[0066] Example 2 discloses Yb (TTA) 3 The preparation method of Phen includes the following steps:
[0067] S2.11: Add 10mmol YbCl 3 ·6H 2 O is dissolved in 30mL ethanol to generate YbCl 3 Solution; Dissolve 30mmol α-thenoyl trifluoroacetone in 50mL ethanol to produce a solution of α-thenoyl trifluoroacetone; dissolve 10mmol 1,10-phenanthroline in 30mL ethanol to produce...
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