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A novel ambient solar energy harvester based on sensitizing dyes

A technology of energy collectors and sensitizing dyes, which is applied in capacitors, photosensitive devices, electrolytic capacitors, etc., can solve the problem of small improvement in the photoelectric conversion efficiency of sensitized nanocrystalline solar cells, and achieve the goal of overcoming corrosion and improving photoelectric conversion efficiency and reduce manufacturing cost

Active Publication Date: 2019-01-18
UNIV OF ELECTRONICS SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] In order to overcome the problems in the background technology, the present invention proposes a novel ambient solar energy harvester based on sensitizing dyes, which uses graphene and TiO 2 Preparation of nanoporous semiconductors to solve the problem that the photoelectric conversion efficiency of dye-sensitized nanocrystalline solar cells is not greatly improved by the coating process, and the corrosion problem caused by using graphene as a catalyst instead of platinum as a counter electrode

Method used

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  • A novel ambient solar energy harvester based on sensitizing dyes
  • A novel ambient solar energy harvester based on sensitizing dyes
  • A novel ambient solar energy harvester based on sensitizing dyes

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Embodiment 1

[0034]The described novel ambient solar energy harvester based on sensitizing dyes includes a photoanode 3, a sensitizing dye layer 4, a redox electrolyte layer 5, and a counter electrode 6, and the photoanode 3 includes a conductive glass layer 1 and a nano Porous semiconductor layer 2; one side of the conductive glass layer 1 forms electrical contact with the nanoporous semiconductor layer 2, the lower surface of the conductive glass layer 1 is the nanoporous semiconductor layer 2, and the lower surface of the nanoporous semiconductor layer 2 is a sensitizing dye Layer 4, the lower surface of the sensitizing dye layer 4 is a redox electrolyte layer 5, the lower surface of the redox electrolyte layer 5 is a counter electrode 6, and the nanoporous semiconductor layer 2 is composed of graphene and TiO 2 Mix to prepare.

[0035] The thickness of the nanoporous semiconductor layer 2 is 40-50um, which can make the fabricated nanoporous semiconductor layer flat, firm in combination...

Embodiment 2

[0053] The described novel ambient solar energy harvester based on sensitizing dyes includes a photoanode 3, a sensitizing dye layer 4, a redox electrolyte layer 5, and a counter electrode 6, and the photoanode 3 includes a conductive glass layer 1 and a nano Porous semiconductor layer 2; one side of the conductive glass layer 1 forms electrical contact with the nanoporous semiconductor layer 2, the lower surface of the conductive glass layer 1 is the nanoporous semiconductor layer 2, and the lower surface of the nanoporous semiconductor layer 2 is a sensitizing dye layer 4, the lower surface of the sensitizing dye layer 4 is a redox electrolyte layer 5, and the lower surface of the redox electrolyte layer 5 is a counter electrode 6, and the counter electrode 6 is made of graphene.

[0054] The graphene used to prepare the counter electrode 6 is in the form of nanosheets, and the graphene nanosheets GNs stacked with multilayer graphene not only inherit the characteristics of gr...

Embodiment 3

[0070] Example 3 as figure 1 As shown, the described novel ambient solar energy harvester based on sensitizing dyes includes a photoanode 3, a sensitizing dye layer 4, a redox electrolyte layer 5, and a counter electrode 6, and the photoanode 3 includes a conductive glass layer 1 and a nanoporous semiconductor layer 2; one side of the conductive glass layer 1 forms electrical contact with the nanoporous semiconductor layer 2, and the lower surface of the conductive glass layer 1 is a nanoporous semiconductor layer 2, and the lower surface of the nanoporous semiconductor layer 2 is The sensitizing dye layer 4, the lower surface of the sensitizing dye layer 4 is a redox electrolyte layer 5, the lower surface of the redox electrolyte layer 5 is a counter electrode 6, and the lower surface of the redox electrolyte layer 5 is a counter electrode 6, and the The counter electrode 6 is made of graphene.

[0071] The graphene used to prepare the counter electrode 6 is in the form of n...

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Abstract

The invention relates to a sensitized dye-based novel environmental solar energy acquisition device, and belongs to the technical field of new energy saving. Electrical contact is formed between one surface of a conductive glass layer of a photo anode and one surface of a nanometer porous semiconductor layer of the photo anode, the nanometer porous semiconductor layer is arranged on a lower surface of the conductive glass layer, a sensitized dye layer is arranged on a lower surface of the nanometer porous semiconductor layer, an oxidation-reduction electrolyte layer is arranged on a lower surface of the sensitized dye layer, and a counter electrode is arranged on a lower surface of the oxidization-reduction electrolyte layer. By means of the advantages of high strength and high carrying capability of graphene, a nanometer porous semiconductor film is prepared from the graphene and TiO2 under a certain process condition, and the photoelectric conversion efficiency is improved; and moreover, Pt is substituted by the graphene to fabricate the counter electrode, so that the manufacturing cost of the dye-sensitized nanocrystal solar acquisition device is further reduced, and the stability of the dye-sensitized nanocrystal solar acquisition device is further improved.

Description

technical field [0001] The invention relates to the technical field of new energy and energy saving, in particular to a novel ambient solar energy collector based on sensitizing dyes. Background technique [0002] How to develop and utilize solar energy is one of the effective means to solve current energy problems. At present, solar cells are devices that can better convert solar energy into electrical energy, and the more promising solar cells have two systems. One is a silicon polycrystalline silicon semiconductor solid-state battery module, and the other is a dye-sensitized solar cell containing a liquid electrolyte. At present, the most mature solar cell is a silicon-based solar cell. The efficiency of a monocrystalline silicon solar cell has reached more than 25%, but it has high requirements on the purity of the material, complicated manufacturing process, and high cost, which greatly limits its wide application. application. Another dye-sensitized nanocrystalline ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G9/20
CPCH01G9/20H01G9/2022Y02E10/542Y02P70/50
Inventor 李晓宁吴婷婷易晶正宫大为刘洋叶小龙梁巍陈亮
Owner UNIV OF ELECTRONICS SCI & TECH OF CHINA
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