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A kind of methacrylate modified reactive resin

A technology of methacrylate and methacrylic acid, which is applied in the direction of coatings and anti-corrosion coatings, can solve the problems of reducing the toughness and impact resistance of coatings, the poor adhesion of substrates, and affecting the film-forming quality of coatings. Ease of promoting the effect of the application

Active Publication Date: 2019-07-02
LIAONING SANHUAN RESINS
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Experiments have proved that the patent's selection of vinyl chloride and ethyl acetate copolymers instead of methacrylate copolymers will make the coatings less compatible and less dispersible to special pigments such as carbon black, which affects the composition of the coatings. film quality
Another example is another patent CN101501085B of Evonik, Germany, which does not add corrosion-resistant and solvent-resistant monomer substances, so the coating made of this resin has poor corrosion resistance; in addition, more than 30% The mass proportion of methyl methacrylate, the experiment proves that although the resin share of methyl methacrylate exceeds 30%, although it will increase the rigidity of the coating, it will obviously reduce the toughness and impact resistance of the coating after film formation. The adhesion performance of the invented resin to the substrate is not outstanding

Method used

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  • A kind of methacrylate modified reactive resin
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Embodiment Construction

[0026] The resin of the present invention is made into a coating for road markings, and the commonly used two-component spraying equipment is used for road coating construction. That is to say, the road marking coating is formed by using the known construction technology of "cooperating in groups, spraying separately-mixing in the air-ground reaction, curing and forming a film".

[0027] The resin formulation of the present invention is divided into two groups of A and B for coordination, and the resins of A and B are made into two groups of coatings of A and B, wherein the resin of group A and the coating made contain accelerators, and the coating of group B is in the Just before spraying, add curing agent benzoyl peroxide, stir evenly and spray the two-component paint at the same time immediately, the accelerator in the A-component paint and the curing agent in the B-component paint are mixed in the air and redox reaction occurs on the ground , so that the methacrylate resin...

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Abstract

A methacrylate-modified reactive resin relates to methacrylate resins used in the production of road markings or floor coatings. Aiming at the deficiencies of the existing known technologies, the methacrylic resin is improved, and the formula composition of the resin is adjusted to realize the purpose that the produced coating has environmental protection performance and can improve the corrosion resistance and adhesion of the coating. The basic formula is composed as follows according to the percentage of mass share: 0.1-15% crosslinking agent 35-60% methacrylate monomer or a mixture of methacrylate monomer and acrylate monomer 0-40% can Copolymerized with methacrylate or acrylate monomers with corrosion resistance Other types of monomer substances 10-50% prepolymer 0.5-2% reaction stabilizer N-tert-butyl-a-phenylnitrone. 1-20% methacrylate-modified oligomer, 0-5% accelerator and other additives, the sum of the mass shares of each component is 100%. The prepared floor coatings are superior to the "China Road Marking Paint Standard" indicators in terms of physical and chemical properties such as water corrosion resistance, alkali corrosion resistance, abrasion resistance, adhesion, and impact resistance.

Description

technical field [0001] The present invention relates to methacrylate resins for the production of road markings or floor coatings. Background technique [0002] At present, my country's road marking or floor coatings can be divided into two categories, one is traditional oil-based coatings, and the other is water-based coatings. During the film-forming process of oil-based paint, a large amount of organic gas will be released to pollute the environment, and its use is now restricted. Although water-based coatings greatly reduce the release of organic gases, their aging resistance and corrosion resistance are far inferior to oil-based coatings, which reduces the functional quality of coatings. The technical key to how to solve the problem of environmental protection and maintain or improve the functional quality of coatings is to solve the performance of resin, the basic raw material for the composition and production of coatings. [0003] In order to improve the performanc...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D4/02C09D4/06C09D5/08C09D7/63C09D7/47
CPCC09D4/06C09D5/08C09D7/47C09D7/63
Inventor 李柏雨
Owner LIAONING SANHUAN RESINS
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