A method for improving optical performance by introducing auxiliary ions into modified Si film
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An optical performance and auxiliary technology, applied in the manufacture of electrical components, circuits, semiconductor/solid-state devices, etc., can solve the problems of low luminous efficiency, hindering thin films, and slow exciton fluorescence annihilation.
Inactive Publication Date: 2020-07-14
YUNNAN UNIV
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Problems solved by technology
The factors that hinder the application of defective Si thin films in the field of light emission are attributed to three aspects, namely, low luminous efficiency, slow exciton fluorescence annihilation speed, and weak luminescence stability in high temperature regions.
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Embodiment 1
[0018] The method of introducing auxiliary ions into the modified Si film to improve the optical properties described in this example specifically includes the following steps:
[0019] (1) Select the SOI sheet of the P-type Si film with the top crystal orientation of (100), and clean it with the RCA standard cleaning method;
[0020] (2) Use an ion implanter to first implant the Si + The ions were implanted into the SOI silicon film layer, and the incident direction of the ions was 7° from the surface normal of the SOI silicon film, and was carried out in a vacuum room temperature environment. + The ion implantation dose is 2×10 17 cm -2 , the injection energy is 70keV;
[0021] (3) Si + After the ion implantation is completed, the iron ions are implanted into the layer, and the implantation dose is 1×10 15 cm -2 , the injection energy is 70keV. The ion incident direction is 7° from the surface normal of the SOI silicon film, and the ion implantation process is carried...
Embodiment 2
[0024] Step (1), step (2), step (4) are the same as in Example 1;
[0025] The difference in step (3) is:
[0026] Si + After the ion implantation is completed, the iron ions are implanted into the layer, and the implantation dose is 5×10 15 cm -2 , the injection energy is 70keV.
Embodiment 3
[0028] Step (1), step (2), step (4) are the same as in Example 1;
[0029] The difference in step (3) is:
[0030] Si + After the ion implantation is completed, cobalt ions are implanted into the layer, and the implantation dose is 1×10 15 cm -2 , the injection energy is 70keV.
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Abstract
The present invention provides a method for improving optical performance by introducing auxiliary ions into a modified Si thin film and belongs to the semiconductor material light emission technical field. According to the method, based on a Si ion self-injecting technique and a rapid thermal annealing process, light emission defects or clusters are generated in a Si film on an SOI substrate. At first, a metal vapor vacuum arc ion source ion injecting machine is adopted to perform ion injection, Si ions and auxiliary ions are injected into an SOI sheet, the top layer of the SOI sheet is (100) crystal orientation P-type single-crystal Si with a thickness of 200 nm, the middle layer of the SOI sheet is SiO2 with a thickness of 375 nm, and the bottom layer of the SOI sheet is P-type single-crystal Si with a thickness of 6.75 microns; and a rapid annealing furnace is adopted to perform rapid annealing on the SOI sheet. The compound injection dose, energy and heating processing process of the auxiliary ions are adjusted, so that the auxiliary ions can be bonded with gap Si atoms, and therefore, exciton fluorescence inactivation energy on an intermediate band can be enhanced. With the method provided by the technical schemes of the invention adopted, the improvement of cluster light emission stability can be facilitated, and therefore, the optical performance of the SOI material can be improved. The method can be popularized in the near room-temperature SOI-LED device field in the aspect of semiconductor light emission materials.
Description
technical field [0001] The invention relates to a method for improving optical performance by introducing auxiliary ions into a modified Si film, in particular using ion implantation technology and rapid annealing technology to prepare silicon-based luminescent materials, belonging to the technical field of semiconductor material luminescence. Background technique [0002] In recent years, combining microelectronics and optoelectronics to develop silicon-based large-scale optoelectronic integration technology has become an inevitable development of information technology and a general consensus in the industry. Silicon is the best candidate material to realize optoelectronic-microelectronic integration engineering. Compared with other optoelectronic materials, silicon-based optoelectronic materials have the advantages of low cost, high reliability, and strong functional expansion, in addition to their easy compatibility and integration; . [0003] At present, there are two...
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