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Non-cross-linked gel plugging system

A non-cross-linking, gel technology, applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve the problems of poor plugging effect, low plugging success rate, and easy to dilute the plugging agent with water, etc.

Inactive Publication Date: 2017-07-07
SICHUAN GUANGYA POLYMER CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, because the plugging agent used is easy to be diluted by water, it is not easy to accumulate in the leakage layer, and it is not easy to form the slug required for plugging, so the plugging effect is not good, and the success rate of plugging is low.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] The non-crosslinked polymer is a binary copolymer of acrylamide and N-tetradecyl acrylamide (the molar ratio of the two is 95:5), and the molecular weight is 17.8 million. The experiment uses simulated brine with a total salinity of 1000 mg / L, and the simulated reservoir temperature is 45°C. Under this condition, the 1.0wt% non-crosslinked polymer dissolving time is 2 hours, and the static shear force of the gel product (currently used) is 47Pa for 1min when tested on a six-speed rotary viscometer; it is static for 4 hours at BrookfieldDV -Ⅲ The viscosity tested on the viscometer is 32740mPa.s, the solution can pick up; the breakthrough pressure gradient is 0.35MPa / m; its indoor aging stability 90d viscosity retention rate is 94.5%.

Embodiment 2

[0054] The non-crosslinked polymer is a terpolymer of acrylamide, octadecyl allyl ammonium bromide and AMPS (2-acrylamide-2-methylpropanesulfonic acid) (the molar ratio of the three is 98.5:0.5 :1), the molecular weight is 13.06 million. The experiment uses simulated brine with a total salinity of 1000 mg / L, and the simulated reservoir temperature is 65°C. Under these conditions, the dissolution time of the 3.2wt% non-crosslinked polymer is 2 hours. The static shear force of the gel product (currently used) is 96Pa for 1 min when tested on a six-speed rotational viscometer; it is static for 4 hours at Brookfield The viscosity tested on the DV-Ⅲ viscometer is 63730mPa.s, the solution can pick up; the breakthrough pressure gradient is 0.72MPa / m; its indoor aging stability 90d viscosity retention rate is 90.3%.

Embodiment 3

[0056] The non-crosslinked polymer is a binary copolymer of acrylamide and cetyl allyl ammonium bromide (the molar feed ratio of the two is 93:7), and the molecular weight is 5.63 million. The experiment uses simulated brine with a total salinity of 3200 mg / L, and the simulated reservoir temperature is 84°C. Under these conditions, the dissolution time of 4wt% non-crosslinked polymer is 3 hours, and the static shear force of the gel product (currently used) is 112Pa for 1 min when tested on a six-speed rotational viscometer; it is static for 4 hours at Brookfield DV -Ⅲ The viscosity tested on the viscometer is 70880mPa.s, the solution can pick up; the breakthrough pressure gradient is 0.76MPa / m; its indoor aging stability 90d viscosity retention rate is 84.2%.

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PUM

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Abstract

The invention provides a non-cross-linked gel plugging system which comprises a non-cross-linked polymer and an aqueous solution, wherein the mass of the non-cross-linked polymer is 0.5%-5.0% of the mass of the non-cross-linked gel plugging system. Compared with the prior art, the non-cross-linked polymer in the non-cross-linked gel plugging system provided by the invention can form a gel in the manner of physical cross-linking; the gel has difficulty in being mixed with oil, gas and water, has a better pumping performance, can easily enter into a crack and can automatically fix; the formation fluid can be fully discharged; the gel can effectively occupy and fill the seam and hole spaces of the underground leakage layer; a 'sectional plug' capable of fully isolating the formation fluid from the well hole is formed in the stratum, has a certain static yield stress and elasticity and is capable of regulating the starting pressure gradient; the gel plugging system provided by the invention can be independently used and can be used together with the other additives; different injection manners can be taken for solving various well leakage problems.

Description

Technical field [0001] The invention belongs to the field of petroleum exploitation, and specifically relates to a non-crosslinked gel plugging system. Background technique [0002] Lost circulation is a type of working fluids including mud, cement slurry, completion fluid and other fluids that leak into the formation under the action of pressure difference during special downhole operations such as drilling, cementing, testing or workover. Phenomenon is one of the most common and common technical problems in underground engineering. [0003] According to the leakage rate, leakage can be divided into micro leakage, small leakage, medium leakage, large leakage, and malignant leakage. Among them, malignant leakage is the most serious and difficult to solve. The malignant leakage of complex formations mainly includes: leakage of fractures with inflow and outflow, and repeated leakage at multiple points at random in low-pressure-bearing formations. Such leakage has a high rate of leak...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/44C09K8/46C08F220/56C08F220/54C08F226/02C08F220/58C08F226/10C04B28/00
CPCC04B28/00C08F220/56C09K8/44C09K8/46C09K2208/18C04B24/26C04B22/002C08F226/02C08F220/585
Inventor 郭拥军张新民许馨樊力胡俊
Owner SICHUAN GUANGYA POLYMER CHEM
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