Non-cross-linked gel plugging system
A non-cross-linking, gel technology, applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve the problems of poor plugging effect, low plugging success rate, and easy to dilute the plugging agent with water, etc.
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Embodiment 1
[0052] The non-crosslinked polymer is a binary copolymer of acrylamide and N-tetradecyl acrylamide (the molar ratio of the two is 95:5), and the molecular weight is 17.8 million. The experiment uses simulated brine with a total salinity of 1000 mg / L, and the simulated reservoir temperature is 45°C. Under this condition, the 1.0wt% non-crosslinked polymer dissolving time is 2 hours, and the static shear force of the gel product (currently used) is 47Pa for 1min when tested on a six-speed rotary viscometer; it is static for 4 hours at BrookfieldDV -Ⅲ The viscosity tested on the viscometer is 32740mPa.s, the solution can pick up; the breakthrough pressure gradient is 0.35MPa / m; its indoor aging stability 90d viscosity retention rate is 94.5%.
Embodiment 2
[0054] The non-crosslinked polymer is a terpolymer of acrylamide, octadecyl allyl ammonium bromide and AMPS (2-acrylamide-2-methylpropanesulfonic acid) (the molar ratio of the three is 98.5:0.5 :1), the molecular weight is 13.06 million. The experiment uses simulated brine with a total salinity of 1000 mg / L, and the simulated reservoir temperature is 65°C. Under these conditions, the dissolution time of the 3.2wt% non-crosslinked polymer is 2 hours. The static shear force of the gel product (currently used) is 96Pa for 1 min when tested on a six-speed rotational viscometer; it is static for 4 hours at Brookfield The viscosity tested on the DV-Ⅲ viscometer is 63730mPa.s, the solution can pick up; the breakthrough pressure gradient is 0.72MPa / m; its indoor aging stability 90d viscosity retention rate is 90.3%.
Embodiment 3
[0056] The non-crosslinked polymer is a binary copolymer of acrylamide and cetyl allyl ammonium bromide (the molar feed ratio of the two is 93:7), and the molecular weight is 5.63 million. The experiment uses simulated brine with a total salinity of 3200 mg / L, and the simulated reservoir temperature is 84°C. Under these conditions, the dissolution time of 4wt% non-crosslinked polymer is 3 hours, and the static shear force of the gel product (currently used) is 112Pa for 1 min when tested on a six-speed rotational viscometer; it is static for 4 hours at Brookfield DV -Ⅲ The viscosity tested on the viscometer is 70880mPa.s, the solution can pick up; the breakthrough pressure gradient is 0.76MPa / m; its indoor aging stability 90d viscosity retention rate is 84.2%.
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