A kind of polymer containing azacrown ether structure and its preparation method and application
An azacrown ether and polymer technology, which is applied in the field of anion exchange membranes containing azacrown ether structures and their preparation, can solve the problems that do not involve the research on azacrown ether polyphosphazene anion exchange membranes, etc. Excellent alkali stability, high ionic conductivity and excellent alkali resistance
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Embodiment 1
[0040] Take 6.14g of the hydroxy crown ether structure (z=1, m=3) represented by formula (2) and 1.2eq of sodium metal into 1,4-dioxane, heat to 60°C, and react for 24h. Then cool to room temperature, and suction filter to obtain a 1,4-dioxane solution of crown ether sodium salt;
[0041] Add the 1,4-dioxane solution of the above-mentioned crown ether sodium salt into a THF solution containing 23.2g of polydichlorophosphazene, and react at 60°C for 48h;
[0042] Add 33.44g of unsubstituted n-amyl alcohol and 1.2eq of metal sodium into THF, react at room temperature for 4h, and then filter with suction to obtain a THF solution of n-amyl alcohol sodium salt;
[0043] Add the obtained THF solution of fatty alcohol sodium salt into the above solution, continue to react for 24 h, then cool to room temperature, concentrate the obtained reaction solution to obtain a viscous liquid, wash with deionized water, and obtain a light yellow elastomer;
[0044] Dissolve the resulting elasto...
Embodiment 2
[0047]Take 18.42g of the hydroxy crown ether structure (z=1, m=3) represented by formula (2) and 1.2eq of sodium metal into 1,4-dioxane, heat to 60°C, and react for 24h. Then cool to room temperature, and suction filter to obtain a 1,4-dioxane solution of crown ether sodium salt;
[0048] Add the 1,4-dioxane solution of the above-mentioned crown ether sodium salt into a THF solution containing 23.2g of polydichlorophosphazene, and react at 60°C for 48h;
[0049] Add 29.92g of unsubstituted n-amyl alcohol and 1.2eq of metal sodium into THF, react at room temperature for 4h, and then filter with suction to obtain a THF solution of n-amyl alcohol sodium salt;
[0050] Add the obtained THF solution of fatty alcohol sodium salt into the above solution, continue to react for 24 hours, then cool to room temperature, concentrate the obtained reaction solution to obtain a viscous liquid, wash with deionized water, and obtain a light yellow elastomer;
[0051] Dissolve the resulting el...
Embodiment 3
[0054] Take 30.7g of the hydroxy crown ether structure (z=1, m=3) represented by formula (2) and 1.2eq of sodium metal, add it to 1,4-dioxane, heat to 60°C, and react for 24h. Then cool to room temperature, and suction filter to obtain a 1,4-dioxane solution of crown ether sodium salt;
[0055] Add the 1,4-dioxane solution of the above-mentioned crown ether sodium salt into a THF solution containing 23.2g of polydichlorophosphazene, and react at 60°C for 48h;
[0056] Add 26.4g of unsubstituted n-amyl alcohol and 1.2eq of sodium metal into THF, react at room temperature for 4h, and then filter with suction to obtain a THF solution of n-amyl alcohol sodium salt;
[0057] Add the obtained THF solution of fatty alcohol sodium salt into the above solution, continue to react for 24 hours, then cool to room temperature, concentrate the obtained reaction solution to obtain a viscous liquid, wash with deionized water, and obtain a light yellow elastomer;
[0058] Dissolve the resulti...
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