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Axial reactor

A reactor, axial technology, applied in the field of axial reactors, can solve the problems of low production intensity per unit catalyst bed, small bed pressure drop, low heat transfer and mass transfer efficiency, etc., and achieve high target product selectivity. , The effect of improving fluid uniformity and improving the conversion rate of raw materials

Active Publication Date: 2017-10-03
SINOPEC ENG +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The axial fixed bed reactor design, processing process is relatively easy, and the operation is simple, but there are problems such as large size of reactor equipment, large bed pressure drop, prone to partial temperature runaway, slow heat transfer, low conversion rate, and obvious amplification effect.
The radial fixed bed reactor has a large height-to-diameter ratio, a small bed pressure drop, and a short residence time of the reactants in the catalyst bed, but it is difficult to achieve uniform distribution of the reactants in the radial direction, and the production intensity of the unit catalyst bed is low
[0003] In order to overcome the problems of low heat transfer and mass transfer efficiency in traditional chemical industry, microchemical technology emerged in the 1980s and 1990s.

Method used

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Examples

Experimental program
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Embodiment 1

[0062] Such as figure 1 As shown, the axial reactor used in this embodiment includes a pressure-bearing shell 2 with an air inlet pipe 18 at the upper end and an air outlet pipe 13 at the lower end. The upper part of the air inlet pipe 18 has an air inlet 1, and the lower part is provided with a first As for the gas distributor 3 , a second gas distributor 17 is arranged below the first gas distributor 3 . There are axial microchannel reaction zone 16 and axial catalytic reaction zone 9 under the intake pipe 18 in the casing 2 , and the axial microchannel reaction zone 16 is arranged directly above the axial catalytic reaction zone 9 . Axial microchannel reaction zone 16 is made of two axial microchannel reaction units 14, comprises bottom sealing plate 15, top sealing plate 4 and sidewall, and its sidewall can overlap with the part sidewall of casing 2, also can be with The side walls of the housing 2 are hermetically connected. The bottom of the housing 2 has a ceramic bal...

Embodiment 2

[0070] Such as Figure 4 , Figure 5 As shown, the reactor of this embodiment is the same as the reactor shell inner diameter of the embodiment 1, the structural parameters such as the axial catalytic reaction zone and the height of the axial microchannel reaction unit are the same. The difference from Example 1 is that in this embodiment, the two axial microchannel reaction units are inverted, that is, the smaller end of the microchannel inlet diameter in this embodiment is the microchannel reaction gas inlet, and the larger diameter end is the product. export port.

[0071] The axial reactor can be used for methanol to olefins reaction.

Embodiment 3

[0073] Such as Image 6 , Figure 7 As shown, the reactor of this embodiment is the same as the reactor shell inner diameter of the embodiment 1, the structural parameters such as the axial catalytic reaction zone and the height of the axial microchannel reaction unit are the same. The difference from Example 1 is that in this example, the axial microchannel reaction zone only includes one axial microchannel reaction unit.

[0074] The reactor of this embodiment can be applied to syngas synthesis C in Fe-based catalyst 2 、C 3 and other small molecule alkenes. The amount of active metal Fe loaded on the inner surface of the micro-reaction channel 7 is 17.5g / m 2 . Feed gas H 2 The / CO volume ratio is 2, the reaction temperature is 325°C, the pressure is 0.55MPa, and the volume space velocity is 3100h -1 .

[0075] Table 2 shows the comparison between the reactor used in this example and the axial reactor in the prior art. The catalytic reaction unit of two kinds of reac...

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Abstract

The invention discloses an axial reactor. The reactor comprises a radial cylindrical sealed pressure-bearing shell body (2), a gas inlet pipe (18), a gas outlet pipe (13), an axial microchannel reaction zone (16) and an axial catalytic reaction zone (9), wherein the axial microchannel reaction zone (16) is located above the axial catalytic reaction zone (9); the axial microchannel reaction zone (16) comprises one or more disk-shaped axial microchannel reaction units (14) which are connected in series up and down; each axial microchannel reaction unit (14) has a plurality of axial microreaction channels (7); and the axial catalytic reaction zone (9) can contain at least one catalyst bed layer, and reactant fluid can flow through the catalyst bed layers from top to bottom for a catalytic reaction. Compared with the prior art, the reactor disclosed by the invention is compact in structure, low in active metal consumption, low in bed layer pressure drop, short in gas product retention time and high in bed layer space utilization ratio and is free of gas bias and short-circuit phenomena.

Description

technical field [0001] The invention relates to an axial reactor. Background technique [0002] There are mainly two types of fixed bed reactors, one is axial fixed bed reactor and the other is radial fixed bed reactor. The axial fixed bed reactor is relatively easy to design and process, and simple to operate, but there are problems such as large size of reactor equipment, large pressure drop in the bed layer, prone to local temperature jump, slow heat transfer, low conversion rate, and obvious amplification effect. The radial fixed bed reactor has a large height-to-diameter ratio, a small bed pressure drop, and a short residence time of the reactants in the catalyst bed, but it is difficult to achieve uniform distribution of the reactants in the radial direction, and the production intensity of the unit catalyst bed is low. [0003] In order to overcome the problems of low heat transfer and mass transfer efficiency in traditional chemical industry, microchemical technolog...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J8/02
CPCB01J8/025B01J8/0278B01J2208/00893B01J2208/00911
Inventor 张旭智凯敏戴文松蒋荣兴
Owner SINOPEC ENG
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