A method for rapid prediction of cycle life of lithium-ion batteries

A lithium-ion battery, cycle life technology, applied in the measurement of electricity, measurement devices, measurement of electrical variables, etc., can solve the problems of complex calculation and lack of universality, and achieve simple and easy accuracy, good consistency, and accuracy. high degree of effect

Active Publication Date: 2020-09-11
HEFEI GUOXUAN HIGH TECH POWER ENERGY
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Problems solved by technology

These reported cycle life prediction methods have their own limitations. The first method only considers the relationship between electrolyte consumption and cycle capacity fading, ignoring the characteristics of the electrode material itself, especially the negative electrode material’s impact on the cycle life of lithium-ion batteries. The impact of life, resulting in a large deviation from the actual test results; the second method is based on the calculation structure of the theoretical model to predict battery life, the calculation is complex and not universal

Method used

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  • A method for rapid prediction of cycle life of lithium-ion batteries
  • A method for rapid prediction of cycle life of lithium-ion batteries
  • A method for rapid prediction of cycle life of lithium-ion batteries

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Embodiment 1

[0041] In this embodiment, the battery cell model is 5Ah soft-pack battery as an example, the active material of the positive electrode is lithium iron phosphate, the active material of the negative electrode is artificial graphite, and the charging and discharging mode is constant current and constant voltage charging-shelving-constant current discharging, charging and discharging The current is 1C, the charge cut-off voltage is 3.6V, the discharge cut-off voltage is 2.0V, and the sleep time is 10min. The test equipment used is a 5V / 10A blue battery charge and discharge instrument.

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Abstract

The invention relates to a method for fast predicting a cycle life of a lithium ion battery. The method for predicting a cycle life of a lithium ion battery comprises steps of performing a short period circulation performance test of different cycle times on a battery to be evaluated, recording different cycle times and a corresponding capacity conservation rate, performing disassembling on a battery in an empty state after various cycle times, scrapping off electrode powder on a negative electrode, using an XRD inner calibration method to test a graphitization degree of a graphite cathode material, performing fitting calculation according to three kinds of test data including cycle times, a capacity conservation rate and the graphitization degree and thus performing prediction on the cycle time of the battery. Compared with a routine cycle life test method, the method for fast predicting the cycle life of the lithium ion battery is easy to implement, greatly shortens a test cycle of the cycle life, and, compared with a pure theoretic calculation and experience model prediction, is more universal and more consistent with a practical test result.

Description

technical field [0001] The invention relates to the technical field of battery testing, in particular to a method capable of rapidly predicting the cycle life of lithium-ion batteries. Background technique [0002] Due to the advantages of high energy density, excellent rate and power performance, long cycle life, safety and environmental protection, lithium-ion batteries are widely used as important chemical power sources in our daily life. In addition to long-term use in traditional digital products such as mobile phones and portable computers, the application range of lithium-ion batteries has gradually expanded to high-tech fields such as electric vehicles, aerospace and energy storage. [0003] As a commercial product, lithium-ion batteries must pass various strict performance tests before they can be put into use, including high and low temperature performance tests, rate performance, long-term cycle performance, and safety performance tests. Long-term cycle performan...

Claims

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Application Information

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IPC IPC(8): G01R31/367G01R31/385G01R31/392
CPCG01R31/367G01R31/385G01R31/392
Inventor 王亚平嵇明翔
Owner HEFEI GUOXUAN HIGH TECH POWER ENERGY
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