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Bactericidal and antiviral compositions for finishing textiles

An anti-virus and textile technology, applied in textiles and papermaking, chemicals for biological control, fungicides, etc., can solve the problems of poor wettability of fabrics and difficult secondary finishing

Active Publication Date: 2019-08-20
廊坊天互抗菌材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chitosan is a non-eluting antibacterial agent, and when it is used in water and oil repellent finishing of fabrics, there is a problem that the wettability of the fabric after finishing is poor, and it is difficult to carry out secondary finishing.

Method used

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  • Bactericidal and antiviral compositions for finishing textiles
  • Bactericidal and antiviral compositions for finishing textiles

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0035] The preparation method of described biquaternary ammonium salt A comprises the following steps:

[0036]Add epichlorohydrin to the reactor, raise the temperature to 75°C, slowly add long-chain alkyl tertiary amine dropwise, after the dropwise addition, stir for 0.5h, cool down to 60°C, add acetonitrile, and then add 1-β-D in 3 times -ribofuranose-1,2,4-triazole-3-hydroxyamide, heat preservation reaction for 7h, cool to room temperature, concentrate under reduced pressure, add acetone and stir for 0.5h, concentrate under reduced pressure to obtain bisquaternary ammonium salt A; The molar ratio of epichlorohydrin to the long-chain alkyl tertiary amine and the 1-β-D-ribofuranose-1,2,4-triazole-3-hydroxyamide is 1:0.56:0.5; The weight ratio of the epichlorohydrin to the acetonitrile and the acetone is 1:6:4, and the long-chain alkyl tertiary amine is tetradecyldimethyl tertiary amine.

[0037] The preparation method of described double quaternary ammonium salt B comprises ...

Embodiment 1

[0066] The bactericidal and antiviral composition for modifying textiles includes 32 parts of chitosan quaternary ammonium salt, 5 parts of penetrant, 3 parts of cationic surfactant, 6 parts of modified chitosan loaded with nano-silver, and 45 parts of purified water ; In the chitosan quaternary ammonium salt, the weight ratio of the chitosan grafted biquaternary ammonium salt A and the biquaternary ammonium salt B to the biquaternary ammonium salt B is 1:0.4; The long-chain alkyl tertiary amine comprises tetradecyl dimethyl tertiary amine; organosilicon in the modified chitosan is 3-(2,3-glycidyloxy) propyltrimethoxysilane and 3 - glycidyl ether oxypropylmethyldiethoxysilane; the penetrating agent is fatty alcohol polyoxyethylene ether; the cationic surfactant is stearyloxyethyl ammonium chloride; the shell The weight average molecular weight of polysaccharide is 12000;

[0067] The preparation method of the bactericidal antiviral composition for modifying textiles, comprise...

Embodiment 2

[0084] The bactericidal and antiviral composition for modifying textiles comprises 20 parts of chitosan quaternary ammonium salt, 5 parts of penetrant, 3 parts of cationic surfactant, 15 parts of modified chitosan loaded with nano-silver, and 45 parts of purified water ; In the chitosan quaternary ammonium salt, the weight ratio of the chitosan grafted biquaternary ammonium salt A and the biquaternary ammonium salt B to the biquaternary ammonium salt B is 1:0.4; The long-chain alkyl tertiary amine comprises tetradecyl dimethyl tertiary amine; organosilicon in the modified chitosan is 3-(2,3-glycidyloxy) propyltrimethoxysilane and 3 - glycidyl ether oxypropylmethyldiethoxysilane; the penetrating agent is fatty alcohol polyoxyethylene ether; the cationic surfactant is stearyloxyethyl ammonium chloride; the shell The weight average molecular weight of polysaccharide is 12000;

[0085] The preparation method of the bactericidal antiviral composition used for modifying textiles, t...

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PUM

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Abstract

The invention provides a bactericidal and antiviral composition for modifying textiles. By weight, the bactericidal and antiviral composition for modifying textiles includes 20-50 parts of a chitosanquaternary ammonium salt, 2-10 parts of a penetrant, 1-5 parts of a cationic surfactant, 3-15 parts of nano-silver loaded modified chitosan, and 30-50 parts of purified water. Specifically, the chitosan quaternary ammonium salt is chitosan grafted biquaternary ammonium salt A and biquaternary ammonium salt B, the preparation raw materials of the biquaternary ammonium salt A include: 1-beta-D-ribofuranose-1, 2, 4-triazole-3-hydroxyamide, epichlorohydrin and long chain alkyl tertiary amine, and the preparation raw materials of the biquaternary ammonium salt B include: 1-hydroxyethyl-2-methyl-5-nitroimidazole, epichlorohydrin and long chain alkyl tertiary amine. And the modified chitosan is a chitosan organosilicon compound.

Description

technical field [0001] The invention relates to the technical field of antibacterial materials, in particular, the invention relates to a bactericidal and antiviral composition for modifying textiles. Background technique [0002] Cotton, linen, silk and other natural textiles are closely related to people's daily life, but they are also the habitats of microorganisms such as bacteria and fungi. With the improvement of the quality of life, people have higher requirements for the antibacterial properties of durable consumer goods such as clothing, sanitary products, and daily necessities. In addition, the use of antibacterial products in public places can effectively inhibit the growth of bacteria and prevent the spread and infection of bacteria. [0003] In addition, cotton fabrics can provide carbon and nitrogen sources for the growth of bacteria, and cotton fabrics are easy to adhere to sweat, sebum and other excrements during use, and these substances are good nutrients ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M15/03D06M11/83A01N59/16A01N55/10A01N43/653A01P1/00A01P3/00D06M101/06
Inventor 吴杨段明星孙桂琴郭聚豪曲利军李公
Owner 廊坊天互抗菌材料有限公司