Preparation method and application of main chain embedded terminal amino silicon oil with side chain containing tertiary amino group

A technology of pendant tertiary amino group and tertiary amino group, which is applied in the field of preparation of main chain-blocked amino silicone oil, can solve the problem of limiting the performance of main chain-blocked amino silicone oil softener, small adjustable space for ammonia value, and poor directional adsorption effect And other problems, to achieve the effect of industrial production and commercial promotion and application, wide adjustable range of ammonia value, and good directional adsorption effect

Active Publication Date: 2018-03-06
SICHUAN TEXTILE SCI RES INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

By comparing the two, it can be seen that the ammonia value of the existing main chain-terminated amino silicone oil is generally not more than 0.3mmol / g, and the ammonia value is low; the amino group is introduced by the reaction of difunctional polyetheramine and epoxy-terminated (polyether) silicone oil. , the range of ammonia value is generally 0.1 ~ 0.3mmol / g, the adjustable space of ammonia value is small; the amino group is located on the main chain of the macromolecule, the steric hindrance is relatively large, and the directional adsorption effect on the fiber surface is not good
Thereby, these problems limit the further promotion of the performance of existing main chain end amino silicone oil softener to a certain extent
For this reason, the present invention provides a main chain capped amino silicone oil containing tertiary amino groups in the side chain, which solves the problem of poor directional adsorption effect of the existing main chain capped amino silicone oil, low ammonia value and small adjustment space for ammonia value, and the Located on the main chain of macromolecules, the steric hindrance is relatively large, which limits the further improvement of the handle of the finished fabric

Method used

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  • Preparation method and application of main chain embedded terminal amino silicon oil with side chain containing tertiary amino group
  • Preparation method and application of main chain embedded terminal amino silicon oil with side chain containing tertiary amino group
  • Preparation method and application of main chain embedded terminal amino silicon oil with side chain containing tertiary amino group

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] In a 500mL three-necked flask with a thermometer, a stirrer and a condenser tube, add 3.06g of secondary amine-terminated linear comb-like epoxy polyamine compound 1 (306.4g / mol, m=1, p= 2, R 1 -O-), 101.71g epoxy-terminated silicone oil (20 342g / mol, q=270, x=0, y=0, the molar ratio of the two is 2:1, n=1) and 209.54g isopropanol (accounting for 200% of the mass ratio of the raw material), the temperature was raised to 60° C. for 24.0 h under stirring, and the main chain terminated amino silicone oil 1 (ammonia value 0.19 mmol / g) containing tertiary amino groups in the side chain was obtained.

Embodiment 2

[0039] In a 500mL three-necked flask with a thermometer, a stirrer and a condenser tube, add 2.73g of secondary amine-terminated linear comb-like epoxy polyamine compound 2 (2706g / mol, m=10, p= 3, R 1 for-OCH 2 CH 2 O-), 153.1g terminal epoxy silicone oil (15 310g / mol, q=202, x=0, y=0, the molar ratio of the two is 1.01:1, n=100) and 180.43g ethylene glycol butyl ether (accounting for 100% of the mass ratio of the raw material), the temperature was raised to 130° C. for 8.0 h under stirring, and the main chain-blocked amino silicone oil 2 (ammonia value 1.22 mmol / g) containing tertiary amino groups in the side chain was obtained.

Embodiment 3

[0041] In a 500mL three-necked flask with a thermometer, a stirrer and a condenser tube, add 28.75g of secondary amine-terminated linear comb-like epoxy polyamine compound 3 (784g / mol, m=2, p=4 , R 1 for-OCH 2 CH 2 OCH 2 CH 2 O-), 199.5g terminal epoxy silicone oil (5 986g / mol, q=76, x=0, y=0, the molar ratio of the two is 1.1:1, n=10) and 114.1g diethylene glycol butyl Ether (accounting for 50% of the mass ratio of raw materials) was heated to 150° C. under stirring for 1.0 h to obtain the main chain-terminated amino silicone oil 3 (ammonia value 0.96 mmol / g) containing tertiary amino groups in the side chain.

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Abstract

The invention discloses a preparation method and application of main chain embedded terminal amino silicon oil with a side chain containing a tertiary amino group. The preparation method comprises thestep: with a side tertiary amino group-containing secondary amine end-capping linear comb-shaped epoxy polyamine compound and end epoxy (polyether) silicone oil as raw materials and an organic solvent as a reaction medium, performing an aminolysis ring-opening reaction of the epoxy group to prepare the main chain embedded terminal amino silicon oil with the side chain containing the tertiary amino group. Then a novel embedded terminal amino silicon oil softening agent for fabric softening and finishing is obtained by adjusting the pH to 5 to 6 with glacial acetic acid, and adding an environment-friendly emulsifier for mechanical emulsification. Compared with the existing main chain embedded terminal amino silicon oil softening agent, the novel embedded terminal amino silicon oil softeningagent has more excellent hand feeling.

Description

technical field [0001] The invention relates to the technical field of textile auxiliaries, in particular to a preparation method and application of a main chain capped amino silicone oil containing tertiary amino groups in the side chain. Background technique [0002] Amino silicone oil is a silicone high-molecular polymer containing amino groups on the side groups of macromolecules. After it is mechanically emulsified into amino silicone oil emulsion with an emulsifier, it can be widely used in the finishing of textiles such as cotton, silk, wool and polyester. The fabric has rich hand feeling such as soft, smooth, fluffy and elastic, and has been widely accepted by people. However, because the macromolecular chain of amino silicone oil usually has no hydrophilic groups, the hydrophilicity of the finished fabric is poor, which makes it difficult to repair and dye, and the wearing comfort is not good. At the same time, the hydrophobicity of its macromolecules also leads to...

Claims

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Application Information

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IPC IPC(8): C08G77/46D06M15/643D06M101/06D06M101/32
CPCC08G77/46D06M15/6436D06M2101/06D06M2101/32D06M2200/50
Inventor 樊武厚黄玉华蒲宗耀蒲实梁娟廖正科胡于庆
Owner SICHUAN TEXTILE SCI RES INST
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