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Polyethylene film with high peeling strength on non-aluminized surface of VMPET and preparation method thereof

A polyethylene film and high peeling technology, which is applied in the field of plastic flexible packaging, can solve the problems of instability, low peel strength between non-aluminized surface and PE film, and achieve the effects of improving adhesion, increasing polarity, and increasing peel strength

Active Publication Date: 2018-04-13
FOSHAN SOUTHERN PACKAGING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The problem of low and unstable peel strength between VMPET non-aluminized surface and PE film is becoming a bottleneck restricting the development and application of composite structures such as PET (BOPP) / VMPET / PE
At present, relevant patents and documents at home and abroad have not reported an effective solution to the above problems.

Method used

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  • Polyethylene film with high peeling strength on non-aluminized surface of VMPET and preparation method thereof
  • Polyethylene film with high peeling strength on non-aluminized surface of VMPET and preparation method thereof
  • Polyethylene film with high peeling strength on non-aluminized surface of VMPET and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] Table 1 shows the amount of hydrogenated dimer acid / rosin-based polyester polyamide raw materials used in this embodiment.

[0053] Table 1

[0054]

[0055] The polyethylene film of the present embodiment is made up of following material calculated by weight percentage: hydrogenated dimer acid / rosin base polyester polyamide 10%, maleic anhydride grafted polyethylene 5%, low density polyethylene 34%, linear low Density polyethylene 34%, metallocene polyethylene 17%.

Embodiment 2

[0057] Table 2 shows the amount of hydrogenated dimer acid / rosin-based polyester polyamide raw materials used in this embodiment.

[0058] Table 2

[0059]

[0060] The polyethylene film of the present embodiment is made up of following material calculated by weight percentage: hydrogenated dimer acid / rosin base polyester polyamide 15%, maleic anhydride grafted polyethylene 5%, low density polyethylene 28%, linear low Density polyethylene 36%, metallocene polyethylene 16%.

Embodiment 3

[0062] Table 3 shows the amount of hydrogenated dimer acid / rosin-based polyester polyamide raw materials used in this embodiment.

[0063] table 3

[0064]

[0065] The polyethylene film of the present embodiment is composed of the following materials calculated by weight percentage: hydrogenated dimer acid / rosin-based polyester polyamide 5%, maleic anhydride grafted polyethylene 2%, low-density polyethylene 35%, linear low Density polyethylene 40%, metallocene polyethylene 18%.

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Abstract

The invention discloses a polyethylene film with high peeling strength on a non-aluminized surface of VMPET and a preparation method thereof. The polyethylene film comprises the following substances by weight: 5 to 15% of hydrogenated dimer acid / rosin-based polyester polyamide, 2 to 5% of maleic anhydride-grafted polyethylene and 80 to 93% of polyethylene, wherein the hydrogenated dimer acid / rosin-based polyester polyamide is prepared by reacting carboxyl-terminated polyamide with dihydric alcohol; the carboxyl-terminated polyamide is prepared by reacting hydrogenated dimer acid with maleic rosin acid and diamine, a weight ratio of the hydrogenated dimer acid to the maleic rosin acid is 5: 5 to 3: 7, and a ratio of the sum of the mole numbers of carboxyl groups in the hydrogenated dimer acid and the maleic rosin acid to the mole number of amino groups in the diamine is 1: 0.6-0.8; and a ratio of the mole number of hydroxyl groups in the dihydric alcohol to the mole number of carboxyl groups in the carboxyl-terminated polyamide is greater than or equal to 1.8: 1. The prepared polyethylene film in the invention has the advantages of smooth surface, uniform color and no foreign matters, and high peeling strength on the non-aluminized surface of a VMPET film.

Description

technical field [0001] The invention relates to the technical field of plastic flexible packaging, and more specifically relates to a polyethylene film with high peel strength from a VMPET non-aluminized surface and a preparation method thereof. Background technique [0002] Aluminum-coated composite film is a compound of aluminum-coated film and transparent plastic film, which is a relatively common film in flexible packaging production. Its excellent barrier properties, metallic luster and operability have replaced aluminum foil composite packaging to a certain extent; Because of its high cost performance, it is more and more favored by flexible packaging companies, and has been widely used in the outer packaging of food, health care products, medicine, cosmetics and other products. [0003] At present, most of the aluminized films are VMPET and VMCPP. This kind of film material is to attach aluminum to the surface of the traditional PET and CPP substrates by a certain pro...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08L23/08C08L77/12C08L51/06C08G69/44C08J5/18B32B27/08B32B27/32
CPCB32B27/08B32B27/32C08G69/44C08J5/18C08J2323/06C08J2323/08C08J2423/06C08J2451/06C08J2477/12
Inventor 郑日安向志军刘长来林灿洪
Owner FOSHAN SOUTHERN PACKAGING
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