Method for determination of thermal stress of prepregs, metal-clad laminates, wiring boards, and wiring board materials
A prepreg, tensile stress technology, used in metal layered products, circuit substrate materials, and the use of stable tension/pressure to test the strength of materials, etc., can solve package warpage, differences, semiconductor chip and substrate connection Reduced reliability and other problems, to achieve the effect of suppressing warpage
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Embodiment 1
[0121] 41.67 parts by mass of naphthalene-type epoxy resin (HP9500 manufactured by DIC Corporation), 28.33 parts by mass of naphthalene-type phenolic curing agent (HPC9500 manufactured by DIC Corporation), epoxy-modified acrylic resin (PMS manufactured by Nagase ChemteX Corporation) -12-82 (500,000 weight molecular weight)) 30 parts by mass, 0.04 parts by mass of imidazole (2E4MZ manufactured by Shikoku Chemical Industry Co., Ltd.: 2-ethyl-4-methylimidazole) as a curing accelerator, and isocyanate silane A resin composition was obtained by mixing 50 parts by mass of spherical silica (SC2500GNO manufactured by Admatechs Company Limited) with a surface-treated coupling agent. Then, this resin composition was diluted with 151 parts by mass of methyl ethyl ketone (MEK) as a solvent, thereby preparing a varnish-like resin composition (resin varnish).
[0122] Using the obtained resin varnish, it was impregnated into a woven fabric substrate (glass cloth, Nitto Boseki Co., Ltd. 1078...
Embodiment 2
[0125] As the woven fabric substrate, use another glass cloth, that is, Nitto Boseki Co., Ltd. T2013 (thickness 71 μm, unit weight 80 g / m 2 ), except that the resin varnish was impregnated so as to have a thickness of 0.1 mm, and a prepreg was obtained in the same manner as in Example 1. Furthermore, for one obtained prepreg, copper foil (thickness 12 μm) was laminated as a metal foil on both sides thereof, and the prepreg was vacuum-conditioned at 2.94 MPa (30 kgf / cm 2 ) was pressed and molded while being heated at 220° C. for 60 minutes to manufacture a copper-clad laminate (CCL) with a thickness of 0.1 mm as a metal-clad laminate.
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