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Zinc-air battery positive electrode and positive electrode powder dry preparation process and zinc-air battery

A technology of zinc-air battery and preparation process, which is applied in the direction of battery electrodes, fuel cell half-cells, primary battery-type half-cells, portable system fuel cells, etc., and can solve the impact of material performance, side reactions, complex costs, etc. Problems, to achieve excellent performance, simple production process, high film strength

Active Publication Date: 2020-08-07
GUANGZHOU GREAT POWER ENERGY & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above-mentioned wet mixing process is extremely complicated and costly. During the mixing process, the presence of moisture may cause side reactions with the material. The later high-temperature baking of the positive electrode mixed powder may also affect the performance of the material itself.

Method used

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  • Zinc-air battery positive electrode and positive electrode powder dry preparation process and zinc-air battery
  • Zinc-air battery positive electrode and positive electrode powder dry preparation process and zinc-air battery
  • Zinc-air battery positive electrode and positive electrode powder dry preparation process and zinc-air battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0063] Cathode materials include binder polytetrafluoroethylene, catalyst MnO 2 , activated carbon, graphite. PTFE powder 2kg, MnO 2 3kg, 4kg of activated carbon and 1kg of graphite are mixed and granulated in a high-speed stirring tank to obtain positive electrode powder. The average particle size of PTFE powder is 450μm.

[0064] Figure 4 The SEM image of the mixed powder after dry mixing and granulation of Example 1 is shown. It can be observed from the figure that the positive electrode mixture powder is evenly mixed after one-step forming dry mixing, and a large amount of binder fibrosis appears in the powder. Then pass the positive electrode powder through a horizontal double-roll machine to form a catalyst sheet with uniform thickness, regular surface and high strength, and then pass the catalyst sheet through a vertical double-roll machine to press nickel mesh and PTFE film on both sides to obtain the required positive electrode. piece. The positive electrode sh...

Embodiment 2

[0067] Cathode materials include binder polytetrafluoroethylene, catalyst MnO 2 , activated carbon, graphite. PTFE powder 1kg, MnO 2 2 kg, 3 kg of activated carbon, and 0.5 kg of conductive carbon were mixed and granulated in a high-speed stirring tank to obtain positive electrode powder, and the rest of the preparation process was the same as in Example 1.

[0068] SEM detection was also carried out on the mixed powder of Example 2, and it was also found that a large amount of binder fibrosis appeared in the powder.

Embodiment 3

[0070] Cathode materials include binder polytetrafluoroethylene, catalyst MnO 2 , activated carbon, graphite. The steps of dry preparation of the positive electrode sheet are as follows: 3 kg of PTFE powder, 5 kg of MnO2, 5 kg of activated carbon and 1.2 kg of conductive carbon are mixed and granulated in a high-speed stirring tank to obtain the positive electrode powder. The rest of the preparation process is the same as in Example 1.

[0071] SEM detection was also carried out on the mixed powder of Example 3, and it was also found that a large amount of binder fibrosis appeared in the powder.

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Abstract

The invention discloses a zinc air battery anode as well as an anode powder drying method preparation process and a zinc air battery thereof. According to the anode powder drying method preparation process, an anode mixing dry powder material for the zinc air battery is dispersed at a high speed by using a high-speed stirring and mixing machine, and then an adhesive in the material can be highly fibered. Compared with a conventional wet-method stirring mode, the n anode powder drying method preparation process is simple in process and low in cost, meanwhile an anode material can be uniformly mixed with high filming strength, and the mercury-free zinc air battery made of the anode material can be excellent in property.

Description

technical field [0001] The invention relates to the field of batteries, in particular to a zinc-air battery positive electrode and a dry method preparation process for the positive electrode powder thereof, and the zinc-air battery. Background technique [0002] With the development of modern manufacturing technology, the ever-increasing energy demand has filled all aspects of life, and the energy demand of small portable devices such as watches, hearing aids, and Bluetooth earphones is also increasing. Zinc-air batteries are widely used as batteries for most hearing aids on the market today due to their many advantages such as high capacity and low cost. [0003] Zinc-air battery is a metal-air battery powered by positive electrode air and negative electrode zinc. Its advantages lie in high capacity and low cost. Among them, the preparation of air cathode is a key process for the efficient industrialization of zinc-air batteries. [0004] In order to prepare an air electr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/90H01M4/92H01M4/96H01M12/06
CPCH01M4/90H01M4/9016H01M4/921H01M4/96H01M12/06H01M2250/30Y02E60/50
Inventor 胡铭昌薛建军崔燕陈玮郭镖周雪晴
Owner GUANGZHOU GREAT POWER ENERGY & TECH CO LTD