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Rh ultrathin two-dimensional nanosheet and preparation method thereof

A two-dimensional nano, ultra-thin technology, applied in the direction of nanotechnology, chemical instruments and methods, metal processing equipment, etc., to achieve the effect of high atom utilization

Active Publication Date: 2018-07-13
INST OF ADVANCED TECH UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Nowadays, many other graphene-like materials have also been studied, such as hexagonal boron nitride (h-BN), transition metal dichalcogenides (TMDs), graphitic carbon nitride (g-C3N4), layered metal oxides and Layered double hydroxides, etc., but there are still great challenges in the synthesis of metal ultrathin two-dimensional nanomaterials

Method used

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  • Rh ultrathin two-dimensional nanosheet and preparation method thereof
  • Rh ultrathin two-dimensional nanosheet and preparation method thereof
  • Rh ultrathin two-dimensional nanosheet and preparation method thereof

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Embodiment 1

[0024] The invention proposes an ultrathin two-dimensional nanosheet of Rh, which has a porous structure.

[0025] The present invention also proposes a method for preparing the ultra-thin two-dimensional nanosheets of Rh, comprising the following steps: using a rhodium compound as a raw material to prepare a precursor suspension, and then mixing the precursor suspension with a capping agent and a solvent Afterwards, the reaction is carried out to obtain the ultrathin two-dimensional nanosheets of Rh.

Embodiment 2

[0027] An ultra-thin two-dimensional nanosheet of Rh proposed by the present invention has a porous structure, its particle size is between 50nm-85nm, and its thickness is 0.6nm-1nm.

[0028] The present invention also proposes a method for preparing the ultra-thin two-dimensional nanosheets of Rh, comprising the following steps: using a rhodium compound as a raw material to prepare a precursor suspension, and then mixing the precursor suspension with a capping agent and a solvent Afterwards, react to obtain the ultrathin two-dimensional nanosheet of Rh;

[0029] Wherein, the rhodium compound is rhodium acetylacetonate;

[0030] The process of preparing precursor suspension with rhodium compound as raw material is as follows: add rhodium acetylacetonate into oleylamine at normal temperature, and use a shaker to disperse evenly to obtain precursor suspension; wherein, the quality of rhodium acetylacetonate is the same as that of oleylamine. The volume ratio is 35:7mg / ml;

[0...

Embodiment 3

[0035] The ultra-thin two-dimensional nanosheet of Rh proposed by the present invention has a porous structure, its particle size is between 100nm-400nm, and its thickness is 0.4nm-0.7nm.

[0036] The present invention also proposes a method for preparing the ultra-thin two-dimensional nanosheets of Rh, comprising the following steps: using a rhodium compound as a raw material to prepare a precursor suspension, and then mixing the precursor suspension with a capping agent and a solvent Afterwards, react to obtain the ultrathin two-dimensional nanosheet of Rh;

[0037] Wherein, the rhodium compound is rhodium acetylacetonate;

[0038] The process of preparing precursor suspension with rhodium compound as raw material is as follows: add rhodium acetylacetonate into oleylamine at normal temperature, and use a shaker to disperse evenly to obtain precursor suspension; wherein, the quality of rhodium acetylacetonate is the same as that of oleylamine. The volume ratio is 45:2mg / ml; ...

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Abstract

The invention discloses an Rh ultrathin two-dimensional nanosheet which is of a porous structure, wherein the particle size is 50-400nm, and the thickness if 0.4-1nm. The invention also provides a preparation method of the Rh ultrathin two-dimensional nanosheet. The preparation method comprises the following steps of preparing a precursor suspension liquid by taking a rhodium compound as a raw material, then mixing the precursor suspension liquid, a capping agent and a solvent, and performing reaction to obtain the Rh ultrathin two-dimensional nanosheet. The preparation method of the Rh ultrathin two-dimensional nanosheet is simple in process and mild in condition; the obtained nanosheet is of a continuous network-shaped hole structure, is small in thickness, particularly large in specificsurface area, more in exposed active sites, particularly high in utilization ratio of atoms and better in stability and has large potential in catalyzation.

Description

technical field [0001] The invention relates to the technical field of nano catalysts, in particular to a Rh ultrathin two-dimensional nano sheet and a preparation method thereof. Background technique [0002] The original idea of ​​"nanoscience" came from a lecture given by the famous physicist Feynman at Caltech University in 1959, and it has emerged since the 1990s. Nanoscience is considered to be a hot subject that has a very important impact on the emergence and development of a series of high-tech in the 21st century. It is listed as one of the key technologies in the 21st century by countries all over the world, and a lot of manpower and material resources are invested in research and development. [0003] Ultrathin two-dimensional nanomaterials are an emerging class of nanomaterials, which have a sheet-like structure with a horizontal dimension of more than 100 nm or a few microns or even larger, but a thickness of only one or a few atoms (typically less than 5 nm). ...

Claims

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Application Information

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IPC IPC(8): B01J23/46B01J35/02B01J35/10B22F9/24B22F1/00B82Y40/00
CPCB82Y40/00B01J23/464B22F9/24B22F1/07B22F1/068B01J35/60B01J35/40
Inventor 闫旭鹏刘英桓黄宏文曾杰
Owner INST OF ADVANCED TECH UNIV OF SCI & TECH OF CHINA
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