Rh ultrathin two-dimensional nanosheet and preparation method thereof
A two-dimensional nano, ultra-thin technology, applied in the direction of nanotechnology, chemical instruments and methods, metal processing equipment, etc., to achieve the effect of high atom utilization
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Embodiment 1
[0024] The invention proposes an ultrathin two-dimensional nanosheet of Rh, which has a porous structure.
[0025] The present invention also proposes a method for preparing the ultra-thin two-dimensional nanosheets of Rh, comprising the following steps: using a rhodium compound as a raw material to prepare a precursor suspension, and then mixing the precursor suspension with a capping agent and a solvent Afterwards, the reaction is carried out to obtain the ultrathin two-dimensional nanosheets of Rh.
Embodiment 2
[0027] An ultra-thin two-dimensional nanosheet of Rh proposed by the present invention has a porous structure, its particle size is between 50nm-85nm, and its thickness is 0.6nm-1nm.
[0028] The present invention also proposes a method for preparing the ultra-thin two-dimensional nanosheets of Rh, comprising the following steps: using a rhodium compound as a raw material to prepare a precursor suspension, and then mixing the precursor suspension with a capping agent and a solvent Afterwards, react to obtain the ultrathin two-dimensional nanosheet of Rh;
[0029] Wherein, the rhodium compound is rhodium acetylacetonate;
[0030] The process of preparing precursor suspension with rhodium compound as raw material is as follows: add rhodium acetylacetonate into oleylamine at normal temperature, and use a shaker to disperse evenly to obtain precursor suspension; wherein, the quality of rhodium acetylacetonate is the same as that of oleylamine. The volume ratio is 35:7mg / ml;
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Embodiment 3
[0035] The ultra-thin two-dimensional nanosheet of Rh proposed by the present invention has a porous structure, its particle size is between 100nm-400nm, and its thickness is 0.4nm-0.7nm.
[0036] The present invention also proposes a method for preparing the ultra-thin two-dimensional nanosheets of Rh, comprising the following steps: using a rhodium compound as a raw material to prepare a precursor suspension, and then mixing the precursor suspension with a capping agent and a solvent Afterwards, react to obtain the ultrathin two-dimensional nanosheet of Rh;
[0037] Wherein, the rhodium compound is rhodium acetylacetonate;
[0038] The process of preparing precursor suspension with rhodium compound as raw material is as follows: add rhodium acetylacetonate into oleylamine at normal temperature, and use a shaker to disperse evenly to obtain precursor suspension; wherein, the quality of rhodium acetylacetonate is the same as that of oleylamine. The volume ratio is 45:2mg / ml; ...
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