Method for degrading organic substance by activating potassium permanganate through sulfite complex reagent
A technology of sulfite and composite agents, applied in chemical instruments and methods, water pollutants, oxidized water/sewage treatment, etc., can solve the problems of low chemical utilization rate, secondary pollution, high chemical consumption, etc. Utilization rate, reduced drug consumption, and low cost effects
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Embodiment 1
[0041] The method that a kind of sulfite composite agent of the present invention activates potassium permanganate to degrade organic matter is applied to process 3mg / L phenol waste water, and its specific steps are as follows:
[0042] (1). Prepare 100mL 80g / L sodium hydroxide solution;
[0043] (2). Prepare 100 mL of magnesium chloride and aluminum chloride mixed solution with a molar ratio of 3:1;
[0044] (3). Stir the mixed solution vigorously, add sodium hydroxide solution into the mixed solution, and continue stirring for 60-120 minutes to obtain a composite solution;
[0045] (4). Heating the above composite solution at a temperature of 65°C for 16 hours, and standing for cooling to obtain a mixed emulsion A;
[0046] (5). Prepare 5mmol / L sodium sulfite solution;
[0047] (6). Prepare 5mmol / L potassium permanganate solution;
[0048] (7). Add 50mL of sodium sulfite solution into the mixed emulsion A, and quickly seal and magnetically stir for 40 minutes at room temp...
Embodiment 2
[0052] This embodiment is basically the same as Embodiment 1, except that the dosage of potassium permanganate solution in the operation step (7) is 25mL, and the reaction is stirred for 30min. After the reaction, the water sample is taken for measurement, wherein the removal rate of phenol is 100%. The concentration of residual sulfate ions was 0.6 mg / L. TOC removal rate is 34% (see figure 1 , figure 2 ).
Embodiment 3
[0054] This embodiment is basically the same as Embodiment 1, except that the dosage of potassium permanganate solution in the operation step (7) is 10mL, the stirring reaction is 30min, and the water sample is taken after the reaction for measurement. Wherein, the removal rate of phenol is 63%. The concentration of residual sulfate ions was 0.5 mg / L. TOC removal rate is 30% (see figure 1 ).
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