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Melt-processable water-soluble pva chip for composite fiber and its preparation process

A melt processing and composite fiber technology, applied in the direction of fiber chemical characteristics, rayon manufacturing, conjugated synthetic polymer rayon, etc., can solve the problems of composite fiber pollution, increase thermal decomposition temperature, reduce labor intensity, The effect of inhibiting crystallization

Active Publication Date: 2020-10-02
浙江泓泰德建新纤维有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In view of the deficiencies in the prior art, the technical problem to be solved by the present invention is to provide a method to solve the pollution problem caused by the traditional PVA slices using organic solvents to prepare composite fibers, to achieve the purpose of composite melt spinning with island phase resins, and to enhance Melt-processable water-soluble PVA chips for composite fibers with reduced labor intensity and production continuity and its preparation process

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A kind of melt-processable water-soluble PVA chip of the present embodiment is used for the composite fiber, is formed by the fusion of the raw materials of following weight ratio: 50 parts of polyvinyl alcohol; 15 parts of polyalcohols or salt compound modifier; Antioxidant 5 parts 5 parts; 5 parts of lubricant; 20 parts of deionized water; wherein, the grade of polyvinyl alcohol is 1099, the modifier of polyalcohol or salt compound is alcohol amine, polyethylene glycol, and the antioxidant is aniline antioxidant, The lubricant is calcium stearate. The purpose of adding antioxidant is to slow down the thermal degradation and yellowing of PVA, and the purpose of lubricant is to improve the flow and formability of PVA.

[0037] The fusion method is to dissolve the polyol or salt compound modifier in deionized water first, then mix it evenly with antioxidant, lubricant and polyvinyl alcohol, and obtain the modified PVA slice after drying. The melting point of the PVA slic...

Embodiment 2

[0046]The melt-processable water-soluble PVA chip used for the composite fiber in this embodiment is formed by fusion of raw materials in the following proportions by weight: 60 parts of polyvinyl alcohol; 18 parts of polyalcohol or salt compound modifier; 7 parts of antioxidant; 8 parts of lubricant; 25 parts of deionized water; among them, the grade of polyvinyl alcohol is 1099, the modifier of polyalcohol or salt compound is acetate and phosphate, and the antioxidant is hindered phenolic antioxidant. β-(3,5-di-tert-butyl-4-hydroxyphenyl), the lubricant is a multifunctional fatty acid complex ester. The purpose of adding antioxidant is to slow down the thermal degradation and yellowing of PVA, and the purpose of lubricant is to improve the flow and formability of PVA.

[0047] The fusion method is to dissolve the polyol or salt compound modifier in deionized water first, then mix it evenly with antioxidant, lubricant and polyvinyl alcohol, and obtain the modified PVA chip af...

Embodiment 3

[0056] The composite fiber of this embodiment is melt-processable water-soluble PVA slices, which are fused by the following raw materials in parts by weight: 70 parts of polyvinyl alcohol; 20 parts of polyalcohols or salt compound modifiers; 10 parts of antioxidants; 10 parts of lubricant; 30 parts of deionized water; among them, the grade of polyvinyl alcohol is 0897, the modifier of polyalcohol or salt compound is polyethylene glycol and acetate, and the antioxidant is β-(3,5 di tert-butyl 4-hydroxy-phenyl), the lubricant is calcium stearate. The purpose of adding antioxidant is to slow down the thermal degradation and yellowing of PVA, and the purpose of lubricant is to improve the flow and formability of PVA.

[0057] The fusion method is to first dissolve polyol or salt compound modifier in deionized water, then mix it with antioxidant, lubricant and polyvinyl alcohol evenly, and obtain modified PVA chips after drying. The melting point of the PVA chips is 190 ℃; meltin...

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Abstract

The invention discloses a melt-processable water-soluble PVA chip for composite fibers. The melt-processable water-soluble PVA chip is prepared by fusing the following raw materials in parts by weight: 50-70 parts of polyvinyl alcohol, 15-20 parts of a polyol or a salt compound modifier, 5-10 parts of an antioxidant, 5-10 parts of a lubricant, and 20-30 parts of deionized water. The invention alsoprovides a preparation technology of the PVA chip. By molecular compounding and plasticizing, the technology provided by the invention adopts an environment-friendly small molecular compound or oligomer having a complementary structure with PVA to form strong hydrogen bonding compounding with PVA, thereby weakening strong hydrogen bonds within and between PVA molecules, inhibiting crystallizationof PVA, lowering the melting point of PVA, increasing the thermal decomposition temperature of PVA, and realizing the purpose of thermoplastic processing of PVA and composite melt spinning of islandphase resin; and PVA sea phase is dissolved with hot water, thereby solving the problems of organic solvent pollution and recycling and waste alkali liquor treatment of a hydrolysis product.

Description

technical field [0001] The invention belongs to the technical field of finishing and processing of functional textiles, and in particular relates to a melt-processable water-soluble PVA chip for composite fibers and a preparation process thereof. Background technique [0002] Sea-island type composite superfine fiber has attracted people's attention due to its high coverage, soft touch, comfortable wearing, soft luster, and good adsorption properties. It is widely used in clothing, artificial leather, building materials, adsorption and filter materials, etc. . The island-in-the-sea composite superfine fiber adopts composite spinning technology to use two fiber-forming polymers as "island" and "sea" components respectively, and melt-spins them according to different ratios, and then uses these two components to form a certain The different solubilities of chemical solvents dissolve the "sea" component and leave the "island" component, which is the composite ultrafine fiber. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L29/04C08L71/02C08K3/32C08K5/098C08K5/17D01F8/12D01F1/10
CPCC08K3/32C08K5/098C08K2003/321C08L29/04D01F1/10D01F8/12C08L71/02C08K5/17
Inventor 尹德河马建伟陈建民
Owner 浙江泓泰德建新纤维有限公司