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Equipment and method for producing directly reduced iron in gas-based vertical furnace by directly utilizing coal gasification hot coal gas

A gas-based shaft furnace and hot gas technology, applied in shaft furnaces, furnaces, furnace types, etc., can solve the problems of low efficiency and high investment in the rotary kiln process, and achieve the effects of high efficiency, good economy and compact structure

Active Publication Date: 2018-09-04
NORTHEASTERN UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, the mature coal-based direct reduction process in my country is only the rotary kiln process, but the high investment and low efficiency of the rotary kiln process discourage most manufacturers

Method used

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  • Equipment and method for producing directly reduced iron in gas-based vertical furnace by directly utilizing coal gasification hot coal gas

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Such as figure 1 As shown, it includes a fluidized bed coal gasifier 1, in which pulverized coal is placed, and oxygen and water vapor are introduced into it. By adjusting the ratio of oxygen and water vapor, the H of the synthesized gas produced is 2 and CO molar ratio is 1.2-1.7. 8-12%wt, preferably 10%wt, of dolomite powder can be mixed into the coal powder to reduce the sulfur content in the synthesis gas. The operating pressure in the fluidized bed coal gasifier 1 is 0.3 MPa-0.6 MPa, the temperature of the generated syngas can reach as high as 980°C, and the generated slag can be used as raw material for cement plants.

[0036] The syngas is mixed with the shaft furnace top gas that has been heat-exchanged and dedusted, and the lower-temperature heat-exchanged and dedusted shaft furnace top gas quenches the syngas to 800°C-850°C, in fact, it can be no higher than 850°C. The mixed gas is called hot raw gas.

[0037] The hot crude gas is passed into the gravity du...

Embodiment 2

[0049] A kind of iron making method, uses pulverized coal, steam and oxygen to prepare syngas under 0.3MPa operation pressure, the H of syngas 2 / CO is 1.2. The shaft furnace top gas with heat exchange and dedusting at 50°C is fed into the synthesis gas, and the two are mixed to obtain hot crude gas at 850°C. Dedust the hot crude gas to obtain a dust content of 9g / m 3 Purified crude gas.

[0050] Pass the purified crude gas into the reforming workspace, the temperature of the workspace is 1200°C, and the workspace is provided with a reforming furnace charge with a particle size of 50mm, including 65%wt coke, 25%wt dolomite and 10%wt converter Steel slag. CO removal in reforming space 2 and H 2 After S, reformed gas is obtained, its temperature is 1100°C, H 2 / CO is 1.2.

[0051] Pass the heat-exchanged and dedusted shaft furnace top gas at 50°C into the reformed gas to obtain synthetic reformed gas. Centrifugal dedusting of synthetically upgraded coal gas. Purified sy...

Embodiment 3

[0053] A kind of ironmaking method, use steam, oxygen and pulverized coal containing 12%wt dolomite powder to prepare synthesis gas under 0.5MPa operating pressure, by adjusting the ratio of water vapor and oxygen, the H of synthesis gas 2 / CO is 1.7. The shaft furnace top gas with heat exchange and dedusting at 30°C is fed into the synthesis gas, and the two are mixed to obtain hot crude gas at 800°C. Gravity dedusting is carried out on the hot crude gas first, and the carryover obtained by gravity dedusting is added back to the pulverized coal; then cyclone dedusting is carried out, and the dust obtained by cyclone dedusting is used to recover waste heat. Get dust content 3g / m 3 Purified crude gas.

[0054] Pass the purified crude gas into the reforming workspace, the temperature of the workspace is 1100°C, and the workspace is provided with reforming furnace charge with a particle size of 100mm, including 85%wt coke, 10%wt dolomite and 5%wt converter Steel slag. CO remo...

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Abstract

The invention relates to equipment and method for producing directly reduced iron (DRI) in a gas-based vertical furnace by directly utilizing coal gasification hot coal gas. The method comprises the following steps: preparing synthetic gas by utilizing coal powder, water steam and oxygen gas, wherein the ratio of H2 to CO is 1.2 to 1.7 and the temperature is not greater than 850 DEG C after heat-exchanged and dust-removed furnace-top coal gas of the vertical furnace is added; carrying out dust removal; carrying out modification and removing CO2 and H2S at the temperature of 1100 to 1250 DEG C,with the help of a furnace material of a modifying furnace, wherein the temperature of modified coal gas is 900 DEG C to 1100 DEG C and the ratio of the H2 to the CO is 1.2 to 1.7; mixing the heat-exchanged and dust-removed furnace-top coal gas of the vertical furnace to obtain synthesized modified coal gas with the temperature of 850 DEG C to 900 DEG C; after removing dust of the synthesized modified coal gas, introducing into a vertical furnace with iron ore to obtain the DRI. According to the method provided by the invention, characteristics of energy resources of China are combined; coalgasification and gas-based vertical furnace direct reduction technologies are combined, and the dependence of a gas-based direct reduction method on natural gas is overcome; a long and complicated procedure of cooling the coal gasification hot coal gas, transforming, purifying and re-heating, and then producing the directly reduced iron by utilizing the coal gasification hot coal gas in the vertical furnace is avoided; the method provided by the invention has the advantages of short flow, low energy consumption, good reduction components, low pollution and the like.

Description

technical field [0001] The invention relates to the metallurgical field of direct reduction in shaft furnaces, in particular to a method in which coal gasification heat gas is directly used in a gas-based shaft furnace to produce direct reduced iron. [0002] The invention also relates to a device for directly using coal gasification hot coal gas to produce direct reduced iron in a gas-based shaft furnace. Background technique [0003] Direct reduction of iron is a method of obtaining metallic iron by reducing it below the softening temperature of iron ore (or iron-containing agglomerates) using gas, liquid fuel or non-coking coal as energy sources. Its products are porous and low-density sponge-like structure, known as DRI (DirectReduced Iron-direct reduced iron) or sponge iron. Direct reduced iron has excellent properties in terms of energy saving and environmental protection. With the rapid development of the world's iron and steel industry and the increasing attention ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21B13/02
CPCC21B13/0073C21B13/02Y02P10/122Y02P10/143
Inventor 储满生李胜康李峰周渝生王国栋唐珏柳政根王佳鑫王正平刘云太
Owner NORTHEASTERN UNIV