SERS (surface enhanced Raman scattering) test strip, and preparation method and application thereof
A technology of test strips and substrates, applied in the field of SERS test strips supported by gold-graphene composite nanomaterials and its preparation, can solve the problems of difficult quantitative analysis, poor anti-interference ability and stability, and few types of SERS test strips , to achieve the effect of large application potential, improved reproducibility and accuracy, and short detection time
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Embodiment 1
[0037] The preparation method of electropositive gold-graphene composite nanomaterial sol comprises the steps:
[0038] (1) HAuCl 4 Add methanol and sonicate for 2h to obtain solution A, HAuCl 4 The mass volume ratio with methanol is 0.15:75, the mass unit is g, and the volume unit is mL; SiO 2 Add another portion of methanol and sonicate for 2 h to obtain solution B, SiO 2 The mass volume ratio of methanol is 1:75, the mass unit is g, and the volume unit is mL; after mixing solution A and solution B, perform ultrasonic treatment for 0.5 to remove methanol, and dry the obtained mixture at 65 °C; Among them, the HAuCl 4 and SiO 2 The mass ratio is 0.35:1.
[0039] (2) Grind the mixture obtained in step (1) into powder, and then in CH 4 Flow rate is 180 cm 2 Burning 8 min under the airflow condition of / mL, burning temperature is 800 ℃, after cooling, mix with the mixed solution that HF, ethanol and water form, centrifuge, obtain gold-graphene composite nanoparticle after...
Embodiment 2
[0043] The preparation method of the SERS test strip loaded by gold graphene composite nanomaterial comprises the steps:
[0044] (1) HAuCl 4 Add methanol and sonicate for 2h to obtain solution A, HAuCl 4 The mass volume ratio with methanol is 0.25:85, the mass unit is g, and the volume unit is mL; SiO 2 Add another portion of methanol and sonicate for 1 h to obtain solution B, SiO 2 The mass-to-volume ratio of methanol is 1:85, the mass unit is g, and the volume unit is mL; after mixing solution A and solution B, perform ultrasonic treatment for 1 hour to remove methanol, and dry the obtained mixture at 75 °C; Among them, the HAuCl 4 and SiO 2 The mass ratio is 0.25:1.
[0045] (2) Grind the mixture obtained in step (1) into powder, and then in CH 4 Flow rate is 150 cm 2 Ignite 11 min under the airflow condition of / mL, and the burning temperature is 1000 ℃, mixes with the mixed solution that HF, ethanol and water are formed after cooling, centrifuges, obtains gold-gra...
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