A kind of low temperature crude oil demulsifier and preparation method thereof

A crude oil demulsifier and low-temperature technology, which is applied in the direction of dehydration/demulsification by chemical methods, can solve the problems of oil and gas gathering and transportation and crude oil refining, consume large energy, and take a long time to overcome the problems of long demulsification time and demulsification The effect of low milk temperature and convenient operation

Active Publication Date: 2020-07-31
XI'AN PETROLEUM UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the development of the world's petroleum industry, the amount of oil extraction is increasing. When crude oil is extracted from the ground, it often carries a large amount of water or brine. Under the action of the interface active substances in crude oil, these water or brine can be combined with crude oil Emulsions with considerable stability are formed. These emulsions bring great difficulties to oil and gas gathering and transportation and crude oil refining. Therefore, dehydration and desalination must be carried out, that is, demulsification. Different methods can be used for demulsification, but the most common is The most effective method is to add chemical reagents for chemical demulsification. The demulsifier molecules penetrate and adhere to the interface of the emulsified droplets, displace the emulsifier and destroy the surface film, so that the dispersed phase is released and coalesced, phase separation, and finally To achieve the purpose of phase separation, commercially available conventional demulsifiers in the prior art often need to be effective at higher temperatures, and heating during demulsification consumes a lot of energy, and the time required for demulsification is long

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  • A kind of low temperature crude oil demulsifier and preparation method thereof
  • A kind of low temperature crude oil demulsifier and preparation method thereof

Examples

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Effect test

Embodiment 1

[0015] The low-temperature crude oil demulsifier of the present embodiment is made of the following raw materials in parts by weight: 56 parts of ethylenediamine, 28 parts of methanol, 37 parts of hexafluorobutyl methacrylate, 19 parts of petroleum sulfonate, 24 parts of sodium persulfate 21 parts of sodium lauryl sulfate, 14 parts of sodium dimethyldithiocarbamate and 10 parts of dodecyl mercaptan.

[0016] The preparation method of the low temperature crude oil demulsifier of the present embodiment: comprise the following steps:

[0017] S1. Raw materials were weighed according to weight ratio: 56 parts of ethylenediamine, 28 parts of methanol, 37 parts of hexafluorobutyl methacrylate, 19 parts of petroleum sulfonate, 24 parts of sodium persulfate, sodium lauryl sulfate 21 parts, 14 parts of sodium dimethyl dithiocarbamate and 10 parts of dodecyl mercaptan;

[0018] S2. Add sodium lauryl sulfate into a four-necked flask, add 3 times the weight of deionized water, feed nitro...

Embodiment 2

[0022] The low-temperature crude oil demulsifier of the present embodiment is made from the following raw materials in parts by weight: 44 parts of ethylenediamine, 28 parts of methanol, 34 parts of hexafluorobutyl methacrylate, 16 parts of petroleum sulfonate, and 17 parts of sodium persulfate. 25 parts of sodium lauryl sulfate, 16 parts of sodium dimethyldithiocarbamate and 8 parts of dodecyl mercaptan.

[0023] The preparation method of the low temperature crude oil demulsifier of the present embodiment: comprise the following steps:

[0024] S1. Raw materials were weighed according to weight ratio: 44 parts of ethylenediamine, 28 parts of methanol, 34 parts of hexafluorobutyl methacrylate, 16 parts of petroleum sulfonate, 17 parts of sodium persulfate, sodium lauryl sulfate 25 parts, 16 parts of sodium dimethyl dithiocarbamate and 8 parts of dodecyl mercaptan;

[0025] S2. Add sodium lauryl sulfate into a four-necked flask, add 2 times the weight of deionized water, feed ...

Embodiment 3

[0029] The low-temperature crude oil demulsifier of the present embodiment is made from the following raw materials in parts by weight: 55 parts of ethylenediamine, 21 parts of methanol, 32 parts of hexafluorobutyl methacrylate, 17 parts of petroleum sulfonate, and 20 parts of sodium persulfate. Parts, 22 parts of sodium lauryl sulfate, 16 parts of sodium dimethyldithiocarbamate and 12 parts of dodecyl mercaptan.

[0030] The preparation method of the low temperature crude oil demulsifier of the present embodiment comprises the following steps:

[0031] S1. Raw materials were weighed according to weight ratio: 55 parts of ethylenediamine, 21 parts of methanol, 32 parts of hexafluorobutyl methacrylate, 17 parts of petroleum sulfonate, 20 parts of sodium persulfate, sodium lauryl sulfate 22 parts, 16 parts of sodium dimethyl dithiocarbamate and 12 parts of dodecyl mercaptan;

[0032] S2. Add sodium lauryl sulfate into a four-neck flask, add 3 times the weight of deionized water...

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Abstract

The invention discloses a low-temperature demulsifier for crude oil and a preparation method of the low-temperature demulsifier, and belongs to the field of additive chemicals for oilfields. The low-temperature demulsifier for the crude oil is prepared from the following raw materials: 40-60 parts of ethylenediamine, 20-36 parts of methanol, 28-42 parts of 2,2,3,4,4,4-hexafluorobutyl methacrylate,15-23 parts of petroleum sulfonate, 10-25 parts of sodium persulfate, 20-36 parts of sodium dodecyl sulfate, 10-18 parts of sodium dimethyldithiocarbamate and 8-15 parts of 1-dodecanethiol. The invention further discloses the preparation method of the low-temperature demulsifier. The demulsifier has the characteristics of high demulsification speed and high efficiency, and the preparation methodis simple and low in cost.

Description

technical field [0001] The invention relates to the technical field of oilfield chemical additives, in particular to a low-temperature crude oil demulsifier and a preparation method thereof. Background technique [0002] With the development of the world's petroleum industry, the amount of oil extraction is increasing. When crude oil is extracted from the ground, it often carries a large amount of water or brine. Under the action of the interface active substances in crude oil, these water or brine can be combined with crude oil Emulsions with considerable stability are formed. These emulsions bring great difficulties to oil and gas gathering and transportation and crude oil refining. Therefore, dehydration and desalination must be carried out, that is, demulsification. Different methods can be used for demulsification, but the most common is The most effective method is to add chemical reagents for chemical demulsification. The demulsifier molecules penetrate and adhere to ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G33/04C08F120/24
CPCC08F120/24C10G33/04
Inventor 陈世军苑慧莹郭军杨继刚
Owner XI'AN PETROLEUM UNIVERSITY
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