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Carbon determination method for converter steelmaking flue gas analysis

A flue gas analysis and converter steelmaking technology, applied in the field of iron and steel metallurgy, can solve the problems that are difficult to accurately determine, and the influence of the decarburization rate of the converter bath is not considered, and achieve the effect of high accuracy

Active Publication Date: 2018-10-12
UNIV OF SCI & TECH BEIJING
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Problems solved by technology

The carbon curve fitting model for the end point of converter smelting focuses on the late stage of blowing. Currently, the common end point carbon curve fitting models include the cubic model and the exponential model. Although these two end point carbon curve fitting models for converter smelting avoid the difficult However, it does not consider the influence of operating process parameters such as oxygen lance position, top-blowing oxygen flow rate, and bottom-blowing gas flow rate on the decarburization rate of the converter melt pool during the actual blowing process.

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  • Carbon determination method for converter steelmaking flue gas analysis
  • Carbon determination method for converter steelmaking flue gas analysis
  • Carbon determination method for converter steelmaking flue gas analysis

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[0058] When the 210-ton converter of a steel plant produces SPHC steel as the implementation carrier, when the converter blowing is close to the end, the oxygen lance position, top blowing oxygen flow rate, bottom blowing gas flow rate, flue gas CO and CO are obtained through the detection equipment. 2 According to the percentage content and flue gas flow rate, according to the molecular theory of metallurgical slag and historical data, the activity of FeO in the slag is calculated to be 0.241. When the average tapping temperature is 1686°C, the limit carbon content w[C] of the molten pool for the selective oxidation of C and Fe elements 0 is 0.033%. Table 1 is the final slag composition of SPHC steel, and Table 2 is the experimental results after the implementation of the present invention. From the experimental results, the prediction error of the carbon content at the end of converter smelting provided by the model has a high hit rate when the error is between ±0.02%.

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Abstract

The invention provides a carbon determination method for converter steelmaking flue gas analysis, belonging to the field of iron and steel metallurgy. The method includes the following steps: firstly,according to the principle of mass conservation, calculating a decarburization rate of a molten pool in combination with the CO and CO2 percentage contents of the flue gas and the flue gas flow obtained by detection equipment in a converter smelting process; secondly, introducing a concept of molten pool mixing degree into an end point carbon curve fitting index model; and then, according to themolecular theory of metallurgical slags and the characteristics of steel grades produced, obtaining compositions of final smelting slags and the temperature of molten steel at a smelting end point, and calculating a limiting carbon content W[C]0 of the smelting molten pool; and finally, obtaining a carbon determination model for converter steelmaking flue gas analysis. The model in the method introduces the concept of molten pool mixing degree, and fully considers the influence of operating process parameters such as oxygen lance positions, top-blown oxygen flow and bottom-blown gas flow on the decarburization process of the converter molten pool; and the limiting carbon content W[C]0 of the molten pool can be calculated by using the activity of molten slags according to actual smelting steel grades, and higher accuracy can be realized.

Description

technical field [0001] The invention relates to the field of iron and steel metallurgy, in particular to a method for analyzing and determining carbon in converter steelmaking flue gas. Background technique [0002] Oxygen converter steelmaking is currently the most important steelmaking method in the world. my country's converter steel production accounts for more than 90% of the total steel production, and the decarburization reaction runs through the converter steelmaking process. A key indicator of whether converter blowing has reached the end of smelting is whether the carbon content of molten steel in the molten pool of converter steelmaking meets the requirements for tapping; in this regard, the sub-lance technology is widely used in large and medium-sized converters in various steel mills to obtain the carbon content of molten steel at the end of smelting . However, key smelting information such as decarburization rate in the converter bath cannot be continuously ob...

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Application Information

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IPC IPC(8): G06F17/50C21C5/28
CPCC21C5/28G06F30/20
Inventor 刘青孙建坤李南曹玲玲林文辉
Owner UNIV OF SCI & TECH BEIJING
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